Cosmic Dust – its Formation, Processing, and Destruction

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Review
08 December 2022

A large fraction of interstellar carbon is locked up in solid grains. The nature, origin and evolution of these grains have been investigated for decades. A combination of observations, models and experiments indicates that carbonaceous dust is mostly made of a mixture of grains composed almost exclusively of carbon and hydrogen. They have different proportions of aliphatic and aromatic structures, and a variable H/C ratio. Their sizes can vary typically between the nm and the hundreds of nm. Carbonaceous grains are largely formed in the envelopes of carbon rich asymptotic giant branch (AGB) stars and evolve in the interstellar medium, where they can be transformed or destroyed by the effects of hydrogen atoms, UV radiation, cosmic rays or shock waves from supernovae. Surviving grains eventually enter dense clouds and participate in the cloud collapse leading to star formation, closing thus their lifecycle. Within this general picture, there are doubts and issues that cannot be solved just by observation and modeling and require laboratory work. In this article we provide an overview of the development and present state of the field indicating open problems and debated questions. We stress recent experimental progress in the understanding of dust formation, both in circumstellar envelopes and the cold interstellar medium, and also in the energetic processing of dust analogs, that points to a possible top down chemistry in the diffuse medium, and especially in photon irradiated regions.

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Visual depiction of the optimized structures for each TASCC with atomic labels, including molecular bond lengths reported in Å, computed at the F12-TZ-cCR level of theory. Silicon is shown in tan and carbon is shown in gray. These are ordered as (top row, from left) r-C4, d-SiC3, r-SiC3, r-Si2C2, t-Si2C2 (bottom row) d-Si2C2, r-Si3C, d-Si3C, r-Si4.
Original Research
06 December 2022
The spectral features and detectability of small, cyclic silicon carbide clusters
Christopher M. Sehring
2 more and 
Ryan C. Fortenberry

Rovibrational spectral data for several tetra-atomic silicon carbide clusters (TASCCs) are computed in this work using a CCSD(T)-F12b/cc-pCVTZ-F12 quartic force field. Accurate theoretical spectroscopic data may facilitate the observation of TASCCs in the interstellar medium which may lead to a more complete understanding of how the smallest silicon carbide (SiC) solids are formed. Such processes are essential for understanding SiC dust grain formation. Due to SiC dust prevalence in the interstellar medium, this may also shed light on subsequent planetary formation. Rhomboidal Si2C2 is shown here to have a notably intense (247 km mol−1) anharmonic vibrational frequency at 988.1 cm−1 (10.1 μm) for ν2, falling into one of the spectral emission features typically associated with unknown infrared bands of various astronomical regions. Notable intensities are also present for several of the computed anharmonic vibrational frequencies including the cyclic forms of C4, SiC3, Si3C, and Si4. These features in the 6–10 μm range are natural targets for infrared observation with the James Webb Space Telescope (JWST)’s MIRI instrument. Additionally, t-Si2C2, d-Si3C, and r-SiC3 each possess dipole moments of greater than 2.0 D making them interesting targets for radioastronomical searches especially since d-SiC3 is already known in astrophysical media.

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5 citations