The characterization of the full-sized pore structure is important for the evaluation and prediction of the reservoir of shale gas with strong heterogeneity. It is of great scientific significance to explore the pore structure characteristics of overmature coal-bearing shale. Core descriptions, X-ray diffraction (XRD), vitrinite reflectance (Ro), field emission scanning electron microscopy (FE-SEM), high-pressure mercury intrusion porosimetry (MIP), and low-pressure N2/CO2 gas adsorption (N2-/CO2-GA) experiments were performed on overmature coal-bearing shale samples from the Wuxiang block, south-central Qinshui Basin, China. The results show that the total organic carbon (TOC) ranged from 0.29 to 8.36%, with an average of 3.84%, and the organic matter (OM) is dominated by type III kerogen. The minerals in the shale primarily consist of clay (43–85.5%, averaging 52.1%) and quartz (12.6–61.2%, averaging 43.5%). The major clay minerals are illite-smectite (I/S) and illite, ranging from 22.5 to 55.6% (mean 41.4%) and 8.7–52.7% (mean 32%), respectively. FE-SEM images reveal that intraparticle pores (IntraP pores) and interparticle pores (InterP pores) are widely developed in clay minerals, and organic pores are occasionally present. Mesopores make the greatest contribution to the total pore volume (PV), and micropores are the major contributors to the specific surface area (SSA). Clays are the main controllers of micropore development. Mesopores developed in the clay mineral layers are promoted by I/S but inhibited by illite. Macropores and microfractures are mainly developed in clays and quartz and do not correlate significantly with the TOC, or mineral composition, due to the influence of compaction and cementation. The TOC and minerals affect pore structure characteristics mainly by influencing micropores.
Based on core observations, thin sections, X-ray diffraction (XRD), and seismic data, the lithofacies types in the organic-rich Longmaxi shale (Lower Silurian) in the Changning area of the southern Sichuan Basin were identified. The factors controlling the spatial variations in the shale lithofacies and the influences of the shale lithofacies on shale gas development were also analyzed. Results indicate that there are seven main types of shale lithofacies in the Long11 sub-member of the Longmaxi Formation, including siliceous shale (S-1), mixed siliceous shale (S-2), carbonate-rich siliceous shale (S-3), clay-rich siliceous shale (S-4), carbonate/siliceous shale (M-1), mixed shale (M-2), and argillaceous/siliceous shale (M-4). A vertical transition from the carbonate shale association + mixed shale association at the bottom of the sub-member to a siliceous shale association and mixed shale association + siliceous shale at the top generally appears in the Long11 sub-member. The shale lithofacies of the Long11 sub-member also laterally change from the central depression (low-lying area) to the geomorphic highland in the east and west parts of the Changning area. The spatial variations in shale lithofacies in the Long11 sub-member of the Changning area were mainly controlled by palaeogeomorphology and relative sea level. The geomorphic highland area is dominated by carbonate-rich siliceous shale and mixed siliceous shale, but the depression (low-lying area) is mainly dominated by mixed siliceous shale and argillaceous/carbonate shale.
Pore structure is a major factor affecting the storage space and oil-bearing properties of shales. Mineralogy, organic matter content, and thermal evolution complicate the pore structures of lacustrine shales. In this study, the porosity evolution of organic-matter-rich shales from the Cretaceous Nenjiang Formation in the Songliao Basin, Northeast China, are investigated using thermal simulation experiments and in-situ scanning electron microscope analysis. Three findings were obtained as follows: 1) The pore system of shales from the Nenjiang Formation is dominated by inter-granular dissolution pores of plagioclase and intra-granular pores of illite-smectite mixed layers. Few organic-matter pores are observed. 2) New pores developing during thermal evolution are primarily organic matter pores and clay mineral pores, with diameters greater than 18 nm. Clay mineral pores with diameters of 18–50 nm are the principal contributors to porosity at temperatures between the low maturity stage and the oil-generation window, and organic matter pores with diameters of greater than 50 nm comprise the majority of pores generated between the gas-generation window and the high-/over-mature stages. 3) Porosity increases continuously with maturity, and the pore system varies at different maturity stages. Porosity evolution is controlled by illite content and organic matter abundance. Total pore volume correlates positively with illite content but negatively with organic matter abundance. These findings could provide guidance on shale oil evaluation in the Songliao Basin and assist in the ‘sweet-spotting’ of lacustrine shale systems across China.
The significance of lacustrine shale oil has gradually become prominent. Lacustrine shale has complex lithologies, and their reservoir properties are quite various. The multi-scale pore structure of shale controls the law of shale oil enrichment. Typical lacustrine shale developed in the Member 2 of Kongdian Formation in Cangdong sag, Bohai Bay Basin. The lithofacies and multi-scale storage space of this lacustrine shale have been systematically studied. 1. The mineral composition is quite different, and the lithofacies can be summarized into siliceous, carbonate and mixed types. The rock structure can be summarized into laminated, layered, and massive types. 2. The pores are diverse and multi-scale. Interparticle pores contribute the main storage space, especially the interparticle pores of quartz and dolomite. 3. The physical properties of the massive shales is relatively inferior to those of layered and laminatedtypes, and it presents the characteristics of " laminated >layered > massive ". The developed laminae can significantly improve the space and seepage capacity of lacustrine shale. 4. Clay minerals provide the main nano-scale storage space, but they are often filled in pores and reduces the shale brittleness, which have destruction effects.
There are a large number of natural fractures in shale reservoirs, which create great challenges to hydraulic fracturing. Activating the natural fractures in reservoirs can form a complex fracture network, enhance fracturing effects, and increase shale gas production. Reservoir geological conditions (low in situ stress, natural fracture distribution, and cement strength) and operation parameters (fracturing fluid viscosity and injection rate) have an important influence on fracture network propagation. In this article, a two-dimensional hydraulic fracturing fluid-mechanic coupling numerical model for shale reservoirs with natural fractures was established. Based on the global cohesive zone model, the influence of geological conditions and operation parameters on the propagation of the hydraulic fracture network and fracturing process is investigated. The numerical simulation results show that when the horizontal in situ stress difference, approach angle, and cement strength are low, it is easier to form a complex fracture network. Research on the construction parameters indicated that when the viscosity of the fracturing fluid is low, it is easier to form a complex network of fractures, but the length of the fractures is shorter; in contrast, the fractures are straight and long. In addition, increasing the injection rate is beneficial for increasing the complexity of the fracture network while increasing the initiation pressure and width of the principal fracture reduces the risk of sand plugging. This article also proposes an optimization solution for hydraulic fracturing operations based on numerical simulation results.


![Various laminated types developed in the mixed sedimentary rocks [(A–F): single polarized light; (G,H): XRF scan].](https://www.frontiersin.org/_rtmag/_next/image?url=https%3A%2F%2Fwww.frontiersin.org%2Ffiles%2FArticles%2F783042%2Ffeart-09-783042-HTML%2Fimage_m%2Ffeart-09-783042-g003.jpg&w=3840&q=75)

