AUTHOR=Lu Liqun , Wang Fengjuan , Wang Yuncheng , Zhang Jiawen , Xiang Li , Liu Zhiyong , Jiang Jinyang TITLE=Probing the nanomechanics of interfacial interactions between hydrophobic surfaces JOURNAL=Frontiers in Physics VOLUME=12 YEAR=2024 URL=https://www.frontiersin.org/journals/physics/articles/10.3389/fphy.2024.1372204 DOI=10.3389/fphy.2024.1372204 ISSN=2296-424X ABSTRACT=

Hydrophobic interactions are widely applied in diverse fields, yet the effect of the degree of hydrophobicity on the interactions between hydrophobic surfaces is still unaddressed, limiting the development of functional hydrophobic surfaces. In this study, the interfacial interactions and configuration of hydrophobic chains on surfaces with ranging hydrophobicity are surveyed by surface forces apparatus. Our findings revealed that with partial hydrophobicity, a long-range electrical double-layer repulsive force pertains between surfaces, while between fully hydrophobized surfaces, only steric hindrance is observed, and the hydrophobic chains maintain configuration even after long time compression. Our findings provide useful implications for understanding hydrophobic interactions.