AUTHOR=Srivastava Amit , Singh Ashwani Kumar , Srivastava O. N. , Tewari H. S. , Masood Khalid B. , Singh Jai 

TITLE=Magnetic and Dielectric Properties of La and Ni Co-substituted BiFeO3 Nanoceramics

JOURNAL=Frontiers in Physics

VOLUME=8

YEAR=2020

URL=https://www.frontiersin.org/journals/physics/articles/10.3389/fphy.2020.00282

DOI=10.3389/fphy.2020.00282

ISSN=2296-424X

ABSTRACT=<p>The increasing plead for the realization of ultra-fast, miniaturized, compact, and ultra-low power consumption in electronic as well as spintronic devices has propelled the quest for novel multiferroic materials that efficiently enable voltage control of magnetism. The present work reports the phase stability, magnetic and dielectric responses of polycrystalline Bi<sub>1−x</sub>La<sub>x</sub>Fe<sub>1−y</sub>Ni<sub>y</sub>O<sub>3</sub> (0 ≤ <italic>x</italic> ≥ 0.2 and 0 ≤ <italic>y</italic> ≥ 0.2) multiferroic ceramics synthesized through a simplistic sol–gel approach. The maneuver substitutions of La at A<sup>−</sup> site of BiFeO<sub>3</sub> multiferroic eliminate the secondary phases formed owing to impurities. Rietveld refined XRD analysis reveals the structural transformation of the orthorhombic (Pbnm) phase as La substitution increases. However, an additional lattice distortion is induced as a result of the substitutions of Ni atoms at B<sup>−</sup> site. A substantial enhancement in magnetic and dielectric responses has been found in the co-doped (Ni and La) sample at both A and B<sup>−</sup> sites as a result of the size confinement of nano-crystallites, the exchange interaction between Fe<sup>3+</sup> and Ni<sup>2+</sup> ions, and corresponding variation in Fe–O–Fe bond angles. The dielectric constant has increased substantially in the low-frequency region with simultaneous substitutions of La and Ni at the sites of Bi and Fe, respectively. A careful observation of temperature-dependent magnetization curves (FC and ZFC) indicates a spin glass response with entangled ferromagnetic components. The experimental findings infer that the co-substitutions of La and Ni at their respective sites in Bi<sub>1−x</sub>La<sub>x</sub>Fe<sub>1−y</sub>Ni<sub>y</sub>O<sub>3</sub> (0 ≤ <italic>x</italic> ≥ 0.2 and 0 ≤ <italic>y</italic> ≥ 0.2) may significantly improve the ferromagnetic and dielectric responses of the studied nanoceramics.</p>