AUTHOR=Hendricks R. J. , Holland D. A. , Truppe S. , Sauer B. E. , Tarbutt M. R. TITLE=Vibrational branching ratios and hyperfine structure of 11BH and its suitability for laser cooling JOURNAL=Frontiers in Physics VOLUME=2 YEAR=2014 URL=https://www.frontiersin.org/journals/physics/articles/10.3389/fphy.2014.00051 DOI=10.3389/fphy.2014.00051 ISSN=2296-424X ABSTRACT=

The simple structure of the BH molecule makes it an excellent candidate for direct laser cooling. We measure the branching ratios for the decay of the A1Π (v′ = 0) state to vibrational levels of the ground state, X1Σ+, and find that they are exceedingly favorable for laser cooling. We verify that the branching ratio for the spin-forbidden transition to the intermediate a3Π state is inconsequentially small. We measure the frequency of the lowest rotational transition of the X state, and the hyperfine structure in the relevant levels of both the X and A states, and determine the nuclear electric quadrupole and magnetic dipole coupling constants. Our results show that, with a relatively simple laser cooling scheme, a Zeeman slower and magneto-optical trap can be used to cool, slow and trap BH molecules.