MINI REVIEW article

Front. Mater.

Sec. Polymeric and Composite Materials

Volume 12 - 2025 | doi: 10.3389/fmats.2025.1582990

This article is part of the Research TopicAdvanced Electronic Packaging Materials: Constitutive Model, Simulation, Design and ReliabilityView all 6 articles

Research Progress in Interface Optimization and Preparation Technology of High Thermal Conductivity Diamond/Copper Composite Materials

Provisionally accepted
Yaohui  XueYaohui Xue1Rui  LiRui Li1Yongru  DengYongru Deng2Zhuo  ZhangZhuo Zhang1Jing  ChenJing Chen1Aijie  MaAijie Ma2*Ruilong  WenRuilong Wen2
  • 1Xi'an Modern Control Technology Research Institute, Xian China, Xian, China
  • 2School of Materials and Chemical Engineering, Xi’an Technological University, Xian China, Xi'an, China

The final, formatted version of the article will be published soon.

With the miniaturization and integration of microelectronic components, the demand for highthermal-conductivity electronic packaging materials has grown substantially. Diamond/copper (Dia/Cu) composites have become a focus of research due to their ultra-high thermal conductivity and low coefficient of thermal expansion. However, poor interfacial bonding and high interfacial thermal resistance between diamond and copper limit their practical performance. This paper reviews strategies to enhance interfacial bonding, including diamond surface metallization (e.g., electroless plating, magnetron sputtering, molten salt method, vacuum electroplating, and embedding) and copper matrix alloying (e.g., gas atomization and alloy smelting), and evaluates their effects on thermal transport properties. Additionally, the influence of preparation processessuch as vacuum hot-pressing sintering, high-temperature high-pressure sintering, spark plasma sintering, and melt infiltration on the microstructure and thermal conductivity of composites are discussed. Key factors including diamond surface roughness, particle size, volume fraction, and sintering conditions (e.g., temperature, pressure, and dwell time) are analyzed. Experimental and computational studies demonstrate that systematic optimization of these factors enhances the thermal conductivity of Dia/Cu composites, providing critical insights for developing nextgeneration high-performance electronic packaging materials.

Keywords: High thermal conductivity, Diamond/copper, Composite material, Surface metallization, Matrix alloying

Received: 25 Feb 2025; Accepted: 19 Mar 2025.

Copyright: © 2025 Xue, Li, Deng, Zhang, Chen, Ma and Wen. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) or licensor are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

* Correspondence: Aijie Ma, School of Materials and Chemical Engineering, Xi’an Technological University, Xian China, Xi'an, China

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