AUTHOR=Liu Miao , Wang Yi , Wu Yingjun , Liu Chunyang , Liu Xin TITLE=Sol-gel synthesis of magnesium aluminate and synergistic degradation of Cr(VI) ion by adsorption and photocatalysis JOURNAL=Frontiers in Materials VOLUME=10 YEAR=2023 URL=https://www.frontiersin.org/journals/materials/articles/10.3389/fmats.2023.1274625 DOI=10.3389/fmats.2023.1274625 ISSN=2296-8016 ABSTRACT=

Introduction: Magnesium aluminate (MgAl₂O₄) is a new adsorbent, which can be used to adsorb dyes and drugs, but it has not been used to adsorb Cr(VI) ions.

Methods: A conventional polyacrylamide gel route with the different chelating agents including ethylenediamine tetraacetic acid (EDTA), oxalic acid and salicylic acid have been applied to synthesis the MgAl₂O₄ nanoparticles with the high adsorption capacity and photocatalytic reduction capacity for the adsorption and reduction of Cr(VI). The phase compositions, microstructure characteristics, optical properties, adsorption capacities and photocatalytic reduction capacities of MgAl₂O₄ nanoparticles can be effectively regulated by changing the type of chelating agent.

Results and discussion: The pure phase MgAl₂O₄ nanoparticles were obtained by using EDTA and oxalic acid as chelating agents, but a small amount of MgO impurity appeared in the MgAl₂O₄ nanoparticles obtained by salicylic acid as chelating agents, which inhibited the adsorption and photocatalytic reduction ability of MgAl₂O₄ nanoparticles. The optimal MgAl₂O₄ content, Cr(VI) initial concentration and pH value were 0.75 mg/L, 100 mg/L and 5, respectively. The photocatalytic reduction capacity of MgAl₂O₄ nanoparticles obtained by oxalic acid as chelating agents was 3.56 times that of MgAl₂O₄ nanoparticles obtained by salicylic acid as chelating agents. The high adsorption capacity of MgAl₂O₄ nanoparticles is mainly due to electrostatic adsorption, while the high photocatalytic reduction capacity is mainly due to the high reduction capacity of active free radicals generated by the conduction electrons and valence band holes of MgAl₂O₄ nanoparticles.