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ORIGINAL RESEARCH article

Front. Mater., 28 April 2022
Sec. Thin Solid Films
This article is part of the Research Topic Thin Film Technology: Processing, Properties and Applications View all 4 articles

Strong Perpendicular Anisotropy and Anisotropic Landé Factor in Bismuth-Doped Thulium Garnet Thin Films

Xiuye ZhangXiuye Zhang1Lichuan Jin
Lichuan Jin1*Dainan ZhangDainan Zhang1Bo Liu
Bo Liu2*Hao MengHao Meng2Lei ZhangLei Zhang1Zhiyong ZhongZhiyong Zhong1Xiaoli TangXiaoli Tang1
  • 1State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu, China
  • 2Key Laboratory of Spintronics Materials, Devices and Systems of Zhejiang Province, Hangzhou, China

With the development of spintronics, garnet films with perpendicular magnetic anisotropy (PMA) have been attracting the attention of researchers for decades. In this work, bismuth-doped thulium iron garnet (Tm2BiFe5O12, TmBiIG) films of varying thickness having strong PMA effect were fabricated on substituted Gd3Ga5O12 (sGGG) (111) substrates using the pulsed laser deposition (PLD) technique. Crystallographic characterization and magnetic properties of TmBiIG films were investigated using high-resolution scanning transmission electron microscopy, X-ray diffraction, vibrating sample magnetometry, and broadband ferromagnetic resonance (FMR). A high perpendicular anisotropic field of H = 4,445 ± 7.5 Oe in a 10-nm-thick film and H = 4,582 ± 7.7 Oe in a 30-nm-thick film at room temperature were obtained and analyzed in detail. Surprisingly, an additional spin-wave mode was observed in the in-plane FMR spectra. The discrepancy between in-plane and the out-of-plane Landé g-factors established a correlation with the PMA effect in the TmBiIG films. The Landé g-factor of the TmBiIG films is much lower than that of free electrons, indicating that the strong spin–orbit coupling is caused by Tm and Bi heavy elements. The Gilbert damping factor α changed from 0.007 to 0.012 in various thicknesses of TmBiIG films.

Introduction

Spintronics based on magnetic garnets is a potential choice for data storage, logical computation, and next-generation sensing. Ferrimagnetic garnets, such as yttrium iron garnet (Sokolov et al., 2016) (Y3Fe5O12, YIG) or thulium iron garnet (Tm3Fe5O12, TmIG) have been extensively studied for spin transport and spin interactions, such as inverse spin Hall effect (Li et al., 2020) (ISHE), spin Seebeck effect (Kikkawa et al., 2013) (SSE), spin–orbit torque (Avci et al., 2017) (SOT) switching, and topological hall effect (Ahmed et al., 2019; Shao et al., 2019), due to their small Gilbert damping factor (10−4–10−2), narrow ferromagnetic resonance linewidth, and perpendicular magnetic anisotropy (PMA) effect. Recently, Avci et al. (2017) developed new devices for regulating SOTs in a TmIG/Pt heterostructure grown on (111)-oriented gadolinium gallium garnet (Gd3Ga5O12, GGG) with the PMA effect. This observation may lead to a new direction of research that can reduce the energy consumption in integrated devices and can demonstrate the importance of investigating new garnets having a reliable and powerful PMA effect.

The method for obtaining a strong PMA effect in garnet films is to introduce a large uniaxial anisotropy, Ku, composed of stress-induced perpendicular anisotropy Kuλ and growth-induced anisotropy Kug, which are related to the lattice mismatch, magnetostriction constant, and interaction between the ions (Hansen and Witter, 1985). There are several ways to obtain ferrimagnetic garnet films with a strong PMA effect, such as doping with Bi (Hansen et al., 1983; Hansen and Krumme, 1984; Hansen and Witter, 1985; Soumah et al., 2018; Lin et al., 2020), introducing extra Kug, substituting other rare-earth elements (Tang et al., 2016; Avci et al., 2017; Wu et al., 2018), using a large magnetostriction constant to improve Kuλ, or changing the substrate materials (Tang et al., 2016; Fu et al., 2017; Ciubotariu et al., 2019) to enlarge Kuλ by creating a greater lattice mismatch. Ultrathin films manufactured in the GGG (111)/TmIG system exhibit the PMA effect, owing to the great negative magnetostriction constant of the TmIG (Tang et al., 2016; Vilela et al., 2020) compared to the YIG (Sokolov et al., 2016; Fu et al., 2017).

In this work, bismuth-doped thulium iron garnet (Tm2BiFe5O12, TmBiIG) films of varying thicknesses with a strong PMA effect were fabricated on 5 mm × 5 mm × 0.5 mm sGGG (111) substrates using the pulsed laser deposition (PLD) technique. The value of the perpendicular anisotropic field in different film thicknesses was determined by ferromagnetic resonance measurements. Due to the strong PMA effect of the film (Farle, 1998), an extra spin-wave mode was observed in the in-plane magnetized condition when applied magnetic field H is smaller than the net perpendicular anisotropy field 4πMeff. This has also been observed in some other materials having a strong PMA effect (Barsukov et al., 2014; Tivakornsasithorn et al., 2014). Moreover, the difference between the in-plane and the out-of-plane Landé g-factors can be obtained from FMR spectrum analysis in correlation with the PMA effect in the TmBiIG films. Furthermore, unlike other rare-earth elements and transition metals (Woltersdorf et al., 2009), the doped Bi3+ ions did not enlarge the Gilbert damping factor α as compared to the TmIG/sGGG (Ciubotariu et al., 2019) system, whose values are 0.007–0.012 in different thickness TmBiIG. This strong perpendicular anisotropy field and relatively low Gilbert damping lay a solid foundation for future study on spintronics materials.

Materials and Methods

In our experiments, a 2-inch Tm2BiFe5O12 ceramic target with high purity was fabricated by a standard solid state reaction method of Tm2O3 (99.999%), Bi2O3 (99.999%), and Fe2O3 (99.999%). Before the growth, a mixture of concentrated 10 ml sulfuric acid and 10 ml hydrogen peroxide was prepared, and the sGGG substrate was immersed for 15 min to remove the oxide impurities on the surface. Then sGGG substrate was soaked in acetone and alcohol, respectively, for ultrasonic cleaning to obtain a clean substrate surface. Before depositing the films, the distance between the target and the substrate was adjusted to 70 mm. The wavelength of the KrF excimer laser used in PLD was 248 nm. Laser intensity and frequency were set to 300 mJ (2.4 J/cm2) and 5 Hz, respectively. The base vacuum level of the chamber was 8 × 10−6 Pa. During the pre-deposition process, the temperature in the chamber was raised from room temperature to 750°C at a rate of about 12°C/min. At the same time, the oxygen pressure was set to 1 Pa in order to form a high-quality TmBiIG film. Under the aforementioned conditions, the growth rate of the film was about 2 nm/min. After the deposition, the films were transferred to a thermal annealing system for recrystallization at 800°C in air atmosphere for 1 h, and the heating rates and cooling rates are 60°C/min and 4.33°C/min, respectively.

TmBiIG films were characterized by a high-resolution X-ray diffractometer (HRXRD, Bede D1), high-resolution scanning transmission electron microscopy (STEM, FEI Talos F200X), atomic force microscope (AFM, PARK-XE7), vibrating sample magnetometry (VSM, USA LakeShore 8,603), and angular-resolved FMR measurements. The FMR spectrum was obtained by sweeping the magnetic field at a fixed microwave frequency. The derivative of microwave absorption power and the static magnetic field was defined as the intensity of the FMR spectrum, which was attained by applying a static magnetic field in-plane and out-of-plane. Coplanar waveguide (CPW) and short circuit antenna structures were composed of 20 nm Ta and 200 nm Au manufactured by photolithography. All the measurements were conducted at room temperature.

Results and Discussion

The surface morphology characterization of a 20-nm-thick TmBiIG film sample measured in the contact mode is shown in Figure 1A. The root-mean-square (rms) roughness of the film over a 2 μm × 2 µm scanned area is 0.3 nm, which indicates a smooth film surface. All samples in this work show a similar rms roughness. The in-plane XRD result along (20-2) of a 30-nm-thick film is shown in Figure 1B, the position of the diffraction peak corresponds to that in the study by Wu et al. (2018). No discernible separation of the peaks of TmBiIG films and sGGG substrates was observed, which means the sample grew coherently on the substrate through the strain. Peaks from thinner samples could not be resolved using XRD. However, considering the thickest sample in the study grow coherently on the substrate and the film of each thickness used in this work exhibits the PMA effect, all thickness samples are supposed to show a similar in-plane XRD pattern. Figure 1C displays a series of HRXRD patterns for the TmBiIG films grown on the (111) sGGG substrates at various thicknesses. The radiation line of the HRXRD is Cu-Kα. A bare substrate diffraction pattern is performed for comparison, revealing the contributions from Kα2 and Kα1 (Illig et al., 2013), which split the main (444) reflection of the substrates. According to the XRD patterns, the thickness of the TmBiIG has an obvious effect on the crystalline structure. With the decrease in the film thickness, the (444) diffraction peak of TmBiIG at an angle of 2θ becomes larger, indicating a more compressed lattice in the direction of growth, which results in a smaller lattice constant in the film’s normal direction. Through Bragg’s laws, the lattice spacing was deduced from the XRD results, and then the lattice parameter was calculated. The out-of-plane strain states ε of 10-, 20-, and 30-nm-thick films are −1.56%, −1.45%, and −1.13%, respectively. Considering all samples are strained without relaxation, the value of in-plane strain states ε was 0.54%. Figure 1D demonstrates a series of narrow rocking curves of the TmBiIG (444) peak (FWHM = 0.0909–0.0986), which confirms its good crystallinity.

FIGURE 1
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FIGURE 1. (A) AFM surface morphology of a 20-nm-thick TmBiIG film in a 2 μm × 2 µm region with rms roughness of 0.3 nm, demonstrating the ultra-flat surface. Crystallographic characterization results for the TmBiIG films; (B) HRXRD in-plane scan of the 30-nm-thick sample along the (20-2) direction; (C) HRXRD ω–2θ scans of the (444) plane of the TmBiIG/sGGG (111), and (D) rocking curve of the TmBiIG (444) for various film thicknesses.

Figure 2 shows a high angle annular dark field scanning transmission electron microscopy (HAADF-STEM) image of the 20-nm-thick sample. The line of dashes in Figure 2 reveals the boundary between the TmBiIG film and the sGGG substrate, identified by an energy dispersive spectrometer (EDS) surface scan. Tm, Bi, and Fe elements in the film and Gd, Ga, and Ca elements in the substrate were verified, exhibiting the slight diffusion phenomenon of the above five atoms at both ends of the interface. Figure 3 demonstrates an image of a high-resolution transmission electron microscope (HR-TEM) of the cross section from the 20-nm-thick TmBiIG film grown on sGGG, and a periodic lattice is clearly observed illustrating the good crystalline quality of the film. The well-ordered atomic structure and sharp diffraction spots illustrate good epitaxial growth of TmBiIG (111) on sGGG (111), and there is no visible dislocation or cracking in the film, even due to the in-plane strain.

FIGURE 2
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FIGURE 2. HAADF-STEM image of the 20-nm-thick TmBiIG/sGGG cross-sectional structure. The black line of dashes shows the boundary between film and substrate. EDS exhibits the location distribution of the Tm, Bi, Fe, Ga, Gd, and Ca elements by comparing different colors.

FIGURE 3
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FIGURE 3. HR-TEM image from a 20-nm-thick TmBiIG/sGGG cross-sectional structure. The white scale bar corresponds to 5 nm. Inset shows the FFT from the image.

In the existing works (Kubota et al., 2013; Zanjani and Onbasli, 2019), the film will be subjected to tensile strain when the film lattice constant afilm is less than the substrate lattice constant asub. The lattice constant of the TmBiIG film is smaller than the lattice constant of the sGGG substrate, inducing a tensile strain in the film. This is the source of the strong PMA effect of the film. To verify the strong PMA effect in the TmBiIG films, VSM measurements were performed on the same sample of TmBiIG films mentioned before. Figure 4A displays the in-plane and the out-of-plane hysteresis loops for the 30-nm-thick sample in a narrow magnetic field range. The out-of-plane hysteresis loop is squared and saturated in a small magnetic field, while the in-plane hysteresis loop does not saturate even with the maximum magnetic field (about 2000 Oe) of the instrument (not shown here), thereby exhibiting a hard-axis behavior. The out-of-plane hysteresis loop in Figure 4B exhibits the coercivity (HC) and the saturation magnetization (MS) per unit volume in the films with varying thicknesses. The saturation magnetization of 10-, 20-, and 30-nm-thick films are about 55, 67, and 71 emu/cm3, respectively.

FIGURE 4
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FIGURE 4. (A) Out-of-plane (black line) and in-plane (red line) hysteresis loops of a 30-nm-thick sample in narrow range. (B) Out-of-plane hysteresis loop of 10-, 20-, and 30-nm-thick films in the narrow range. The paramagnetic contribution from the substrate sGGG has been removed in the raw data.

In the TmBiIG/sGGG system, the main contributors to the effective anisotropy energy density are shape anisotropy Kshape, uniaxial anisotropy Ku (commonly expressed as K2 in other literature), and magnetocrystalline anisotropy K1 (commonly expressed as K4 in other literature). Generally, perpendicular anisotropy in thin films is due to the sum of the perpendicular anisotropy energy K (Ku+K1), which is large enough to overcome the shape anisotropy energy Kshape. In this article, we used angular-resolved FMR measurements and VSM to determine the total perpendicular anisotropy energy of the TmBiIG films. The angle-dependent Smith–Suhl method for the arbitrary orientation of the applied magnetic field is used to deduce the ferromagnetic resonance condition in this work (Farle, 1998; Shaw et al., 2015; Ciubotariu et al., 2019):

(ωrγ)2=1(MSsinθ)2(FθθFφφFθφ2).(1)

Eq. 2 displays the free energy of the TmBiIG film:

F=12μ0MS2cos2θKucos2θ12K1cos4θ18K1(3+cos4φ)sin4θ   μ0MSH(cosθcosθH+cos(φφH)sinθsinθH),(2)

where (θ, φ) and (θH, φH) are the polarization angle and in-plane azimuthal angle of magnetic moment and static magnetic field, respectively. γ is the gyromagnetic ratio and μ0 is the vacuum permeability. When θ (θH) is 90 (0) degrees, the magnetic moment (static magnetic field) is considered as in-plane (out-of-plane). In Eq. 2, the first term is the demagnetization energy, the second term is the uniaxial anisotropy energy, the third and fourth terms are the magnetocrystalline anisotropy energy, and the fifth term is the Zeeman energy. We have measured the FMR spectrum of 10- and 30-nm-thick TmBiIG samples in in-plane and out-of-plane, respectively, shown in Figure 5, and in-plane angular FMR measurements (not shown here) exhibit the resonance field HR that has barely any variation, indicating that the K1 of the films can be neglected. The in-plane ferromagnetic resonance condition and the out-of-plane ferromagnetic resonance condition can be derived from Eqs 1, 2, as follows:When θ = θH = 0°,

ωrγ=HR4πMS+2(Ku+K1)MS.(3)

When θ = θH = 90°,

ωrγ=HR(HR+4πMS2KuMs).(4)

Moreover,

4πMeff=4πMs2KuMs2K1Ms,(5)
4πMeff=4πMs2KuMs,(6)

where 4πMeff and 4πMeff extracted from the in-plane and the out-of-plane fitting curves, respectively, are as shown in Figures 6A,B. Meanwhile, the net perpendicular anisotropy field is defined as 4πMeff. A negative value of 4πMeff explains that the perpendicular anisotropy energy overcomes the demagnetization energy and makes the residual magnetic moment orient out-of-plane. Furthermore, perpendicular anisotropic field H were 4,445 ± 7.5 Oe and 4,582 ± 7.7 Oe in the 10- and 30-nm-thick films, respectively, from Eq. 7.

H=4πMs4πMeff.(7)

FIGURE 5
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FIGURE 5. FMR measurement of the TmBiIG film. In-plane ferromagnetic resonance spectra of (A) 10- and (B) 30-nm-thick samples. Out-of-plane ferromagnetic resonance spectra of (C) 10 nm thickness in 9–16 GHz (1 GHz interval) and (D) 30 nm thickness in 9–18 GHz (1 GHz interval).

FIGURE 6
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FIGURE 6. Resonance magnetic field dependence on the frequency in (A) 10- and (B) 30-nm-thick films. An extra spin-wave mode (SWR) was detected in the in-plane ferromagnetic resonance spectra.

However, the experimental results show that the perpendicular anisotropic field H of the 10-nm-thick film is slightly smaller than that of the 30-nm-thick film. This is due to the 4πMS in the 10-nm-thick film being smaller than that in the 30-nm-thick film, which is shown in Figure 4B.

The comparison of the H value between the TmBiIG/sGGG system and other ferrimagnetic garnet systems are shown in Table 1. It should be noted that the H value in the TmBiIG/sGGG system is larger than that in the TmIG/sGGG system when the film has the same thickness (10 nm). This is due to the extra growth-induced anisotropy introduced by Bi doping. As a heavy element with strong spin–orbit interaction, Bi3+ ions have a profound influence on the local symmetry, super-exchange interaction, and spin–orbit coupling in the nearby Fe3+ ions. The order of priority for the Bi3+ ions in the dodecahedron position affects the uniaxial component of free energy of the adjacent Fe3+ ions in the octahedron and the tetrahedron positions, thus resulting in an additional magnetic anisotropy (Hansen and Witter, 1985).

TABLE 1
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TABLE 1. Comparison of magnetic anisotropy parameters based on the recent works. Partial reference data have been converted from the SI units to the CGS units in the article. It should be pointed out that the sGGG* listed in the table has a larger lattice constant than the substrate used in this work.

As shown in Figures 5A,B, a special spin-wave mode exists at low frequencies and for low magnetic fields in all thickness films, which is also observed in other materials due to the strong perpendicular anisotropy (Barsukov et al., 2014; He et al., 2016; Glowinski et al., 2017; Devolder et al., 2018). This special spin mode was observed using the in-plane FMR measurements and is usually known as the smallest spin mode in bubble films (Portis, 1963; Dötsch et al., 1978). Unlike the Kittel mode, the magnitude of the resonance field is inversely related to the resonance frequency as this spin-wave mode occurs when the magnetic moment is not fully oriented in the in-plane, indicating that the magnetic moments are not processed uniformly (Hoekstra et al., 1977; Dötsch et al., 1978).

From the fitting analysis in Eqs 3, 4, the gyromagnetic ratio of the in-plane and the out-of-plane magnetized of various thicknesses of the TmBiIG film is obtained. The values of (γ2π) are 2.37 ± 0.003 GHz/kOe, 2.40 ± 0.001 GHz/kOe, and 2.37 ± 0.003 GHz/kOe, and the values of (γ2π) are 2.33 ± 0.002 GHz/kOe, 2.37 ± 0.003 GHz/kOe, and 2.29 ± 0.004 GHz/kOe in the 10-, 20-, and 30-nm-thick films, respectively. The g and the g in various thicknesses of the TmBiIG film are determined by Eq. 8:

g=γμB,(8)

where is the reduced Planck constant and μB is the Bohr magneton. A similar tendency is observed in all thickness samples, in which the g is larger than g. The discrepancy of the Landé g-factor in every sample is demonstrated in Table 2, which reveals the anisotropy of the Landé g-factor in the TmBiIG film.

TABLE 2
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TABLE 2. Gyromagnetic ratio and Landé g-factor under in-plane and out-of-plane magnetized condition of the TmBiIG film with various thicknesses.

Based on the Bruno theory (Bruno, 1989) and the Justin M. Shaw experiments (Shaw et al., 2013), when the Curie temperature (TC) of the material is much higher than the room temperature, the asymmetric g-factor between the hard axis and the easy axis indicates the asymmetry of the orbital magnetic moment, confirming that the TmBiIG film has a perpendicular anisotropy along the easy axis, as demonstrated in Eqs 9, 10:

MAE=Aξ4μBΔμL,(9)
ΔμL=μLμL=μS2(gg),(10)

where ξ is the spin–orbit coupling parameter, A is a pre-factor which is a function of the electronic structure, and μB is the Bohr magneton. The Landé g-factor of the TmBiIG films is much lower than that of free electrons, indicating the mixing of orbital magnetism caused by the coupling of high spin–orbits from heavy elements Tm and Bi (Crossley et al., 2019).

Gilbert damping factor α and the FMR linewidth ΔH are usually used to characterize the magnetic dissipation. Damping parameter α from in-plane FMR usually includes a contribution from the non-Gilbert relaxation, namely, two-magnon scattering (Woltersdorf et al., 2009; Khodadadi et al., 2020) driven by defects, which broadens the ΔH as shown in Figure 7. However, two-magnon scattering is suppressed when the film is magnetized out-of-plane. The value of α is evaluated from the frequency dependence of the ΔH when an out-of-plane magnetic field is applied to the films. For the various thicknesses of films, α and ΔH0 were extracted from the slope and the intercept with the y-axis using the following Eq. 11:

ΔH=ΔH0+4παγf.(11)

FIGURE 7
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FIGURE 7. Relationship between the frequency and the FMR linewidth in (A) 10-, (B) 20-, and (C) 30-nm-thick samples under in-plane and out-of-plane magnetized condition. The Gilbert damping factor in each thickness film and its error bar are shown in the figure, respectively.

The values of Gilbert damping α in 10-, 20-, and 30-nm-thick TmBiIG films are 0.007 ± 0.001, 0.009 ± 0.001, and 0.012 ± 0.004, demonstrating that the TmBiIG/sGGG system is of the same order as that of the TmIG/sGGG system, which has been recently reported to be in the range of 0.015–0.025 (Ciubotariu et al., 2019), suggesting that the doping of Bi element has no significant influence on α. In addition, no clear thickness dependence of the damping constant was observed.

Conclusion

In summary, in this work, ultrathin TmBiIG films with strong PMA were fabricated on [111]-oriented sGGG substrate using pulsed laser deposition. The perpendicular anisotropic field of TmBiIG films with different thicknesses was determined by ferromagnetic resonance measurements. The anisotropic gyromagnetic ratio and the anisotropic g-factor are extracted from the in-plane and the out-of-plane FMR measurements, respectively. The appearance of the spin-wave mode in-plane is also related to the strong perpendicular anisotropy. The outstanding PMA effect and the relatively small Gilbert damping (α) indicate the potential application of the ultrathin TmBiIG films in the field of spintronic devices.

Data Availability Statement

The original contributions presented in the study are included in the article/Supplementary Material, further inquiries can be directed to the corresponding authors.

Author Contributions

XZ performed sample preparation and wrote the manuscript; LJ designed and supervised this work; DZ and LZ performed FMR measurements; XT and ZZ took part in data analysis; HM and BL provided editing and writing assistance. All authors read and contributed to the manuscript.

Funding

This work was supported by the National Key Research and Development Plan under Grant No. 2016YFA0300801, National Key Scientific Instrument and Equipment Development Project No. 51827802, the National Natural Science Foundation of China under Grant No. 62171096, and the Sichuan Science and Technology Support Project under Grant Nos. 2021YFG0347 and 2021YFG0091.

Conflict of Interest

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Publisher’s Note

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors, and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.

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Keywords: bismuth-doped thulium iron garnet, perpendicular magnetic anisotropy, spintronic materials, Landé g-factor, ferromagnetic resonance spectrum

Citation: Zhang X, Jin L, Zhang D, Liu B, Meng H, Zhang L, Zhong Z and Tang X (2022) Strong Perpendicular Anisotropy and Anisotropic Landé Factor in Bismuth-Doped Thulium Garnet Thin Films. Front. Mater. 9:879711. doi: 10.3389/fmats.2022.879711

Received: 20 February 2022; Accepted: 28 March 2022;
Published: 28 April 2022.

Edited by:

Jijie Huang, Sun Yat-sen University, China

Reviewed by:

Yanda Ji, Nanjing University of Aeronautics and Astronautics, China
Di Zhang, Los Alamos National Laboratory (DOE), United States

Copyright © 2022 Zhang, Jin, Zhang, Liu, Meng, Zhang, Zhong and Tang. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

*Correspondence: Lichuan Jin, lichuanj@uestc.edu.cn; Bo Liu, liubo_sm@163.com

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