AUTHOR=Hamawandi Bejan , Mansouri Hamta , BALLIKAYA Sedat , Demirci Yunus , Orlovská Martina , Bolghanabadi Nafiseh , Sajjadi Seyed A., Toprak Muhammet S.

TITLE=A Comparative Study on the Thermoelectric Properties of Bismuth Chalcogenide Alloys Synthesized through Mechanochemical Alloying and Microwave-Assisted Solution Synthesis Routes

JOURNAL=Frontiers in Materials

VOLUME=7

YEAR=2020

URL=https://www.frontiersin.org/journals/materials/articles/10.3389/fmats.2020.569723

DOI=10.3389/fmats.2020.569723

ISSN=2296-8016

ABSTRACT=<p>The way a material is synthesized and processed has an immense effect on its microstructure, which in turn has a big impact on its transport properties. Here, we compare the thermoelectric (TE) properties of n- and p-type Bi<sub>2−x</sub>Sb<sub>x</sub>Te<sub>3</sub> (x: 0 and 1.5) materials synthesized through two different routes, specifically mechanochemical alloying (MA)—as a solid-state synthesis route—and microwave(MW)-assisted polyol synthesis—as a solution synthesis route. Reaction time is significantly reduced in the MW synthesis, leading to significantly lower energy consumption (i.e., higher energy efficiency) per batch than using the MA route. The resultant materials are compared for their crystallinity, phase purity, morphology, and microstructure. Spark plasma sintering was used to prepare pellets, and the resultant consolidates were evaluated for their transport properties. TE properties and microstructure of the specimens were investigated in relation to processing conditions and composition. MA samples formed fused structures (from 200 nm to several micrometers in size) composed of smaller particles. MW-synthesized materials exhibited hexagonal platelet morphology, high crystallinity, and phase purity. They also showed lower thermal conductivity, leading to a higher resultant TE figure-of-merit <italic>ZT</italic>. TE properties of Bi<sub>2−x</sub>Sb<sub>x</sub>Te<sub>3</sub> samples were studied on sintered cylindrical pellet samples, where the highest <italic>ZT</italic> values achieved were 1.04 (at 440 K) for MW-Bi<sub>2</sub>Te<sub>3</sub> and 0.76 (at 523 K) for MW-Bi<sub>0.5</sub>Sb<sub>1.5</sub>Te<sub>3</sub> samples, while MA-Bi<sub>2</sub>Te<sub>3</sub> and MA-Bi<sub>0.5</sub>Sb<sub>1.5</sub>Te<sub>3</sub> samples showed maximum <italic>ZT</italic> values of 0.74 (at 460 K) and 0.27 (at 300 K), respectively, as n- and p-type TE materials. The observed trend is much higher <italic>ZT</italic> values for MW samples, ascribed to their higher degree of texturing and nanostructured grains reducing the thermal conductivity, thus achieving a better overall performance, verifying the prospect to enhance <italic>ZT</italic> using MW-assisted solution synthesis approach.</p>