AUTHOR=Wu Yu-Cheng , Yang Yu , Tan Xiao-Yue , Luo Laima , Zan Xiang , Zhu Xiao-Yong , Xu Qiu , Cheng Ji-Gui TITLE=Preparation Technology of Ultra-Fine Tungsten Carbide Powders: An Overview JOURNAL=Frontiers in Materials VOLUME=7 YEAR=2020 URL=https://www.frontiersin.org/journals/materials/articles/10.3389/fmats.2020.00094 DOI=10.3389/fmats.2020.00094 ISSN=2296-8016 ABSTRACT=

Ultrafine tungsten carbide (WC) powder refers to WC powders with a particle size between 100 and 500 nm. Researchers have improved the comprehensive properties of WC-based cemented carbides by preparing ultra-fine WC powders. Because of the preparation and application of nanoscale WC powders, ultrafine-grain cemented carbides with excellent hardness and wear resistance have been successfully produced. In this paper, the preparation methods of ultra-fine WC powder are divided into solid-phase, liquid-phase, and vapor-phase methods according to the state of the raw materials (i.e., the W or C source). The liquid-phase methods could realize the preparation of WC at the temperature between 500 and 800°C. The purity of WC prepared by vapor-phase method is the highest. The solid-phase reduction carbonization method has potential industrial application.