AUTHOR=Contri Giseli , Zimmermann Camila Aparecida , Ramoa Sílvia Daniela Araújo Da Silva , Schmitz Débora Pereira , Ecco Luiz Gustavo , Barra Guilherme Mariz de Oliveira , Fedel Michele 

TITLE=Polypyrrole Modified E-Coat Paint for Corrosion Protection of Aluminum AA1200

JOURNAL=Frontiers in Materials

VOLUME=7

YEAR=2020

URL=https://www.frontiersin.org/journals/materials/articles/10.3389/fmats.2020.00045

DOI=10.3389/fmats.2020.00045

ISSN=2296-8016

ABSTRACT=<p>This article reports the potential use of Polypyrrole (PPy) particles as anticorrosive additive on an epoxy water-based paint to increase the corrosion protective property of aluminum-coated panels. AA1200 aluminum panels were painted using the electrophoretic deposition method and the coatings with different concentrations of PPy particles were tested. PPy particles were synthetized by oxidative polymerization of pyrrole (Py) with iron (III) chloride hexahydrate (FeCl<sub>3</sub>.6H<sub>2</sub>O) in the presence of dodecylbenzenesulfonic acid (DBSA). Electrically conducting PPy particles (6.5 S cm<sup>–1</sup>) were obtained with a size average of 154 nm. The as-prepared PPy particles were added into a water-based epoxy paint and AA1200 panels were coated via electrophoretic deposition method. The corrosion protective properties of e-coated AA1200 panels were evaluated by means of electrochemical impedance spectroscopy over prolonged exposure time in neutral non-aerated 0.1 M sodium chloride NaCl electrolyte. In particular, the addition of 0.4% by weight PPy has improved the coating corrosion protective property with respect to epoxy clearcoat and exhibited the highest value of impedance modulus at low frequency among the studied coatings.</p>