AUTHOR=Zhu Yonghao , Zhang Detao , Gong Lele , Zhang Lipeng , Xia Zhenhai TITLE=Catalytic Activity Origin and Design Principles of Graphitic Carbon Nitride Electrocatalysts for Hydrogen Evolution JOURNAL=Frontiers in Materials VOLUME=6 YEAR=2019 URL=https://www.frontiersin.org/journals/materials/articles/10.3389/fmats.2019.00016 DOI=10.3389/fmats.2019.00016 ISSN=2296-8016 ABSTRACT=

Graphitic carbon nitrogen (g-C3N4) has been shown to have huge potential in photo-/electrocatalytic hydrogen generation, owing to its unique electronic structure, high nitrogen content, and excellent thermal and chemical stabilities. We have, for the first time, developed a descriptor and design principle to accurately predict the HER electrocatalytic activities of heteroatom-doped g-C3N4. The new descriptor includes the dopant and its bonding environmental information, which provides a detailed guide to the rational design and screening of high-performance catalysts. A “volcano” relationship between the descriptor and the electrocatalytic activity was established, from which the most active dopant elements and related structures were identified. It was shown that doping near the edge of g-C3N4 could be a promising strategy in developing highly active metal-free g-C3N4-based catalysts. We also reveal the intrinsic origin of the catalytic activity of the doped g-C3N4 for different activity sites. Our work provides a basic design principle of heteroatom-doped g-C3N4 as an efficient HER catalyst and a fundamental understanding of the HER mechanism.