AUTHOR=Guan Yifan , McKinley Galen A. , Fay Amanda R. , Doney Scott C. , Keppel-Aleks Gretchen TITLE=Ocean-driven interannual variability in atmospheric CO2 quantified using OCO-2 observations and atmospheric transport simulations JOURNAL=Frontiers in Marine Science VOLUME=11 YEAR=2024 URL=https://www.frontiersin.org/journals/marine-science/articles/10.3389/fmars.2024.1272415 DOI=10.3389/fmars.2024.1272415 ISSN=2296-7745 ABSTRACT=

Interannual variability (IAV) in the atmospheric CO2 growth rate is caused by variation in the balance between uptake by land and ocean and accumulation of anthropogenic emissions in the atmosphere. While variations in terrestrial fluxes are thought to drive most of the observed atmospheric CO2 IAV, the ability to characterize ocean impacts has been limited by the fact that most sites in the surface CO2 monitoring network are located on coasts or islands or within the continental interior. NASA’s Orbiting Carbon-Observatory 2 (OCO-2) mission has observed the atmospheric total column carbon dioxide mole fraction (XCO2) from space since September 2014. With a near-global coverage, this dataset provides a first opportunity to directly observe IAV in atmospheric CO2 over remote ocean regions. We assess the impact of ocean flux IAV on the OCO-2 record using atmospheric transport simulations with underlying gridded air-sea CO2 fluxes from observation-based products. We use three observation-based products to bracket the likely range of ocean air-sea flux contributions to XCO2 variability (over both land and ocean) within the GEOS-Chem atmospheric transport model. We find that the magnitude of XCO2 IAV generated by the whole ocean is between 0.08-0.12 ppm throughout the world. Depending on location and flux product, between 20-80% of the IAV in the simulations is caused by IAV in air-sea CO2 fluxes, with the remainder due to IAV in atmospheric winds, which modulate the atmospheric gradients that arise from climatological ocean fluxes. The Southern Hemisphere mid-latitudes and low-latitudes are the dominant ocean regions in generating the XCO2 IAV globally. The simulation results based on all three flux products show that even within the Northern Hemisphere atmosphere, Southern Hemisphere ocean fluxes are the dominant source of variability in XCO2. Nevertheless, the small magnitude of the air-sea flux impacts on XCO2 presents a substantial challenge for detection of ocean-driven IAV from OCO-2. Although the IAV amplitude arising from ocean fluxes and transport is 20 to 50% of the total observed XCO2 IAV amplitude of 0.4 to 1.6 ppm in the Southern Hemisphere and the tropics, ocean-driven IAV represents only 10% of the observed amplitude in the Northern Hemisphere. We find that for all three products, the simulated ocean-driven XCO2 IAV is weakly anti-correlated with OCO-2 observations, although these correlations are not statistically significant (p>0.05), suggesting that even over ocean basins, terrestrial IAV obscures the ocean signal.