AUTHOR=Fan Jinqi , Duan Liqin , Yin Meiling , Yuan Huamao , Li Xuegang TITLE=Nonconservative behavior of dissolved molybdenum and its potential role in nitrogen cycling in the Bohai and Yellow Seas JOURNAL=Frontiers in Marine Science VOLUME=9 YEAR=2022 URL=https://www.frontiersin.org/journals/marine-science/articles/10.3389/fmars.2022.1094846 DOI=10.3389/fmars.2022.1094846 ISSN=2296-7745 ABSTRACT=
Molybdenum plays an important role in marine biological activity, especially in nitrogen cycling as a cofactor for N2 fixation and nitrate reductase. However, the dissolved Mo (dMo) behavior and its interaction with N cycling in the coastal waters is still unclear. In this study, the dMo concentrations and parameters related to Mo distribution and N cycling in surface and bottom seawaters of the Bohai (BS) and Yellow Seas (YS) were examined. The results showed that dMo concentrations ranged from 36.4 nmol L-1 to 125.0 nmol L-1, most of which deviated significantly from the conservative line, indicating nonconservative behavior of Mo relative to salinity. The highest dMo concentrations occurring in 36°N section of north of the South YS (SYS), were close to conservative value (105 nmol L-1). Significant depletion up to 40-50 nmol L-1 of dMo mainly appeared in the BS, NYS and south of the SYS, suggesting the possible removal of dMo by biological utilization and particle adsorption. Particularly, the increasing dMo concentrations away the Yellow River estuary indicated that freshwater dilution was one of reasons for dMo distributions in the BS. The similar spatial distribution of dMo and dissolved Mn concentrations suggested the possible scavenging by MnOx phases for Mo removal. The negative correlation between dMo and chlorophyll-