AUTHOR=Liang Gemeng , Pillai Anoop Somanathan , Peterson Vanessa K. , Ko Kuan-Yu , Chang Chia-Ming , Lu Cheng-Zhang , Liu Chia-Erh , Liao Shih-Chieh , Chen Jin-Ming , Guo Zaiping , Pang Wei Kong 

TITLE=Effect of AlF3-Coated Li4Ti5O12 on the Performance and Function of the LiNi0.5Mn1.5O4||Li4Ti5O12 Full Battery—An in-operando Neutron Powder Diffraction Study

JOURNAL=Frontiers in Energy Research

VOLUME=6

YEAR=2018

URL=https://www.frontiersin.org/journals/energy-research/articles/10.3389/fenrg.2018.00089

DOI=10.3389/fenrg.2018.00089

ISSN=2296-598X

ABSTRACT=<p>The LiNi<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4</sub> ||Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub> (LMNO||LTO) battery possesses a relatively-high energy density and cycle performance, with further enhancement possible by application of an AlF<sub>3</sub> coating on the LTO electrode particles. We measure the performance enhancement to the LMNO||LTO battery achieved by a AlF<sub>3</sub> coating on the LTO particles through electrochemical testing and use <italic>in-operando</italic> neutron powder diffraction to study the changes to the evolution of the bulk crystal structure during battery cycling. We find that the AlF<sub>3</sub> coating along with parasitic Al doping slightly increases capacity and greatly increases rate capability of the LTO electrode, as well as significantly reducing capacity loss on cycling, facilitating a gradual increase in capacity during the first 50 cycles. Neutron powder diffraction reveals a structural response of the LTO and LNMO electrodes consistent with a greater availability of lithium in the battery containing AlF<sub>3</sub>-coated LTO. Further, the coating increases the rate of structural response of the LNMO electrode during charge, suggesting faster delithiation, and enhanced Li diffusion. This work demonstrates the importance of studying such battery performance effects within full configuration batteries.</p>