AUTHOR=Hao Qing , Coleman Garrett J. , Xu Dongchao , Segal Evan R. , Agee Phillip , Wu Shijie , Lucas Pierre 

TITLE=Nanograined GeSe4 as a Thermal Insulation Material

JOURNAL=Frontiers in Energy Research

VOLUME=6

YEAR=2018

URL=https://www.frontiersin.org/journals/energy-research/articles/10.3389/fenrg.2018.00021

DOI=10.3389/fenrg.2018.00021

ISSN=2296-598X

ABSTRACT=<p>Owing to its amorphous structure, a chalcogenide glass exhibits a thermal conductivity <italic>k</italic> approaching the theoretical minimum of its composition, called the Einstein’s limit. In this work, this limit is beaten in an amorphous solid consisting of glassy particles joined by nanosized contacts. When amorphous particles are sintered below the glass transition temperature under a high pressure, these particles can be mechanically bonded with a minimized interfacial thermal conductance. This reduces the effective <italic>k</italic> below the Einstein’s limit while providing superior mechanical strength under a high pressure for thermal insulation applications under harsh environments. The lowest room temperature <italic>k</italic> for the solid counterpart can be as low as 0.10 W/m·K, which is significantly lower than <italic>k</italic>≈0.2 W/m·K for the bulk glass.</p>