- 1State Key Laboratory of Coal Mine Disaster Dynamics and Control, Chongqing University, Chongqing, China
- 2School of Resources and Safety Engineering, Chongqing University, Chongqing, China
- 3Key Laboratory of Continental Shale Hydrocarbon Accumulation and Efficient Development, Ministry of Education, Northeast Petroleum University, Daqing, China
- 4Department de Mineralogia, Petrologia i Geologia Aplicada, Facultat de Ciències de la Terra, Universitat de Barcelona (UB), Barcelona, Spain
CO2 geological storage (CGS) is considered to be an important technology for achieving carbon peak and carbon neutralization goals. Injecting CO2 into deep unminable coal seams can achieve both CGS and enhance coalbed methane (ECBM) production. Therefore, the deep unminable coal seams are considered as promising geological reservoirs. CO2 exists in a supercritical CO2 (ScCO2) when it was injected into deep unminable coal seams. The injection of ScCO2 can induce changes in the seepage characteristics and microstructure of deep water-bearing coal seams. In this study, typical bituminous coal from Shenmu, Shanxi Province was used to investigate the effects of ScCO2 on seepage characteristics, pore characteristics, and mineral composition through experiments such as seepage tests, low-temperature liquid nitrogen adsorption, and X-ray diffraction (XRD). The results indicate that ScCO2 treatment of dry and saturated coal samples caused a significant increase in clay mineral content due to the dissolution of carbonates, leading to the conversion of adsorption pores to seepage pores and an improvement in seepage pore connectivity. Therefore, the Brunauer-Emmett-Teller (BET) specific surface area and pore volume of the two coal samples both decreased after ScCO2 treatment. Moreover, the permeability of dry and saturated coal samples increased by 191.53% and 231.71% at 10 MPa effective stress respectively. In semi-saturated coal samples, a large amount of dolomite dissolved, leading to the precipitation of Ca2+ and CO32- to form calcite. This caused pore throats to clog and macropores to divide. The results show that the pore volume and average pore size of coal samples decrease, while the specific surface area increases after ScCO2 treatment, providing more space for gas adsorption. However, the pore changes also reduced the permeability of the coal samples by 32.21% and 7.72% at effective stresses of 3 MPa and 10 MPa, respectively. The results enhance our understanding of carbon sequestration through ScCO2 injection into water-bearing bituminous coal seams.
1 Introduction
Massive CO2 emissions contribute to the global greenhouse effect, which in turn causes a series of climate catastrophes. Scholars worldwide have proposed many carbon reduction options in response (Liu et al., 2019; Li X. et al., 2022; Xu et al., 2022), including carbon geological storage (CGS), which has gained recognition as an effective way to achieve CO2 sequestration and reduce greenhouse gas emissions (Wang Y. et al., 2021; Liu et al., 2021). In particular, CO2 injection into deep unminable coal seams offers a promising geological reservoir for simultaneous CO2 storage and coalbed methane (CBM) recovery (Chiquet et al., 2007; Li et al., 2009; Zepeng et al., 2022). CO2 exists in the form of ScCO2 when the depth of the coal seams exceeds 800 m, and the pressure and temperature exceed the critical conditions of 7.38 MPa and 31°C (Zhang et al., 2017). Injection of ScCO2 into coal seams, especially those containing water, can cause significant modifications to the pore and fracture structure of the coal due to mineralization reactions between ScCO2-H2O and minerals. These changes can impact permeability and adsorption capacity in turn (Dawson et al., 2011; Wang Z. et al., 2022). Scholars have conducted extensive research on the interaction of ScCO2 with coal. ScCO2 geochemical reaction experiment on typical high-rank coal of Qinshui Basin was conducted and it is found that ScCO2 dissolved minerals and change the porosity, pore volume and specific surface area of coal (Du et al., 2018). The seepage test before and after CO2 adsorption were conducted to found that CO2 adsorption increases the permeability anisotropy of coal due to the high permeability adsorption sensitivity of low permeability cleats and the low permeability adsorption sensitivity of high permeability bedding (Niu et al., 2018). Xiaolei Wang et al. treated coal with subcritical CO2 and ScCO2, respectively, and found that the solubility of minerals in ScCO2-treated coal is stronger. Furthermore, the total pore volume and BET specific surface area of coal gradually increase with the increase of CO2 intrusion pressure (Wang X. et al., 2022). Yugang Cheng et al. studied the effects of subcritical and supercritical CO2 on the pore structure of coal and found that the porosity and pore volume of coal showed an inverted “U” shaped change which first increased and then decreased with the increase of CO2 pressure (Cheng et al., 2021). M.S.A. Perera et al. conducted adsorption experiments of coal at different CO2 pressures, indicating that the maximum swelling of coal occurs within 3–4 h after CO2 injection. And the swelling strain increases while the permeability decreases as CO2 pressure increases (Perera et al., 2011).
Several studies have highlighted the important role of water in geochemical interactions (Li et al., 2019). Renxia Jiang et al. conducted a ScCO2-H2O interaction experiment on coal to investigate the effect of ScCO2-H2O on the primary mineral composition of coal. And the study found that ScCO2 effectively improves the solubility of various elements of coal in water (Jiang et al., 2019). Ruihui Li et al. conducted ScCO2 soaking experiments on bituminous coals with varying moisture contents and investigated the modification of pore characteristics and microcrystalline structure of bituminous coals with the effect of ScCO2 under different moisture conditions (Li R. et al., 2022). Guodong Cui et al. injected water and CO2 into rock samples, respectively, to investigate the effects of water and CO2 injection on minerals. The results indicated that mixing the injected water with the original formation water results in significant mineral precipitation, while acidification resulting from the injection of CO2 leads to the dissolution of some minerals and the precipitation of dolomite, altering the composition of the formation water (Cui et al., 2021). Shasha Gao et al. studied the effect of CO2-H2O interaction on the pore structure and mineral composition of coal. The results show that the pore structures of coal become more complex due to the geochemical reaction between CO2-H2O and carbonate minerals, and the fractures expands and develops after CO2-H2O treatment which is positive for permeability (Gao et al., 2022). Yao Song et al. analyzed the influences of the ScCO2–H2O coupling effect on the microstructures of low-rank coal samples and found that mineral dissolution increases as the CO2 pressure increases, resulting in an increase in porosity and macropore ratio in the coal samples (Song et al., 2020).
Although the effects of ScCO2 on the pore structure and mineral composition of coal have been extensively studied, most experiments are based on soaking treatment. The hydrological and in situ stress conditions of actual coal seams are not be considered (Mirzaeian et al., 2006; Qu et al., 2012; Song et al., 2020; Gao et al., 2022). Therefore, this paper conducted ScCO2 injection experiments on bituminous coal with varying water saturation under in situ stress to investigate the influence of ScCO2-H2O interaction on coal seepage characteristics, pore characteristics, and mineral composition through seepage, low-temperature liquid nitrogen adsorption, and XRD experiments. The findings of this study provide a theoretical guideline for CO2 geological storage (CGS) and CO2-enhanced coal bed methane recovery (CO2-ECBM).
2 Material and methods
2.1 Coal samples
The experiments in this study utilized typical bituminous coal samples from Ningtiaota coal mine, Yulin City, Shanxi Province. The coal was taken from Yan’an Formation. The coal samples were as shown in Figure 1.
Upon on-site collection, the coal was immediately wrapped with plastic and transported to the laboratory. Subsequently, it was cored, polished, and processed into standard cylindrical samples of 50 × 100 dimensions. And the experiments were repeated 2–3 times to ensure the validity of the experimental results. Coal is a natural organic rock with anisotropy. The coal samples used in the tests were all sampled perpendicular to the bedding direction in order to avoid the influence of coal anisotropy on the experimental results (Perera et al., 2011). And the coal samples are depicted in Figure 2.
2.2 Seepage test
The coal samples were divided into different groups based on their water saturation levels achieved through soaking for varying periods of time before the ScCO2 treatment. The specific group numbers and treatment conditions are presented in Table 1.
The coal rock rheology seepage system which was independently developed by the laboratory to simulate the geological environment was used to conduct the seepage tests. And the experimental equipment is illustrated in Figure 3.
Seepage tests were conducted at different axial and confining pressures namely 2.8 MPa and 5.5 MPa as well as 9.8 MPa and 12.5 MPa respectively. The seepage gas pressure was maintained at 3.1 MPa to study changes at different effective stresses. The effective stress acting on the coal sample was calculated using the Terzaghi effective stress formula (Liu Z. et al., 2020):
Where
The steady-state test method was used in the experiments. For compressible gases, the expansion of fluid can affect the measurement of permeability. Assuming that the permeation of gas through the sample is an isothermal process and that the ideal gas law is applicable. So the gas permeability was calculated according to Darcy’s law (Liu X. et al., 2020):
Where
The experimental procedure was conducted as follows: (1) The coal sample was placed in the reaction chamber and the temperature was raised to 35°C. The effective stress was adjusted to 3 MPa and 10 MPa, respectively. Helium (He) was injected to measure the initial permeability of the bituminous coal before ScCO2 treatment. (2) The He injection was stopped, and the axial and radial stress were adjusted to 10 MPa to simulate geological conditions at a depth of 1,000 m underground (Du et al., 2020). Then, ScCO2 of 8 MPa was injected after discharging the residual gas. Previous studies have pointed out that the maximum expansion strain occurs within 3–4 h after CO2 injection, so an 8-hour period is sufficient to investigate the effect of ScCO2-H2O on coal. And the coal samples were left to fully absorb and react for 8 h (Cheng et al., 2021). (3) After complete CO2 adsorption and desorption of the coal samples, step (1) was repeated to measure the permeability of the coal sample after ScCO2 treatment.
2.3 Low temperature liquid nitrogen adsorption test
The low temperature liquid nitrogen adsorption tests were conducted by using a fully automated multistation specific surface area and pore size analyzer, Quadrasorb 2 MP, manufactured by Conta Instruments, USA. Prior to the experiments, the coal samples were processed into 60–80 mesh powder and then pretreated by drying and degassing at 110°C for 24 h. The tests were used to measure the specific surface area, pore size distribution, and pore volume of the coal samples.
2.4 XRD test
The mineral components of the coal samples were analyzed by using a high efficiency conventional powder X-ray diffractometer from Spectris, the Netherlands. The coal samples were ground into a powder of 200 mesh size and were pretreated prior to the experiments. The crystallographic information of the coal samples was obtained by scanning angles ranging from 5°–80° with a scanning time of 20 min.
3 Results and Discusssion
3.1 Permeability characteristics
He seepage tests were performed on bituminous coal samples with varying water saturation levels before and after treatment to examine the effects of ScCO2-H2O on permeability characteristics. Figure 4 presents the measured permeability values.
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FIGURE 4. Permeability of the coal samples before and after ScCO2 treatment at different effective stresses. (A) 3 MPa effecitve stress, (B) 10 MPa effective stress.
Figure 4 indicates that the permeability of bituminous coal is primarily influenced by the moisture content of the coal samples prior to ScCO2 treatments (Zhang X. et al., 2019). Specifically, the permeability of coal samples declines from 0.226 mD to 0.144 mD with the increase of water saturation at 3 MPa effective stress. Similarly, the permeability of coal samples drops from 0.040 mD to 0.028 mD as water saturation increases at 10 MPa effective stress, which aligns with earlier research findings (Pan et al., 2010). The decline can be attributed to the combination of seepage channels such as the pores blockage by water and the squeezing effect caused by internal water absorption expansion (Teng et al., 2017; Talapatra et al., 2020). Moreover, the permeability of coal samples decreases due to compression of the seepage channels caused by increased stress as effective stress increases, which was the result of the continuous closure of pores and fractures as the effective stress increases (Niu et al., 2019).
In order to describe the changes of coal samples’ permeability before and after ScCO2 treatment better, the permeability change index
Where,
Upon comparing the permeability of coal samples before and after ScCO2 treatment, it is evident that the permeability of samples B and D increased after CO2 treatment. The permeability of sample B increased from 0.226 mD to 0.269 mD at 3 MPa effective stress with the growth rate of 19.09%. Similarly, the permeability of sample D increased from 0.144 mD to 0.178 mD at 3 MPa effective stress with a growth rate of 23.81%. The physical-chemical reactions of ScCO2 on the minerals of coal samples such as dissolution and extraction resulted in the widening of pores and fractures and improved pore connectivity, leading to an increase of permeability (Zhang G. et al., 2019). Moreover, the permeability of sample B increased from 0.040 mD to 0.118 mD at 10 MPa effective stress with a growth rate of 191.53%, and sample D’s permeability increased from 0.028 mD to 0.093 mD with a growth rate of 231.71%. The
Additionally, Figure 4 shows that the permeability of sample C decreases after ScCO2 treatment. There are two possible reasons for the phenomenon. Firstly, the in situ stress conditions may have caused the collapse of the pores in the coal samples, leading to the blockage of seepage channels despite the modification of pore fissures by ScCO2. Secondly, ScCO2 treatment may have caused the generation of new mineral precipitations in sample C, which could have blocked the pore channels and had a negative impact on the permeability.
3.2 Pore characteristics
Coal is a naturally occurring organic rock with a dual pore structure that is influenced by various factors such as the freeze-thaw effect, effective stress and the action of ScCO2 (Huang et al., 2017; Li et al., 2020; Chen et al., 2022). The pore structure is considered to be the most significant factor affecting the efficiency of ECBM and the stability of CGS (Wang et al., 2015; Zhang et al., 2020). The strong interaction of ScCO2-H2O and coal results in significant changes in the pore structure (Pan et al., 2018). The low temperature liquid nitrogen adsorption tests were conducted on coal samples before and after ScCO2 treatment to investigate the effect of ScCO2 on the pore characteristics of water-bearing coal samples. The adsorption and desorption capacity at different relative pressures were measured, and important parameters such as adsorption-desorption isotherms, pore size distribution, pore volume, specific surface area, and average pore size were calculated (Yi et al., 2012; Ni et al., 2020; Liu et al., 2022).
Experiments were conducted on both the original coal (sample A) and the ScCO2-treated coal (samples B, C and D), and the resulting adsorption-desorption curves are displayed in Figure 5. The curves demonstrate varying trends, which can be classified into two types based on their morphological characteristics as defined in this paper.
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FIGURE 5. Low temperature liquid nitrogen adsorption-desorption curve. (A) sample A, (B) sample B, (C) sample C, (D) sample D.
Type A is characterized by a sharp decrease in the desorption branch at the relative pressure of 0.9–1.0, followed by a slow decrease as the relative pressure decreases. Then there is a certain decreasing inflection point at the relative pressure of about 0.5. When the relative pressure is below 0.1, the adsorption and desorption branches are not closed, and the distance between them is relatively small (Figures 5A, B, D). This type is caused by the existence of permeable pores with open ends and ink bottle type pores in the coal samples.
Similar to Type A, type B is characterized by a sharp decrease in the desorption branch at the relative pressure of 0.9–1.0, followed by a slow decrease as the relative pressure decreases. Then there is a certain inflection point at the relative pressure of about 0.5. When the relative pressure is below 0.1, the adsorption and desorption branches are not completely closed, and the distance between them is relatively large (Figure 5C). This type is caused by the development of pore narrow crevice pores, ink bottle pores, and permeable pores with open ends of the coal samples.
Based on Kelvin’s capillary coalescence theory, we used the BJH pore size analysis model to analyze the pores in the paper, which is widely accepted (Hu et al., 2021). The pore size distribution of the coal samples was plotted with BJH pore size (W) as the horizontal coordinate and the differential of pore volume to pore size (dV/dW) as the vertical coordinate, as shown in Figure 6.
The pore size distribution curves of the four coal samples in Figure 6 show similar trends that most pores falling within the 1–10 nm size range, and two main peaks observed between 2–5 nm and 5–8 nm. Additionally, there are several small peaks in the 10 nm range for three of the coal samples. As can be seen from Figure 6, the pore sizes of samples B and D tend to increase, while the pore sizes of sample C tend to decrease. Coal pore sizes can generally be categorized into adsorption pores (<100 nm) and seepage pores (>100 nm) (Mou et al., 2021). And the adsorption pores can be divided into coagulation-adsorption pores (10–100 nm) and absorption pores (<10 nm) further (Ni et al., 2020). The results in Figure 6 indicate that the pore size distribution of coal samples changed significantly after ScCO2 treatment. Consequently, the volumes of adsorption pores and coagulation-adsorption pores for each of the four coal samples were calculated and are shown in Figure 7.
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FIGURE 7. Adsorption pore volume of coal samples. (A) Adsorption pores, (B) Coalescence-adsorption pores.
As depicted in Figure 7, the pore volumes of the four coal samples display distinct changes. Samples B and D show a decrease in the adsorption pore volumes, while sample C exhibits an increase. Conversely, the volumes of the coalescence-adsorption pore of samples B and D increase, while sample C shows a decrease. These findings indicate that the pores of coal samples undergo transformations after ScCO2 treatment, where the pore size of samples B and D increases while the pore size of sample C decreases. Based on the changes in pore size, the samples can be categorized as either pore broadening type (samples B, D) or pore shrinkage type (sample C). The trend in pore changes in coal samples is consistent with the permeability changes discussed earlier. The BJH pore size analysis model was employed to determine the average pore size, pore volume, and specific surface area of the four coal samples. The specific parameters are presented in Figure 8.
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FIGURE 8. Pore parameters of coal samples. (A) BET surface area, (B) Pore volume, (C) Average diameter of pores.
Figure 8A shows that the specific surface area of samples B and D decreased after ScCO2 treatment compared to raw coal (sample A) before ScCO2 treatment. This is caused by the conversion of adsorption pores into seepage pores in coal samples, which is not conducive to gas adsorption. In contrast, the specific surface area of sample C increased after ScCO2 treatment, providing more space for CO2 adsorption and improving the stability of CO2 sequestration.
It is evident that the pore volumes of samples B, C, and D decreased to varying degrees in Figure 8B. The decrease in pore volumes of the three coal samples is caused by axial and radial stress compression during ScCO2 treatment. Then the transformation effect of ScCO2 on coal is enhanced as the water content increases, and the pore volume of coal samples is restored to a certain extent. Therefore, the pore volume of coal samples continuously increases as the water content increases.
Figure 8C illustrates that the average pore size of sample B increases, while the average pore size of samples C and D decreases. This trend is opposite to that of the specific surface area due to the fact that the small pores provide more specific surface area than large pores.
The results above indicate that ScCO2 promotes the development of seepage pores in dry and water saturated coal samples, leading to an increase in permeability and enhancement of CBM extraction efficiency. Furthermore, ScCO2 causes the transformation of macropores into micropores and small pores of the half-saturated coal samples, providing more space for CO2 adsorption and improving the capacity of CO2 sequestration.
3.3 Mineral composition
XRD tests were performed on the four coal samples. The resulting data were analyzed by Jade 6 software to determine the mineral composition of the different water-saturated coal samples, which is shown in Figure 9. The analysis reveals that the minerals present in the raw coal samples include 25.1% calcite (CaCO3), 20.0% dolomite (CaMg (CO3)2), 15.1% quartz (SiO2), 2.3% pyrite (FeS2), and 37.5% clay minerals, with illite (K3Fe4Si14Al7O40(OH) 8) and kaolinite (Al2Si2O5(OH)4) accounting for 11.2% and 26.3% of the clay minerals, respectively.
As shown in Figure 9, the ScCO2 treatment resulted in a decrease in the content of carbonate minerals and an increase in the content of clay minerals in samples B, C, and D. This can be attributed to the strong dissolution reaction of carbonate minerals which are more sensitive to acidic environments (Zhang K. et al., 2019; Fatah et al., 2021; Ozotta et al., 2021). Although clay minerals can also be dissolved, the reaction rate is relatively slow, leading to an increase in their content. Specifically, the dolomite in sample B was violently dissolved, while calcite was slowly dissolved, resulting in a relatively higher content of the remaining minerals. Similarly, the violent dissolution of calcite led to a relatively higher content of other minerals in sample D. The reaction above promoted the expansion of pores in samples B and D and improved the connectivity of pores. Therefore, their adsorption pores decrease and permeability increases.
Notably, the content of dolomite in sample C decreased significantly, while the content of calcite increased. This can be explained by the fact that the water in sample C reduced the pH value of the solution compared to sample D, intensifying the dissolution of dolomite. However, the large amount of Ca2+ and Mg2+ generated by the dolomite reaction could not be completely dissolved by the water in coal sample C. Moreover, the solubility of Ca2+ is lower than that of Mg2+, causing Ca2+ to combine with CO32- to precipitate as new calcite and increase the relative content of calcite. Moreover, a large amount of newly formed calcite precipitates in key seepage channels such as pore throats, dividing the original pores, resulting in an increase in BET specific surface area and a decrease in permeability.
3.4 Reaction mechanism
The combination of ScCO2 and water generates H2CO3, which has strong extraction and corrosion effects on coal. Consequently, the microstructure of coal samples with different water saturation changes drastically after ScCO2 treatment, leading to changes of permeability. The transformation mechanism is illustrated in Figure 10.
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FIGURE 10. Reaction mechanism. (A) Before ScCO2 treatment, (B) After ScCO2 treatment, (C) Semi-saturated coal sample.
There is a series of geochemical reactions minerals in coal after ScCO2 injection, and the specific reactions are as follows (Wang Z. et al., 2021; Ozotta et al., 2021):
Dolomite in the coal samples undergoes significant dissolution after ScCO2 treatment, while the dissolution rate of clay minerals is relatively slow, resulting in an increased content of clay minerals. The content of quartz increases as the water saturation increases, although it does not undergo any significant reaction. This can be attributed to two reasons: (1) the dissolution of clay minerals produces new quartz minerals; (2) the violent dissolution of carbonate minerals leads to the relative increase in the content of quartz due to a decrease in the content of carbonate minerals.
In Figure 10B, it can be observed that the injection of ScCO2 results in significant dissolution of carbonate minerals in samples B and D. This dissolution widens the original pores and fractures, transforms the micropores into macropores, and improves the connectivity of seepage channels, thus enhancing the permeability of the coal samples. The formation of H2CO3 due to the CO2-H2O reaction in sample D leads to a lower pH and faster dissolution rate of carbonate minerals. Additionally, the presence of sufficient water increases the solubility of Ca2+ and Mg2+ which promotes the reaction progress and increases the connectivity of seepage pores further (Jiang et al., 2019). Therefore, the permeability growth of sample D is higher after ScCO2 treatment comparing to sample B. However, this reaction also results in a reduction of initial adsorption pores and BET specific surface area, which is negative for CO2 adsorption and stable storage.
In Figure 10C, it is shown that the dissolution of dolomite in sample C results in a substantial increase in Ca2+ and Mg2+. However, the water in the sample C is unable to dissolve these ions completely comparing to sample D. As a result, the Ca2+ combines with CO32− in the solution, leading to the precipitation of calcite. The newly formed calcite aggregates in the original seepage channels and pore throats, obstructing the seepage channels and reducing the size of the original macropores. This leads to a decrease in the pore size and an increase in the specific BET surface area of the coal samples. Consequently, the permeability of sample C decreases. However, the increased BET specific surface area provides more sites for CO2 adsorption.
The fractures in coal samples are closed at high stress conditions, and the permeability is controlled by the seepage pores. However, the contact area between the ScCO2 and pores surface is greater comparing to fractures, and the reaction is more efficient, resulting in better transformation effects. Therefore, the seepage growth of coal samples at high stress conditions is higher.
4 Conclusion
The ScCO2-H2O reaction experiments on coal samples with varying water saturation levels at in situ stress were conducted. Then the seepage tests, low temperature liquid nitrogen adsorption tests, and XRD tests was conducted to analyze the changes of the samples before and after treatment. The key findings are summarized below:
(1) ScCO2 treatment significantly increases the permeability of both dry and water saturated coal samples at in situ stress conditions, which is more effective for water saturated coal samples. The growth rates of permeability as the effective stress increases due to the improved pore transformation. However, the permeability of semi-saturated coal samples decreases after ScCO2 treatment due to the effects of stress compression and seepage channel blockage caused by new mineral precipitation.
(2) The low temperature liquid nitrogen adsorption tests revealed that ScCO2 treatment effectively increased the pore size of dry and water saturated coal samples. And the pore volume of coal samples increases as the moisture content increases. However, ScCO2 treatment significantly increased the size of adsorption pores in semi-saturated coal samples, which provided more space for CO2 adsorption.
(3) XRD analysis showed that ScCO2 treatment makes the carbonate mineral content decrease and silicate minerals content increase in coal samples, which facilitated pore connectivity. Although the dissolution of dolomite increased the pore size of semi-saturated coal samples, the newly formed calcite and quartz clogged the pore throats and divided the pores, leading to a reduction in seepage pores.
(4) The experimental and analytical results show that the reaction mechanism of coal samples with different moisture content after ScCO2 injection is different. ScCO2 effectively improves the pore connectivity of dry and water saturated coal samples. This effect is even greater for saturated coal samples. Although the pores of semi saturated coal samples have been expanded after ScCO2 treatment, the newly formed minerals such as quartz and calcite have a negative impact on pore connectivity and permeability.
The study compared the changes of mineral composition, pore structure, and permeability of coal samples with different water saturations before and after ScCO2 treatment, and the change mechanism of bituminous coal with different water saturations was analyzed, which is significant for CGS and ECBM. However, the explanation for the change of semi-saturated bituminous coal after ScCO2 treatment is still unclear. Therefore, it is necessary to further analyze the change rules and mechanisms of bituminous coal with different moisture content under the action of ScCO2 in detail.
Data availability statement
The original contributions presented in the study are included in the article/supplementary material, further inquiries can be directed to the corresponding authors.
Author contributions
CL, JZ, and SH conceived and designed the experiments; CL performed the experiments; CL analyzed the data; CL and JZ contributed materials and analysis tools; CL and JZ wrote the paper. SH reviewed and edited.
Funding
The authors acknowledge fundings by National Natural Science Foundation of China (No. 42202155), China Postdoctoral Science Foundation (No. 2021MD703807), Heilongjiang Provincial Postdoctoral Science Foundation (No. LBH-Z20121).
Acknowledgments
We thank Chongqing University and Northeast Petroleum University for the financial support to this study.
Conflict of interest
The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.
Publisher’s note
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Keywords: bituminous coal, in situ stress, supercritical CO2, seepage characteristics, pore characteristics, mineral composition
Citation: Li C, Zheng J and Huang S (2023) The effects of supercritical CO2 on the seepage characteristics and microstructure of water-bearing bituminous coal at in-situ stress conditions. Front. Earth Sci. 11:1188302. doi: 10.3389/feart.2023.1188302
Received: 17 March 2023; Accepted: 03 April 2023;
Published: 13 April 2023.
Edited by:
Peng Tan, CNPC Engineering Technology R&D Company Limited, ChinaReviewed by:
Wang Zepeng, Henan Polytechnic University, ChinaJianghui Ding, CNPC Engineering Technology R&D Company Limited, China
Copyright © 2023 Li, Zheng and Huang. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
*Correspondence: Jingwei Zheng, zhengjingwei@cqu.edu.cn; Saipeng Huang, huangspcugb@hotmail.com