Effective and realistic sequestration of Sr 2+ and B 3+ ions from the aqueous environments using coral reefs based Ca-MCM-41: Gulf of Suez as case study

Alshaima Sayed ¹ Ahmed M. El-Sherbeeny ² Gouda Ismail Abdel-Gawad ¹ Essam A. Mohamed ¹ Mostafa R. Abukhadra ³ Mostafa R. Abukhadra ^1*

• ¹ Beni-Suef University, Beni-Suef, Egypt
• ² King Saud University, Riyadh, Riyadh, Saudi Arabia
• ³ Yeungnam University, Gyeongsan, North Gyeongsang, Republic of Korea

A mesoporous calcium-bearing siliceous framework (Ca-MCM-41) was synthesized using natural coral reef carbonate rocks as precursors. The structural characterization, confirmed through XRD, SEM, FT-IR, and BET analyses, validated the formation of the MCM-41 framework with well-defined mesoporous properties and a high surface area of 159.6 m²/g. The developed Ca-MCM-41 was evaluated as a potential adsorbent for the removal of Sr²⁺ and B³⁺ ions from both aqueous solutions and real seawater samples collected from the Gulf of Suez, Egypt. The adsorption capacity at saturation reached 285.9 mg/g for Sr²⁺ and 86.1 mg/g for B³⁺, demonstrating the framework's high affinity for these contaminants. The adsorption mechanisms were elucidated using steric and energetic parameters, as derived from statistical physics-based isotherm models.The Ca-MCM-41 framework exhibited a higher active site density (148.9 mg/g) for Sr²⁺ compared to B³⁺ (54.8 mg/g), explaining its superior sequestration performance for strontium ions. Each receptor site was capable of accommodating up to three Sr²⁺ ions and two B³⁺ ions, indicating a multi-ionic interaction process and preferential vertical alignment during adsorption. Energetic analysis revealed that the sequestration process occurred via physical adsorption with interaction energies below 7 kJ/mol, alongside exothermic and spontaneous behavior, as evidenced by calculated internal energy, entropy, and enthalpy values. The developed Ca-MCM-41 structure demonstrated notable efficiency in real seawater applications, achieving sequestration percentages of 80% for Sr²⁺ and 64% for B³⁺, considering their average concentrations (24.2 mg/L for Sr²⁺ and 12.85 mg/L for B³⁺) in a 1-liter volume. These findings highlight the high potential of Ca-MCM-41 as an effective and sustainable adsorbent for Sr²⁺ and B³⁺ removal in environmental water treatment applications.