AUTHOR=Hoffmann Norbert , Gomez Fernandez Mario Andrés , Desvals Arthur , Lefebvre Corentin , Michelin Clément , Latrache Mohammed TITLE=Photochemical reactions of biomass derived platform chemicals JOURNAL=Frontiers in Chemistry VOLUME=12 YEAR=2024 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2024.1485354 DOI=10.3389/fchem.2024.1485354 ISSN=2296-2646 ABSTRACT=

Platform chemicals obtained from biomass will play an important role in chemical industry. Already existing compounds or not yet established chemicals are produced from this renewable feedstock. Using photochemical reactions as sustainable method for the conversion of matter furthermore permits to develop processes that are interesting from the ecological and economical point of view. Furans or levoglucosenone are thus obtained from carbohydrate containing biomass. Photochemical rearrangements, photooxygenation reactions or photocatalytic radical reactions can be carried out with such compounds. Also, sugars such pentoses or hexoses can be more easily transformed into heterocyclic target compounds when such photochemical reactions are used. Lignin is an important source for aromatic compounds such as vanillin. Photocycloaddition of these compounds with alkenes or the use light supported multicomponent reactions yield interesting target molecules. Dyes, surfactants or compounds possessing a high degree of molecular diversity and complexity have been synthesized with photochemical key steps. Alkenes as platform chemicals are also produced by fermentation processes, for example, with cyanobacteria using biological photosynthesis. Such alkenes as well as terpenes may further be transformed in photochemical reactions yielding, for example, precursors of jet fuels.