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ORIGINAL RESEARCH article

Front. Chem.
Sec. Electrochemistry
Volume 12 - 2024 | doi: 10.3389/fchem.2024.1469520
This article is part of the Research Topic Energy and Environmental Sustainability through Electrochemistry in South Korea View all 3 articles

Stepwise emergence of CO gas sensing response and selectivity on SnO2 using C supports and PtOx decoration

Provisionally accepted
Yong Hwan Kim Yong Hwan Kim 1Seung Yong Lee Seung Yong Lee 1Yunseong Ji Yunseong Ji 1Jeong Ho Lee Jeong Ho Lee 1Daewoo Kim Daewoo Kim 1Byeongdeok Lee Byeongdeok Lee 2Changhyun Jin Changhyun Jin 1*Kyu Hyoung Lee Kyu Hyoung Lee 1,3
  • 1 Yonsei University, Seoul, Republic of Korea
  • 2 Institute for Advanced Engineering, Yongin-si, Republic of Korea
  • 3 Yonsei-KIST Convergence Research Institute, Seoul, Republic of Korea

The final, formatted version of the article will be published soon.

    Room temperature gas sensing is crucial for practical devices used in indoor environments. Among various materials, metal oxides are commonly used for gas sensing, but their strong insulating properties limit their effectiveness at room temperature. To address this issue, many studies have explored diverse methods such as nanoparticle decoration or conductive support, etc. Here, we report the emergence of gas-sensing functionality at room temperature with improved CO gas selectivity on SnO2 nanoparticles through sequential steps by using amorphous carbon (a-C) support and PtOx decoration. The SnO2 decorated on amorphous carbon shows enhanced gas adsorption compared to inactive gas sensing on SnO2 decorated carbon support. The higher Vo site of SnO2 on a-C induces gas adsorption sites, which are related to the higher sp 2 bonding caused by the large density of C defects. The ambiguous gas selectivity of SnO2/a-C is tailored by PtOx decoration, which exhibits 6 values of sensing responses (Rg/Ra or Ra/Rg) under CO gas at room temperature with higher selectivity. Compared to PtOx/a-C, which shows no response, the enhanced CO gas sensing functionality is attributed to the CO adsorption site on PtOx-decorated SnO2 particles. This report not only demonstrates the applicability of CO gas sensing at room temperature but also suggests a strategy for using SnO2 and carbon compositions in gas sensing devices.

    Keywords: SnO2, Gas sensor, CO gases, room temperature, Nanocomposites

    Received: 24 Jul 2024; Accepted: 13 Sep 2024.

    Copyright: © 2024 Kim, Lee, Ji, Lee, Kim, Lee, Jin and Lee. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) or licensor are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

    * Correspondence: Changhyun Jin, Yonsei University, Seoul, Republic of Korea

    Disclaimer: All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article or claim that may be made by its manufacturer is not guaranteed or endorsed by the publisher.