AUTHOR=Eswara Rao C. V. V. , Janardan Sannapaneni , Manjunatha H. , Venkata Ratnam K. , Kumar Sandeesh , Chandrababu Naidu K. , Ranjan Shivendu TITLE=Synthesis and electrochemical studies of NaCoPO4 as an efficient cathode material using natural deep eutectic solvents for aqueous rechargeable sodium-ion batteries JOURNAL=Frontiers in Chemistry VOLUME=12 YEAR=2024 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2024.1440639 DOI=10.3389/fchem.2024.1440639 ISSN=2296-2646 ABSTRACT=

In this work, sodium cobalt phosphate (NaCoPO4) was successfully prepared by a cost-effective ionothermal method using a deep eutectic solvent (DES) for the first time. The synthesized NaCoPO4 was used to fabricate a cathode material for aqueous rechargeable sodium-ion batteries. The surface morphology of the prepared materials and its compositional analysis were done by using field emission scanning electron microscopy (FESEM) and energy-dispersive X-ray (EDX) analysis, respectively. The X-ray diffraction (XRD), SEM, and EDX studies revealed that the material has orthorhombic-shaped particle morphology with uniform distribution and is in nanoscale (approximately 50 nm). The nature of the cation inserted (Na+ ion insertion) was confirmed by recording CV profiles at different concentrations of the Na2SO4 electrolyte. The reversibility of the electrode redox reaction was studied by varying the scan rate in CV studies, and it was found that the electrode exhibits a reversible behavior with a resistive behavior. In GCPL studies, the cell TiO2/2MNa2SO4/NaCoPO4 showed significant reversibility with a prominent discharge capacity of 85 mAh g−1 at 0.1°C and 88% of capacity retention after 100 cycles. Thus, the prepared materials could be used as an effective futuristic alternative battery material for rechargeable batteries.