AUTHOR=Cao Yan , Taghvaie Nakhjiri Ali , Ghadiri Mahdi 

TITLE=Breakthrough applications of porous organic materials for membrane-based CO2 separation: a review

JOURNAL=Frontiers in Chemistry

VOLUME=12

YEAR=2024

URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2024.1381898

DOI=10.3389/fchem.2024.1381898

ISSN=2296-2646

ABSTRACT=<p>Over the last decades, porous organic materials (POMs) have been extensively employed in various industrial approaches including gas separation, catalysis and energy production due to possessing indisputable advantages like great surface area, high permeability, controllable pore size, appropriate functionalization and excellent processability compared to traditional substances like zeolites, Alumina and polymers. This review presents the recent breakthroughs in the multifunctional POMs for potential use in the membrane-based CO<sub>2</sub> separation. Some examples of highly-selective membranes using multifunctional POMs are described. Moreover, various classifications of POMs following with their advantages and disadvantages in CO<sub>2</sub> separation processes are explained. Apart from reviewing the state-of-the-art POMs in CO<sub>2</sub> separation, the challenges/limitations of POMs with tailored structures for reasonable application are discussed.</p>