Hongguo Wu
Hu Li
Yaqiong Su
Song Yang- 1National Key Laboratory of Green Pesticide, Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, State-Local Joint Laboratory for Comprehensive Utilization of Biomass, Center for R&D of Fine Chemicals, College of Pharmacy, Guizhou University, Guiyang, Guizhou, China
- 2School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Materials Chemistry, State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an, China
Editorial on the Research Topic
Sustainable catalytic production of bio-based heteroatom-containing compounds Volume III
Heteroatom-containing compounds are core scaffolds in a variety of medicines, and important building blocks for the synthesis of fine chemicals (Li et al., 2016; Meng et al., 2022; Wang et al., 2023a). As a promising alternative to fossil fuels, biomass sources rich in oxygen species can be used as versatile feedstocks for producing both biofuels and task-specific molecules (Li et al., 2018; Wang et al., 2023b; Huang et al., 2023; Meng et al., 2023). For the sustainable conversion processes developed for biomass upgrading, the used catalytic pathways and strategies are key to regulating product distribution. Also, increasing attention has been paid to investigating the reaction mechanisms using advanced or in situ characterization techniques and theoretical calculations. Moreover, environmental and energy issues (e.g., the greenhouse effect and energy depletion) encountered in the conventional use of fossil resources have arisen more concerns in the exploration of renewable biomass and waste CO2 for the manufacture of carbon-based functional materials/substances employing well-tailored catalysts or catalytic systems.
This Research Topic is Volume III of a series, and here we present a Research Topic of original research and review articles (12 papers in total) with topics on green and sustainable chemistry, including catalytic production of biodiesel (Zhang et al., and Pan et al.), catalytic upgrading of biomass derivatives (Wang et al., Li et al., Zheng et al., and Huang et al.), selective hydrogenation of CO2 to CH4 (Xiang et al.), bioactive assessment of natural products (Qu et al.), and environmental issues involved in the biomass utilization processes (Liu et al., Yang et al., Yang et al., and Yang et al.).
A research paper by Wang et al. reports the preparation of Pt-WOx catalysts supported on TiO2 with different crystal forms and WOx loadings for catalytic performance in the hydrogenolysis of glycerol to 1,3-propanediol. The anatase-type TiO2-supported catalyst (Pt/W/A-Ti) with higher stability shows superior catalytic performance to the rutile-type TiO2 catalyst (Pt/W/R-Ti). Also, the catalytic mechanisms are investigated by in situ characterization techniques, manifesting that glycerol is first transformed into 3-hydroxypropanal over Pt/W/A-Ti, followed by succeeding conversion steps to give 1,3-propanediol. Xiang et al. detailedly study the formation process of methane (up to 100% selectivity) from catalytic hydrogenation of CO2 at 280°C over a Ni-based ETS-10 zeolite catalyst, which is prepared by in situ doping and impregnation. Intensive characterizations and measurements are conducted to get insights into the catalyst promotional mechanisms, with attention to the impact of different Ni incorporation methods on the catalyst stability. In addition, the antifungal activities of the Allium mongolicum Regel leaf (Qu et al.), and the health risks of heavy metals in soils and food crops (Liu et al.) are assessed, as well.
This Research Topic also features several Mini reviews with varying scopes (Zhang et al., Pan et al., Li et al., Zheng et al., Huang et al., Yang et al., Yang et al., and Yang et al.). Zhang et al. summarize recent advances in the development of magnetic catalytic materials for producing biodiesel, with a focus on the catalyst physicochemical properties, performance, and recyclability. The involved catalytic mechanisms and reaction conditions in biodiesel production are discussed, and attention is also paid to the limitations and challenges for future research. Viewing that ionic liquid-functionalized materials have the unique characteristics of both homogeneous and heterogeneous catalysts, they are recently considered as one of the promising alternatives to conventional homogeneous acid/base catalysts for biodiesel production. Accordingly, a review on the topic of developing supported acid/base ionic liquids as heterogeneous catalysts for producing biodiesel is presented (Pan et al.). The merits and demerits of various supports (e.g., mesoporous silica, porous polymers, carbonaceous materials, metal-organic frameworks, and ferromagnetic materials) in biodiesel production are collected, and their performance in immobilization of ionic liquids is compared, with emphasis on the developed methods effective for immobilizing ionic liquids onto solid supports to prepare the functional ionic liquids. The ionic liquid-based solid catalysts are also reported to be efficient for the pretreatment of lignocellulosic biomass, and the obtained cellulose and hemicellulose components can be further converted to 5-hydroxymethylfurfural in the presence of the tailored acidic ionic liquids (Li et al.).
Instead of chemocatalysis, Zheng et al. make a brief introduction to the classification, source and application of alginate lyases in the biocatalytic degradation of carbohydrates, which primarily concentrates on screening of strains, mining of genes, and analysis of degradation substrate and product structure. In addition to the comprehensive utilization of saccharides, Huang et al. introduce the development of a variety of anodes (e.g., Pt, Pb, Ir, Ni, and Co) for electro-oxidative degradation of lignin, with emphasis on the product distribution caused by different electrodes, as well as the involved reaction pathways and catalytic mechanisms. For the construction of ecological civilization and the goal of carbon peak and carbon neutralization, several reviews regarding carbon effect calculation and upgrading strategy (Yang et al.), improvement of rural soil properties and states by biomass carbon (Yang et al.), and rural resilience research from the perspective of the ecosystem (Yang et al.) are also showcased.
We wish this Research Topic enlightens more sustainable and eco-friendly conversion pathways, sheds light on reaction mechanisms, and develops novel catalytic strategies for producing biofuels and high-value chemicals. Enjoy its reading!
Author contributions
All authors listed have made a substantial, direct, and intellectual contribution to the work and approved it for publication.
Acknowledgments
HL thanks financial support of the Guizhou Provincial S&T Project [ZK(2022)011].
Conflict of interest
The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.
Publisher’s note
All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.
References
Huang, J., Wang, J., Huang, Z., Liu, T., and Li, H. (2023). Photothermal technique-enabled ambient production of microalgae biodiesel: Mechanism and life cycle assessment. Bioresour. Technol. 369, 128390. doi:10.1016/j.biortech.2022.128390
Li, H., Fang, Z., Smith, R. L., and Yang, S. (2016). Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials. Prog. Energy Combust. Sci. 55, 98–194. doi:10.1016/j.pecs.2016.04.004
Li, H., Riisager, A., Saravanamurugan, S., Pandey, A., Sangwan, R. S., Yang, S., et al. (2018). Carbon-increasing catalytic strategies for upgrading biomass into energy-intensive fuels and chemicals. ACS Catal. 8, 148–187. doi:10.1021/acscatal.7b02577
Meng, Y., Jian, Y., Li, J., Wu, H., Zhang, H., Saravanamurugan, S., et al. (2023). Surface-active site engineering: Synergy of photo- and supermolecular catalysis in hydrogen transfer enables biomass upgrading and H2 evolution. Chem. Eng. J. 452, 139477. doi:10.1016/j.cej.2022.139477
Meng, Y., Yang, S., and Li, H. (2022). Electro- and photocatalytic oxidative upgrading of biobased 5-hydroxymethylfurfural. ChemSusChem 15, e202102581. doi:10.1002/cssc.202102581
Wang, B., Li, M., Zhang, S., Wu, H., Liao, Y., and Li, H. (2023a). Synergistic effect between Co single atoms and nanoparticles enables selective synthesis of bio-based benzimidazoles. Appl. Catal. B Environ. 327, 122454. doi:10.1016/j.apcatb.2023.122454
Keywords: green chemistry, biomass and biofuels, heterogeneous catalysis, waste valorization, biological activity
Citation: Wu H, Li H, Su Y and Yang S (2023) Editorial: Sustainable catalytic production of bio-based heteroatom-containing compounds Volume III. Front. Chem. 11:1210932. doi: 10.3389/fchem.2023.1210932
Received: 23 April 2023; Accepted: 24 April 2023;
Published: 02 May 2023.
Edited and reviewed by:
James Clark, University of York, United KingdomCopyright © 2023 Wu, Li, Su and Yang. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
*Correspondence: Hu Li, aGxpMTNAZ3p1LmVkdS5jbg==; Song Yang, amh6eC5tc21AZ21haWwuY29t