AUTHOR=Zhang Xin , Huang Gun , Shu Zhile , Tong Yao TITLE=Study on key influencing factors of competitive adsorption of coalbed methane by carbon dioxide displacement JOURNAL=Frontiers in Chemistry VOLUME=10 YEAR=2022 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2022.998592 DOI=10.3389/fchem.2022.998592 ISSN=2296-2646 ABSTRACT=

The extraction of coal bed methane (CBM) by injecting CO2 into deeply buried unmined coal seams in competition with CH4 adsorption to provide a clean fuel is known as enhanced coal bed methane recovery (ECBM) and has proven to be an effective technological strategy to address global warming. The study of the interaction of coal with CO2 and CH4 under multi-physical field conditions is particularly necessary. In this work, a series of experiments were conducted on a home-made test system to investigate the competing sorption patterns of high and medium ash coal samples subjected to variables such as gas pressure, temperature, nodulation and lateral limit constraints. The results show that there is a sorption isotherm relationship between coal samples and exposure time. The adsorption capacity sorption of CH4/CO2 varied considerably for different ash coal samples. As the CO2 pressure increased from 2.3 to 5.5 MPa, the strain on the coal samples increased from 0.082 to 0.4%. The deformation in the vertical laminae direction is always greater than that in the parallel laminae direction. A correlation coefficient K exists between 1 and 2, and there is an internal expansion pattern in the adsorption deformation of coal. This paper can contribute to the improvement of ECBM efficiency.