A novel approach based on the ultrasonic-assisted microwave method for the efficient synthesis of Sc-MOF@SiO2 core/shell nanostructures for H2S gas adsorption: A controllable systematic study for a green future

In this work, for the first time, novel Sc-MOF@SiO₂ core/shell nanostructures have been synthesized under the optimal conditions of ultrasonic-assisted microwave routes. The final products showed small particle size distributions with homogeneous morphology (SEM results), high thermal stability (TG curve), high surface area (BET adsorption/desorption techniques), and significant porosity (BJH method). The final nanostructures of Sc-MOF@SiO₂ core/shell with such distinct properties were used as a new compound for H₂S adsorption. It was used with the systematic investigation based on a 2^K−1 factorial design, which showed high-performance adsorption of about 5 mmol/g for these novel adsorbents; the optimal experimental conditions included pressure, 1.5 bar; contact time, 20 min; and temperature, 20°C. This study and its results promise a green future for the potential control of gas pollutants.

1 Introduction

Recently, the applications of metal-organic frameworks (MOFs) have received special attention due to their desirable properties (O'Neill et al., 2010; Yang et al., 2021; Chen et al., 2022). These compounds, which consist of various metals and linkers with their mechanical strength, thermal stability, and high specific surface, have many applications in industry, environment, and medicine (Ding et al., 2019; Wang and Astruc, 2019; Shyngys et al., 2021).

Due to the spread of air pollutants, controlling and reducing them is a necessity. Gaseous pollutants are an important group of pollutants that have affected the environment, humans, and other animals (Cesur et al., 2017). One of the most critical types of gaseous pollutants is sulfide gas, such as H₂S molecules. This compound, which has increased with population, has adverse environmental effects; therefore, small amounts are dangerous (Lantto and Mizsei, 1991).

Various methods for controlling and trapping gaseous pollutants have been studied, including catalytic processes, absorption, and adsorption procedures (Perera et al., 2012; Ma et al., 2018; Zhang et al., 2020). Adsorption is an inexpensive, controllable, simple, and green process that has been highlighted compared to other methods. Previous studies have also confirmed the importance of the adsorption procedure in comparison with other classical methods (Li et al., 2020). MOFs with desirable physicochemical properties are one of the novel candidates for the adsorption process (Krishna et al., 2011; Xi et al., 2022). These compounds have high surface area, significant porosity, and desirable mechanical features, which are attractive for the adsorption of various compounds (Krishna et al., 2010; Zhu et al., 2022). These novel crystalline compounds, which consist of metal nodes and organic ligands, have some structural flexibility and textural properties that make them a very effective class of compounds for potential adsorption processes.

On the other hand, the type of synthesis method also has a great effect on the amount of gas adsorption. MOFs are synthesized in a variety of ways, including ultrasonic, microwave, sol–gel, and co-precipitation methods (Rivera-Muñoz and Huirache-Acuña, 2010; Guo et al., 2022). The use of novel methods such as ultrasonic and microwave compared to conventional methods not only synthesizes samples in short time but also affects the physicochemical properties of the final compounds (Qiu et al., 2014; González et al., 2021).

One of the effective factors in increasing the functional efficiency of MOF nanostructures on gas adsorption is a systematic process study. Among the parameters affecting the efficiency of gas adsorption, temperature, time contact, and pressure are important factors (Alhamami et al., 2014; Guo et al., 2021). It is critical to systematically study the effect of these parameters on gas adsorption. The use of conventional systematic study increases the number of experiments significantly, which results in a long testing process (Pu et al., 2021). Recently, the use of a 2^k−1 factorial design has been considered for designing experiments, which results in the production of novel products with distinctive features (Yu and Sepehrnoori, 2014).

Although MOF nanostructures have distinct properties compared to other compounds, increasing their specific surface area for functional potential is a major challenge (Falcaro et al., 2014; Rubio-Martinez et al., 2017). Recently, the synthesis of core/shell nanostructures has been given special attention in order to increase the specific surface area and stability of the product (Liu and Tang, 2013; Liu et al., 2022). Silica is one of the stable substrates that in the form of a shell can affect the specific surface of the product (Kalambate et al., 2019).

In this study, for the first time, Sc-MOF@SiO₂ core/shell nanostructures were synthesized by combining Sc-MOF nanostructures and SiO₂ shell powders, and their properties were characterized using scanning electron microscopy (SEM), energy-dispersive spectrometry (EDS) mapping analysis, Fourier transform-infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), and BET surface area technique. Finally, adsorption studies were developed systematically for H₂S gas adsorption with a 2^k−1 factorial design.

2 Materials and methods

2.1 Materials

Scandium 3) nitrate hexahydrate with MW of 248.99 g/mol and purity of 99.90 (Sigma-Aldrich, Steinheim, Germany), 2,6 pyridine dicarboxylic acid with MW of 167.12 g/mol and purity of 99.80% (Sigma-Aldrich, Steinheim, Germany), silicon dioxide substrate with MW of 60.08 g/mol and purity of 99.80% (Sigma-Aldrich, Steinheim, Germany), and H₂S capsule with purity of 98.98% (Sigma-Aldrich, Steinheim, Germany) were prepared without any purification. Deionized water obtained by the Millipore Milli-Q system (Darmstadt, Germany) was used in all experiments.

2.2 Characterization of the products

The particle size distribution and morphology of the products were determined using a scanning electron microscope (SEM) (EVO 10, Carl Zeiss AG, Jena, Germany). FTIR spectroscopy was performed on a Nicolet-6700 FTIR spectrometer with a wavenumber range of 400–4,100 cm⁻¹. TGA was measured using a Netzsch Thermoanalyzer STA 409 in an Ar atmosphere at a heating rate of 5°C/min. The BET surface areas of Sc-MOF@SiO2 core shell nanostructures were determined using a Micromeritics TriStar II 3020 analyzer.

2.3 Synthesis of Sc-MOF nanostructures

In a typical microwave-assisted synthesis, 0.0235 g of Sc (NO3)₃ (0.2 mmol) and 0.0722 g of pyridine-2,6 dicarboxylic acid were dissolved in 40 ml of double-distilled water, and the mixture was stirred for approximately 35 min at 70°C. Then, the resultant solutions were transferred to the microwave device and placed under optimal microwave radiation with a power of 300 W for 40 min at an ambient temperature.

2.4 Synthesis of Sc-MOF@SiO₂ core/shell nanostructures

The synthesis of Sc-MOF@SiO₂ core/shell nanostructures using the ultrasonic-assisted microwave method is as follows: the mixture obtained in the previous stage (2.3) was added to 0.453 mg of SiO₂ nanostructures. The compound is placed in the ultrasonic device with a frequency of 21 Hz and subjected to ultrasound irradiation with a power of 20 W for 40 min at a temperature of 33°C. After cooling to room temperature, the nanostructures were isolated by washing with distilled water.

3 Results and discussion

3.1 Characterization of nanostructures

3.1.1 Morphology and particle size distribution

The mean particle size distribution along with the morphology of Sc-MOF nanostructures and the Sc-MOF@SiO₂ core/shell nanostructures are shown in Figure 1A,B. Accordingly, the mean particle size distribution of the Sc-MOF was distributed in the nanometric range (diameter less than 100 nm). According to Figure 1B, the Sc-MOF nanoparticles are agglomerated in the core/shell network of the Sc-MOF@SiO₂ nanostructures with a uniform distribution. It can be seen that the morphology of Sc-MOF was slightly changed in the final structures, which can be related to the effects of ultrasonic-assisted microwave methods. In order to ensure the presence of the characteristic elements in the final structures, the EDS elemental with mapping analysis has been used, and, as seen in Figure 2, the related elements are displayed in the final product. As an important result, the synthesis of Sc-MOF@SiO₂ core/shell nanostructures by the ultrasonic-assisted microwave method was confirmed. Also, in order to ensure that the core and shell nanostructures are formed, TEM images of Sc-MOF@SiO₂ core/shell nanostructures were taken. As shown in Figure 1D, there is a clear distinction between the core (Sc-MOF) and shell (SiO₂) structures. As an important result, the formation of MOF@SiO₂ core/shell nanostructures with a homogeneous morphology improves the functional potential of these nanostructures in the field of gas adsorption.

FIGURE 1

FIGURE 1. SEM images (A) Sc-MOF and (B) Sc-MOF@SiO₂) with (C) EDS elemental analysis for core (Sc and C) and shell structures (Si) and (D)TEM image of Sc-MOF@SiO₂ core/shell nanostructures.

FIGURE 2

FIGURE 2. FTIR spectra of (A) SiO₂, (B) Sc-MOF, and (C) Sc-MOF@SiO₂ core/shell nanostructures.

3.1.2 Suggested structures

Figure 2 depicts the FTIR spectra of SiO₂ structures (A), Sc-MOF (B), and Sc-MOF@SiO₂ core/shell nanostructures (C). According to the FTIR spectra of Sc-MOF, the absorption peaks at 3,070 cm⁻¹ may be related to the coordinated solvent in the products. The peaks near 2,800 cm⁻¹ may be attributed to the aromatic CH groups. The strong bands at 1,360 and 1,490 cm⁻¹ correspond to the asymmetric and symmetric stretching peaks of COO groups, respectively (Rojas et al., 2014). The absorption bands at 800 cm⁻¹ are assigned to C–H bonds. For both SiO₂ and Sc-MOF nanostructures, the peaks near 2,500–1,500 cm⁻¹ can be attributed to the Si–O and Sc–O bonds, respectively (Han et al., 2015; Zhang et al., 2022). According to Figure 2C, the characteristic peaks of SiO₂ and Sc-MOF can be seen in the FTIR spectrum of Sc-MOF@SiO₂ core/shell nanostructures. Figure 3 shows the CHNS/O elemental analysis of Sc-MOF@SiO₂ core/shell nanostructures. According to this figure, the amounts of related elements of C, H, N, and O are distributed well. As an important result, based on the FTIR spectra of samples, different linker configurations (Watanabe et al., 2006; Deng et al., 2019), and also CHNS/O analysis, the suggested structures for Sc-MOF@SiO₂ core/shell nanostructures are shown in Figure 4.

FIGURE 3

FIGURE 3. CHNSO/analysis for Sc-MOF@SiO₂ core/shell nanostructures synthesized using the ultrasonic-assisted microwave method.

FIGURE 4

FIGURE 4. Suggested formula for Sc-MOF@SiO₂ core/shell nanostructures synthesized using the ultrasonic-assisted microwave method.

3.1.3 Thermal stability and surface area

The thermal stability of siO₂, Sc-MOF, and Sc-MOF@SiO₂ core/shell nanostructures is shown in Figure 5. By comparing these peaks, the Sc-MOF@SiO₂ core/shell nanostructures have a high thermal stability (328°C) compared to the SiO₂ nanoparticles (264°C) and Sc-MOF nanostructures (292°C). As an important result, the thermal stability of the Sc-MOF@SiO₂ core/shell nanostructures developed in this study is greatly increased compared to similar samples (Nazir et al., 2021; Zhao et al., 2021). This can be related to the choice of structure type and the ultrasonic-assisted microwave route. The high thermal stability can provide a significant possibility for the application of this compound in different areas, such as novel adsorption.

FIGURE 5

FIGURE 5. Thermal stability of (A): SiO₂ powder, (B): Sc-MOFs, and (C): Sc-MOF@SiO2 core/shell nanostructures.

The results of various analyses showed that the Sc-MOF@SiO₂ core–shell nanostructures have better physicochemical properties than pure Sc-MOF and SiO₂ powders. Therefore, these compounds were selected as new products for further applications. Figure 6 shows the adsorption/desorption isotherms of the Sc-MOF@SiO₂ core/shell nanostructures synthesized by the ultrasonic-assisted microwave method. Based on this isotherm, the adsorption/desorption behaviors of the samples are similar to the second series of classical isotherms, which confirms the mesoporous behavior (size distribution between 2 and 50 nm) for the final sample (Ebadi et al., 2009). Also, based on the BET results, Sc-MOF@SiO₂ core/shell nanostructures have a surface area of about 3,700 m²/g. In order to correlate between adsorption isotherms and particle size distributions, the BJH method has been used. As shown in Figure 7, the size of the pore distribution was more than 2 nm, which confirms the significant porosity of Sc-MOF@SiO₂ core/shell nanostructures with mesopore size distributions. As an important result, the synthesis of samples with high porosity provides the applicable potential for adsorption procedures.

FIGURE 6

FIGURE 6. N₂ adsorption/desorption isotherms of Sc-MOF@SiO2 core/shell nanostructures.

FIGURE 7

FIGURE 7. BJH pore size distribution for Sc-MOF@SiO₂ core shell nanostructures.

3.2 H₂S gas adsorption

3.2.1 Experimental design

Sc-MOF@SiO2 core/shell nanostructures have been selected as a new option for gas adsorption due to their desirable properties such as narrow particle size distribution, high thermal stability, remarkable surface area, and significant porosity. In order to measure the amount of H₂S gas adsorption by these novel nanostructures, a volumetric method has been used. This method was carried out based on previous studies (Roy et al., 2017). In order to systematically design the process and investigate the effective experimental parameters on H₂S adsorption, the 2^k−1 method has been used. Effective parameters included pressure (A), time contact (B), and temperature (C). The values of each of these parameters and the results of the H₂S gas adsorption are presented in Table 1. Also, the distributions of experiments with two repetitions are presented in Table 2.

TABLE 1

TABLE 1. 2^k−1 factorial design for H₂S gas adsorption studied by Sc-MOF@SiO2 core/shell nanostructures.

TABLE 2

TABLE 2. H₂S gas adsorption experiments under different conditions by Sc-MOF@SiO₂ core/shell nanostructures (design by 2^k−1 factorial).

3.2.2 Systematic study for H₂S gas adsorption

Figure 8 shows the residual plots for different distributions of the experiments in a 2^k−1 factorial design. Based on the results, there is no evidence of nonrandom distribution of experiments in all kinds of experiments. As an important result, the randomized distribution of H₂S gas adsorption was confirmed by a 2^k−1 experimental design.

FIGURE 8

FIGURE 8. Different residual plot for H₂S gas adsorption by Sc-MOF@SiO₂ core shell nanostructures.

The results of the analysis of variance for H₂S gas adsorption are shown in Table 3. Based on these results, the amount of P_value for all three factors (pressure, time contact, and temperature) is close to 0.000. This amount indicates the effective effect of experimental parameters on the efficiency of H₂S gas adsorption.

TABLE 3

TABLE 3. Analysis of variance for H₂S gas adsorption (coded units).

In fact, by increasing the contact time, the interaction between the adsorbent and H₂S gas molecules can be increased. As shown in condition b (Table 2), this amount to some extent affects the amount of gas adsorption, and then the efficiency of the sample may decrease (Li et al., 2009). As an important result, the Sc-MOF nanostructures (core) and SiO₂ powders (shell) may be agglomerated into each other if the contact time is high. To verify this, SEM images were taken of Sc-MOF@SiO₂ core shell nanostructures in condition b which, as it turns out, the particles tended to agglomerate (Figure 9) (Guo et al., 2020). This problem can affect the efficiency of the nanostructure (0.4 mmol/g H₂S gas adsorption in condition b compared to 5 mmol/g in optimal conditions). Other parameters affecting the rate of H₂S gas adsorption include temperature. As the temperature increases, the effective collision level increases, and this affects the performance of the Sc-MOF@SiO₂ core/shell nanostructures in H₂S gas adsorption (condition b). The effect of pressure on H₂S gas adsorption is also in accordance with previous studies (Xiao et al., 2009).

FIGURE 9

FIGURE 9. SEM images of Sc-MOF@SiO₂ core/shell nanostructures in condition b (Table 2).

The Pareto chart (Figure 10) also confirms the significant effects of experimental parameters (pressure, time contact, and temperature) on H₂S gas adsorption. This figure also shows the high efficiency of H₂S gas adsorption by the Sc-MOF@SiO₂ core/shell nanostructures. The results of the Pareto chart agree with the data obtained from the analysis of variance, which confirmed the significant effects of pressure, time contact, and temperature on CH₄ gas adsorption. The relationship between experimental parameters and gas absorption is very important. This relationship is schematically shown in Figure 11. As known, by selecting any of the values, the relevant answers can be obtained.

FIGURE 10

FIGURE 10. Pareto chart for different conditions of a 2^k−1 design in H₂S gas adsorption.

FIGURE 11

FIGURE 11. 3D surface plot for the relation between experimental parameters and H₂S gas adsorption.

4 Conclusion

In this study, for the first time, Sc-MOF@SiO₂ core/shell nanostructures were developed using novel ultrasonic-assisted microwave routes in mild conditions. These novel nanostructures showed distinctive properties such as high specific surface area (3,700 m²/g), significant porosity (more than 2 nm), narrow particle size distribution (less than 100 nm), and high thermal stability (328°C). The results of 2^K−1 factorial experimental designs showed that the Sc-MOF@SiO₂ core/shell nanostructures have an adsorption rate of 5 mmol/g in optimal conditions. It seems that the development of ultrasonic-assisted microwave routes and the introduction of new nanostructures with immobilization of Sc-MOF in the core–shell network may affect the functional efficiency of the Sc-MOF@SiO₂ core/shell products.

Data availability statement

The raw data supporting the conclusions of this article will be made available by the authors, without undue reservation.

Author contributions

All authors listed have made a substantial, direct, and intellectual contribution to the work and approved it for publication.

Conflict of interest

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Publisher’s note

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.

References

Alhamami, M., Doan, H., and Cheng, C.-H. (2014). A review on breathing behaviors of metal-organic-frameworks (MOFs) for gas adsorption. Materials 7, 3198–3250. doi:10.3390/ma7043198

PubMed Abstract | CrossRef Full Text | Google Scholar

Cesur, R., Tekin, E., and Ulker, A. (2017). Air pollution and infant mortality: Evidence from the expansion of natural gas infrastructure. Econ. J. 127, 330–362. doi:10.1111/ecoj.12285

CrossRef Full Text | Google Scholar

Chen, Z., He, X., Ge, J., Fan, G., Zhang, L., Parvez, A. M., et al. (2022). Controllable fabrication of nanofibrillated cellulose supported HKUST-1 hierarchically porous membranes for highly efficient removal of formaldehyde in air. Ind. Crops Prod. 186, 115269. doi:10.1016/j.indcrop.2022.115269

CrossRef Full Text | Google Scholar

Deng, W., Xu, K., Xiong, Z., Chaiwat, W., Wang, X., Su, S., et al. (2019). Evolution of aromatic structures during the low-temperature electrochemical upgrading of bio-oil. Energy fuels. 33, 11292–11301. doi:10.1021/acs.energyfuels.9b03099

CrossRef Full Text | Google Scholar

Ding, M., Cai, X., and Jiang, H.-L. (2019). Improving MOF stability: Approaches and applications. Chem. Sci. 10, 10209–10230. doi:10.1039/c9sc03916c

PubMed Abstract | CrossRef Full Text | Google Scholar

Ebadi, A., Mohammadzadeh, J. S. S., and Khudiev, A. (2009). What is the correct form of BET isotherm for modeling liquid phase adsorption? Adsorption 15, 65–73. doi:10.1007/s10450-009-9151-3

CrossRef Full Text | Google Scholar

Falcaro, P., Ricco, R., Doherty, C. M., Liang, K., Hill, A. J., and Styles, M. J. (2014). MOF positioning technology and device fabrication. Chem. Soc. Rev. 43, 5513–5560. doi:10.1039/c4cs00089g

PubMed Abstract | CrossRef Full Text | Google Scholar

González, C. M. O., Kharisov, B. I., Kharissova, O. V., and Quezada, T. E. S. (2021). Synthesis and applications of MOF-derived nanohybrids: A review. Mater. Today Proc. 46, 3018–3029. doi:10.1016/j.matpr.2020.12.1231

CrossRef Full Text | Google Scholar

Guo, C., Ye, C., Ding, Y., and Wang, P. (2020). A multi-state model for transmission system resilience enhancement against short-circuit faults caused by extreme weather events. IEEE Trans. Power Deliv. 36, 2374–2385. doi:10.1109/tpwrd.2020.3043938

CrossRef Full Text | Google Scholar

Guo, J., Gao, J., Xiao, C., Chen, L., and Qian, L. (2022). Mechanochemical reactions of GaN-Al2O3 interface at the nanoasperity contact: Roles of crystallographic polarity and ambient humidity. Friction 10, 1005–1018. doi:10.1007/s40544-021-0501-9

CrossRef Full Text | Google Scholar

Guo, J., Xiao, C., Gao, J., Li, G., Wu, H., Chen, L., et al. (2021). Interplay between counter-surface chemistry and mechanical activation in mechanochemical removal of N-faced GaN surface in humid ambient. Tribol. Int. 159, 107004. doi:10.1016/j.triboint.2021.107004

CrossRef Full Text | Google Scholar

Han, Y., Qi, P., Feng, X., Li, S., Fu, X., Li, H., et al. (2015). In situ growth of MOFs on the surface of Si nanoparticles for highly efficient lithium storage: Si@ MOF nanocomposites as anode materials for lithium-ion batteries. ACS Appl. Mat. Interfaces 7, 2178–2182. doi:10.1021/am5081937

PubMed Abstract | CrossRef Full Text | Google Scholar

Kalambate, P. K., Dhanjai, Z., Huang, Y., Li, Y., Shen, M., Xie, Y., et al. (2019). Core@ shell nanomaterials based sensing devices: A review. TrAC Trends Anal. Chem. 115, 147–161. doi:10.1016/j.trac.2019.04.002

CrossRef Full Text | Google Scholar

Krishna, C. R., Thampy, U. U., Sathish, D., Reddy, C. V., Chandrasekhar, A., Reddy, Y., et al. (2011). Synthesis and spectroscopic characterization of Mn(II) doped organic amine templated chlorocadmiumphosphate CdHPO4Cl · [H3N(CH2)6NH3]0.5crystals. J. Coord. Chem. 64, 4276–4285. doi:10.1080/00958972.2011.638376

CrossRef Full Text | Google Scholar

Krishna, C., Thampy, U., Reddy, Y., Rao, P., Yamauchi, J., and Ravikumar, R. (2010). Co (II) ion doped chlorocadmiumphosphate[MathML equation] crystals: A novel organically templated hybrid open-framework. Solid State Commun. 150, 1479.

Google Scholar

Lantto, V., and Mizsei, J. (1991). H2S monitoring as an air pollutant with silver-doped SnO2 thin-film sensors. Sensors Actuators B Chem. 5, 21–25. doi:10.1016/0925-4005(91)80214-5

CrossRef Full Text | Google Scholar

Li, J.-R., Kuppler, R. J., and Zhou, H.-C. (2009). Selective gas adsorption and separation in metal–organic frameworks. Chem. Soc. Rev. 38, 1477–1504. doi:10.1039/b802426j

PubMed Abstract | CrossRef Full Text | Google Scholar

Li, X., Zhang, L., Yang, Z., Wang, P., Yan, Y., and Ran, J. (2020). Adsorption materials for volatile organic compounds (VOCs) and the key factors for VOCs adsorption process: A review. Sep. Purif. Technol. 235, 116213. doi:10.1016/j.seppur.2019.116213

CrossRef Full Text | Google Scholar

Liu, Y., Li, B., Lei, X., Liu, S., Zhu, H., Ding, E., et al. (2022). Novel method for high-performance simultaneous removal of NO and SO2 by coupling yellow phosphorus emulsion with red mud. Chem. Eng. J. 428, 131991. doi:10.1016/j.cej.2021.131991

CrossRef Full Text | Google Scholar

Liu, Y., and Tang, Z. (2013). Multifunctional nanoparticle@MOF core-shell nanostructures. Adv. Mat. 25, 5819–5825. doi:10.1002/adma.201302781

PubMed Abstract | CrossRef Full Text | Google Scholar

Ma, S., Zhang, M., Nie, J., Yang, B., Song, S., and Lu, P. (2018). Multifunctional cellulose-based air filters with high loadings of metal-organic frameworks prepared by in situ growth method for gas adsorption and antibacterial applications. Cellulose 25, 5999–6010. doi:10.1007/s10570-018-1982-1

CrossRef Full Text | Google Scholar

Nazir, A., Le, H. T., Kasbe, A., and Park, C.-J. (2021). Si nanoparticles confined within a conductive 2D porous Cu-based metal–organic framework (Cu3 (HITP) 2) as potential anodes for high-capacity Li-ion batteries. Chem. Eng. J. 405, 126963. doi:10.1016/j.cej.2020.126963

CrossRef Full Text | Google Scholar

O'Neill, L. D., Zhang, H., and Bradshaw, D. (2010). Macro-/microporous MOF composite beads. J. Mat. Chem. 20, 5720–5726. doi:10.1039/c0jm00515k

CrossRef Full Text | Google Scholar

Perera, M. S. A., Ranjith, P., Choi, S., Airey, D., and Weniger, P. (2012). Estimation of gas adsorption capacity in coal: A review and an analytical study. Int. J. Coal Prep. Util. 32, 25–55. doi:10.1080/19392699.2011.614298

CrossRef Full Text | Google Scholar

Pu, Q., Zou, J., Wang, J., Lu, S., Ning, P., Huang, L., et al. (2021). Systematic study of dynamic CO2 adsorption on activated carbons derived from different biomass. J. Alloys Compd. 887, 161406. doi:10.1016/j.jallcom.2021.161406

CrossRef Full Text | Google Scholar

Qiu, S., Xue, M., and Zhu, G. (2014). Metal-organic framework membranes: From synthesis to separation application. Chem. Soc. Rev. 43, 6116–6140. doi:10.1039/c4cs00159a

PubMed Abstract | CrossRef Full Text | Google Scholar

Rivera-Muñoz, E. M., and Huirache-Acuña, R. (2010). Sol gel-derived SBA-16 mesoporous material. Int. J. Mol. Sci. 11, 3069–3086. doi:10.3390/ijms11093069

PubMed Abstract | CrossRef Full Text | Google Scholar

Rojas, S., Quartapelle-Procopio, E., Carmona, F., Romero, M., Navarro, J., and Barea, E. (2014). Biophysical characterisation, antitumor activity and MOF encapsulation of a half-sandwich ruthenium (II) mitoxantronato system. J. Mat. Chem. B 2, 2473–2477. doi:10.1039/c3tb21455a

PubMed Abstract | CrossRef Full Text | Google Scholar

Roy, A., Mondal, S., Halder, A., Banerjee, A., Ghoshal, D., Paul, A., et al. (2017). Benzimidazole linked arylimide based covalent organic framework as gas adsorbing and electrode materials for supercapacitor application. Eur. Polym. J. 93, 448–457. doi:10.1016/j.eurpolymj.2017.06.028

CrossRef Full Text | Google Scholar

Rubio-Martinez, M., Avci-Camur, C., Thornton, A. W., Imaz, I., Maspoch, D., and Hill, M. R. (2017). New synthetic routes towards MOF production at scale. Chem. Soc. Rev. 46, 3453–3480. doi:10.1039/c7cs00109f

PubMed Abstract | CrossRef Full Text | Google Scholar

Shyngys, M., Ren, J., Liang, X., Miao, J., Blocki, A., and Beyer, S. (2021). Metal-organic framework (MOF)-Based biomaterials for tissue engineering and regenerative medicine. Front. Bioeng. Biotechnol. 9, 603608. doi:10.3389/fbioe.2021.603608

PubMed Abstract | CrossRef Full Text | Google Scholar

Wang, Q., and Astruc, D. (2019). State of the art and prospects in metal-organic framework (MOF)-Based and MOF-derived nanocatalysis. Chem. Rev. 120, 1438–1511. doi:10.1021/acs.chemrev.9b00223

PubMed Abstract | CrossRef Full Text | Google Scholar

Watanabe, N., Hattori, M., Yokoyama, E., Isomura, S., Ujita, M., and Hara, A. (2006). Entomogenous fungi that produce 2, 6-pyridine dicarboxylic acid (dipicolinic acid). J. Biosci. Bioeng. 102, 365–368. doi:10.1263/jbb.102.365

PubMed Abstract | CrossRef Full Text | Google Scholar

Xi, M., He, C., Yang, H., Fu, X., Fu, L., Cheng, X., et al. (2022). Predicted a honeycomb metallic BiC and a direct semiconducting Bi2C monolayer as excellent CO2 adsorbents. Chin. Chem. Lett. 33, 2595–2599. doi:10.1016/j.cclet.2021.12.041

CrossRef Full Text | Google Scholar

Xiao, B., Byrne, P. J., Wheatley, P. S., Wragg, D. S., Zhao, X., Fletcher, A. J., et al. (2009). Chemically blockable transformation and ultraselective low-pressure gas adsorption in a non-porous metal organic framework. Nat. Chem. 1, 289–294. doi:10.1038/nchem.254

PubMed Abstract | CrossRef Full Text | Google Scholar

Yang, Y., Zhu, H., Xu, X., Bao, L., Wang, Y., Lin, H., et al. (2021). Construction of a novel lanthanum carbonate-grafted ZSM-5 zeolite for effective highly selective phosphate removal from wastewater. Microporous Mesoporous Mat. 324, 111289. doi:10.1016/j.micromeso.2021.111289

CrossRef Full Text | Google Scholar

Yu, W., and Sepehrnoori, K. (2014). An efficient reservoir-simulation approach to design and optimize unconventional gas production. J. Can. Pet. Technol. 53, 109–121. doi:10.2118/165343-pa

CrossRef Full Text | Google Scholar

Zhang, X., Sun, X., Lv, T., Weng, L., Chi, M., Shi, J., et al. (2020). Preparation of PI porous fiber membrane for recovering oil-paper insulation structure. J. Mat. Sci. Mat. Electron. 31, 13344–13351. doi:10.1007/s10854-020-03888-5

CrossRef Full Text | Google Scholar

Zhang, Y., Pan, Z., Yang, J., Chen, J., Chen, K., Yan, K., et al. (2022). Study on the suppression mechanism of (NH4) 2CO3 and SiC for polyethylene deflagration based on flame propagation and experimental analysis. Powder Technol. 399, 117193. doi:10.1016/j.powtec.2022.117193

CrossRef Full Text | Google Scholar

Zhao, X., Zheng, M., Gao, X., Zhang, J., Wang, E., and Gao, Z. (2021). The application of MOFs-based materials for antibacterials adsorption. Coord. Chem. Rev. 440, 213970. doi:10.1016/j.ccr.2021.213970

CrossRef Full Text | Google Scholar

Zhu, L., Liang, G., Guo, C., Xu, M., Wang, M., Wang, C., et al. (2022). A new strategy for the development of efficient impedimetric tobramycin aptasensors with metallo-covalent organic frameworks (MCOFs). Food Chem. x. 366, 130575. doi:10.1016/j.foodchem.2021.130575

CrossRef Full Text | Google Scholar