AUTHOR=Chen Si-Qi , Zhao Wei , Wu Biao TITLE=Separation of Sulfate Anion From Aqueous Solution Governed by Recognition Chemistry: A Minireview JOURNAL=Frontiers in Chemistry VOLUME=10 YEAR=2022 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2022.905563 DOI=10.3389/fchem.2022.905563 ISSN=2296-2646 ABSTRACT=

The sulfate anion (SO42–) is known as an end metabolite of cysteine and methionine, and its proper concentration is associated with the expression of key functions in the physiological system. Thus, maintaining sulfate concentration at a precise level is of great significance for biology, environments, and industrial productions. Fundamental research for sulfate anion chemistry can help understand sulfate-associated physiological processes and related applications, for example, remediation. In this minireview, we summarized recent research progresses in sulfate recognition and separation using crystallization and liquid–liquid extraction. We focused on the studies wherein molecular recognition is the key element and is considered the driving force for selective sulfate separations from aqueous solution.