AUTHOR=Wang Yiying , Shen Hongtao , Qiu Jianhua , Chen Mengqi , Song Weimin , Zhao Mingqin , Wang Longfei , Bai Feng , Wang Hongxia , Wu Zhiyong 

TITLE=Copper-Promoted Hiyama Cross-Coupling of Arylsilanes With Thiuram Reagents: A Facile Synthesis of Aryl Dithiocarbamates

JOURNAL=Frontiers in Chemistry

VOLUME=10

YEAR=2022

URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2022.867806

DOI=10.3389/fchem.2022.867806

ISSN=2296-2646

ABSTRACT=<p>We report herein a facile Hiyama cross-coupling reaction of arylsilanes with thiuram reagents (tetraalkylthiuram disulfides or tetraalkylthiuram monosulfide) enabled by copper fluoride. Compared to our previous work, this protocol is an alternative protocol for the generation of S-aryl dithiocarbamates. It features low toxic and readily available substrates, cost-effective promoter, easy performance, and provides good yields.</p>