Dafeng Yan
Longlu Wang
Feng Zeng
Huawei Huang4*- 1College of Chemistry and Chemical Engineering, Hubei University, Wuhan, China
- 2College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications (NJUPT), Nanjing, China
- 3State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing, Jiangsu, China
- 4KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology (KAUST), Thuwal, Saudi Arabia
Editorial on the Research Topic
Defect Chemistry in Electrocatalysis
With the fast development of modern society, environmental pollution and energy crisis have been drawing broad attention. It is highly desirable to develop renewable and clean energy conversion and storage technologies to overcome these issues (Yan et al., 2022; Zhang et al., 2016). Electrochemical energy storage and conversion devices show great potential for their intrinsic advantages, such as low cost, environment-friendly, and renewable (Chen and Shi, 2022). Electrocatalysis plays a vital role in electrochemical energy storage and conversion devices. Since the performances of these devices are greatly limited by the electrochemical reactions, it is very necessary to design highly efficient electrocatalysts to promote these reactions (Yan et al., 2022a). As the electrocatalytic reactions occur on the surface of the catalysts, the surface electronic structure of electrocatalysts largely determines their performance (Xie et al., 2021).
Among various strategies to modulate the electronic structure of electrocatalysts, defect engineering has recently become a very hot topic and draws much attention to the application of electrocatalytic fields (Yan et al., 2022b; Yan et al., 2017; Yan et al., 2019). In recent years, many researches related to defect chemistry in electrocatalysis were published and cited, which indicated that this topic is very hot and has drawn much attention (Li et al., 2022c). Though many researchers have paid their attention to defect chemistry in electrocatalysis, it is still in the initial period and there is great space for exploration in the aspects of synthetic method, structure characterization and dynamic evolution during different electrocatalytic reactions.
Herein, we collected five valuable contributions focusing on the defect chemistry of different materials and different electrocatalytic reactions. This special Research Topic includes four reviews and one original research. Defect engineering on carbon-based and metal-based single-atom electrocatalysts was highlighted by (Li et al., 2022b) along with the discussions of their characterization. Defective Noble metal and non-noble metal catalysts for electrocatalytic oxygen reduction reaction were discussed and summarized by (Mao et al., 2022) Based on experimental results and theoretical calculations, they clarified the structure-activity relationships between defect engineering and catalytic performance. Oxygen vacancies engineering in electrocatalysts for nitrogen reduction reaction was summarized by (Zhu et al., 2022) They focused on the methods to generate oxygen vacancies and their effects on electrocatalytic nitrogen reduction reaction. (Li et al., 2022a) briefly summarized recent research progress in defect engineering of electrocatalysts for electrochemical CO2 reduction. They summarized various strategies for adjusting and modifying the surface defects of catalysts, including intrinsic defects, heteroatom doping, single-metal-atom sites, vacancies, grain boundaries and lattice defects. (Xiao et al., 2022) successfully introduced the doughty-electronegative heteroatom defect to MoS2 through a large-scale and simple ball milling strategy, which can greatly enhance the hydrogen evolution reaction performance.
As guest editors, we would like to thank all the authors for their valuable contributions to this Research Topic and all the reviewers for their important and thoughtful comments. We hope that this Research Topic will provide useful insights for the development of and help readers understand more about the effects of defect chemistry on different electrocatalytic reactions.
Author contributions
All authors listed have made a substantial, direct, and intellectual contribution to the work and approved it for publication.
Conflict of interest
The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.
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References
Chen, L., and Shi, J. (2022). Co-electrolysis toward value-added chemicals. Sci. China Mater. 65 (1), 1–9. doi:10.1007/s40843-021-1809-5
Li, H., Li, R., Niu, J., Gan, K., and He, X. (2022a). Defect chemistry of electrocatalysts for CO2 reduction. Front. Chem. 10, 1067327. doi:10.3389/fchem.2022.1067327
Li, W., Chen, Z., Jiang, X., Jiang, J., and Zhang, Y. (2022b). Recent advances in the design of single-atom electrocatalysts by defect engineering. Front. Chem. 10, 1011597. doi:10.3389/fchem.2022.1011597
Li, W., Wang, D., Liu, T., Tao, L., Zhang, Y., Huang, Y.-C., et al. (2022c). Doping-modulated strain enhancing the phosphate tolerance on PtFe alloys for high-temperature proton exchange membrane fuel cells. Adv. Funct. Mater. 32 (8), 2109244. doi:10.1002/adfm.202109244
Mao, Z., Tang, X., An, X., and Jiang, J. (2022). Defective nanomaterials for electrocatalysis oxygen reduction reaction. Front. Chem. 10, 1023617. doi:10.3389/fchem.2022.1023617
Xiao, Z., Luo, S., Duan, W., Zhang, X., Han, S., Liu, Y., et al. (2022). Doughty-electronegative heteroatom-induced defective MoS2 for the hydrogen evolution reaction. Front. Chem. 10. doi:10.3389/fchem.2022.1064752
Xie, L., Wang, L., Zhao, W., Liu, S., Huang, W., and Zhao, Q. (2021). WS2 moiré superlattices derived from mechanical flexibility for hydrogen evolution reaction. Nat. Commun. 12 (1), 5070. doi:10.1038/s41467-021-25381-1
Yan, D., Li, Y., Huo, J., Chen, R., Dai, L., and Wang, S. (2017). Defect chemistry of nonprecious-metal electrocatalysts for oxygen reactions. Adv. Mater. 29 (48), 1606459. doi:10.1002/adma.201606459
Yan, D., Li, H., Chen, C., Zou, Y., and Wang, S. (2019). Defect engineering strategies for nitrogen reduction reactions under ambient conditions. Small Methods 3 (6), 1800331. doi:10.1002/smtd.201800331
Yan, D., Xia, C., He, C., Liu, Q., Chen, G., Guo, W., et al. (2022). A substrate-induced fabrication of active free-standing nanocarbon film as air cathode in rechargeable zinc–air batteries. Small 18 (7), 2106606. doi:10.1002/smll.202106606
Yan, D., Mebrahtu, C., Wang, S., and Palkovits, R. (2022a). Innovative electrochemical strategies for hydrogen production: From electricity input to electricity output. Angew. Chem. Int. Ed. doi:10.1002/anie.202214333
Yan, D., Xia, C., Zhang, W., Hu, Q., He, C., Xia, B. Y., et al. (2022b). Cation defect engineering of transition metal electrocatalysts for oxygen evolution reaction. Adv. Energy Mater. n/a 12, 2202317. doi:10.1002/aenm.202202317
Zhang, B., Zheng, X., Voznyy, O., Comin, R., Bajdich, M., García-Melchor, M., et al. (2016). Homogeneously dispersed multimetal oxygen-evolving catalysts. Science 352 (6283), 333–337. doi:10.1126/science.aaf1525
Keywords: electrocatalysis, defect engineering, defect chemistry, electrocatalyst, energy storage and conversion
Citation: Yan D, Wang L, Zeng F and Huang H (2022) Editorial: Defect chemistry in electrocatalysis. Front. Chem. 10:1118783. doi: 10.3389/fchem.2022.1118783
Received: 08 December 2022; Accepted: 09 December 2022;
Published: 16 December 2022.
Edited and reviewed by:
Nosang Vincent Myung, University of Notre Dame, United StatesCopyright © 2022 Yan, Wang, Zeng and Huang. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
*Correspondence: Dafeng Yan, ZGFmZW5neWFuQGhudS5lZHUuY24=; Longlu Wang, d2FuZ2xvbmdsdUBuanVwdC5lZHUuY24=; Feng Zeng, emVuZ0BuanRlY2guZWR1LmNu; Huawei Huang, aHVhd2VpLmh1YW5nQGthdXN0LmVkdS5zYQ==