AUTHOR=Ciferri Alberto 

TITLE=Molecular recognition at interfaces. Adhesion, wetting and bond scrambling

JOURNAL=Frontiers in Chemistry

VOLUME=10

YEAR=2022

URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2022.1088613

DOI=10.3389/fchem.2022.1088613

ISSN=2296-2646

ABSTRACT=<p>The quantitative description of the supramolecular interaction occurring at the adhesion surfaces of different polymers has enabled elaborate dissections of contributions to cohesive and surface energies. An alternative analysis is proposed here based on solubility parameters and binding constants that traditionally describe the weakest and relatively larger association energies in polymer blends. The article emphasizes a feature of supramolecular polymers that has not received adequate consideration: The dynamic bond scrambling that allows a most efficient molecular recognition over significant areas of synthetic and biological surfaces.</p>