AUTHOR=Greaney Allison T. , Ngelale Randy O. , Bruffey Stephanie H. , Martin Leigh R. 

TITLE=Abatement of radioiodine in aqueous reprocessing off-gas

JOURNAL=Frontiers in Chemistry

VOLUME=10

YEAR=2023

URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2022.1078668

DOI=10.3389/fchem.2022.1078668

ISSN=2296-2646

ABSTRACT=<p>The reprocessing used nuclear fuel (UNF) releases volatile fission and activation products, including <sup>129</sup>I, into the off-gas of a processing plant. Mitigation of the release of vapor phase radionuclides is necessary for meeting regulatory requirements in the United States and other countries. In an aqueous reprocessing plant, volatile radioiodine could be present in several forms, depending on the chemistry of the process used. Inorganic iodine will be the predominate species in any shearing or voloxidation pretreatment off-gas and dissolver off-gas (DOG). Organic iodides such as CH<sub>3</sub>I, C<sub>4</sub>H<sub>9</sub>I, and C<sub>12</sub>H<sub>25</sub>I have been proposed to be generated during solvent extraction; thus, these species must be captured from the vessel off-gas (VOG). The abatement of inorganic and organic iodide species to meet United States regulatory requirements has been demonstrated in laboratory experiments using Ag-based solid sorbents. The data presented in this paper includes the effect of gas composition (e.g., the presence of water vapor and NO<sub><italic>x</italic></sub>), iodine speciation (I<sub>2</sub>, CH<sub>3</sub>I, C<sub>4</sub>H<sub>9</sub>I, C<sub>12</sub>H<sub>25</sub>I), and sorbent bed parameters (e.g., temperature, sorbent age) on complete iodine capture on Ag-mordenite in an aqueous reprocessing plant.</p>