AUTHOR=Hong Zhongzhu , Luo Peifu , Wu Tingting , Wu Qinxia , Chen Xiaoling , Yang Zhijian , Dai Shuheng , Jiang Hao , Chen Qihao , Sun Qiang , Xie Lili TITLE=High-resolution flexible X-ray luminescence imaging enabled by eco-friendly CuI scintillators JOURNAL=Frontiers in Chemistry VOLUME=10 YEAR=2022 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2022.1052574 DOI=10.3389/fchem.2022.1052574 ISSN=2296-2646 ABSTRACT=

Solution-processed scintillators hold great promise in fabrication of low-cost X-ray detectors. However, state of the art of these scintillators is still challenging in their environmental toxicity and instability. In this study, we develop a class of tetradecagonal CuI microcrystals as highly stable, eco-friendly, and low-cost scintillators that exhibit intense radioluminescence under X-ray irradiation. The red broadband emission is attributed to the recombination of self-trapped excitons in CuI microcrystals. We demonstrate the incorporation of such CuI microscintillator into a flexible polymer to fabricate an X-ray detector for high-resolution imaging with a spatial resolution up to 20 line pairs per millimeter (lp mm−1), which enables sharp image effects by attaching the flexible imaging detectors onto curved object surfaces.