AUTHOR=Shi Shunli , Yu Ying , Zhang Bingzhen , Zhong Yicheng , Wang Lei , Wang Shuhua , Ding Shunmin , Chen Chao TITLE=Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst JOURNAL=Frontiers in Chemistry VOLUME=9 YEAR=2021 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2021.738736 DOI=10.3389/fchem.2021.738736 ISSN=2296-2646 ABSTRACT=

The development of efficient heterogeneous catalysts for one-pot tandem/cascade synthesis of imines remains meaningful and challenging. Herein, we constructed an Au/MOF catalyst featured hollow and double MOF shell nanostructure. Owing to its structural merits and acid-basic nature, the as-synthesized Void|(Au)ZIF-8|ZIF-8 catalyst exhibited an enhanced synergistically catalytic performance for tandem catalytic synthesis of imines from benzyl alcohol and aniline under air atmosphere and solvent-free condition. Its 170.16 h−1 of turnover frequency (TOF) was 2.5 times higher than that of the reported catalyst with the highest TOF value.