AUTHOR=Januario Eliane Ribeiro , Silvaino PatrĂ­cia Ferreira , Machado Arthur Pignataro , Moreira Vaz Jorge , Spinace Estevam Vitorio TITLE=Methane Conversion Under Mild Conditions Using Semiconductors and Metal-Semiconductors as Heterogeneous Photocatalysts: State of the Art and Challenges JOURNAL=Frontiers in Chemistry VOLUME=9 YEAR=2021 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2021.685073 DOI=10.3389/fchem.2021.685073 ISSN=2296-2646 ABSTRACT=

The processes currently used in the chemical industry for methane conversion into fuels and chemicals operate under extreme conditions like high temperatures and pressures. In this sense, the search for methane conversion under mild conditions remains a great challenge. This review aims to summarize the use semiconductors and metal-semiconductors as heterogeneous photocatalysts for methane conversion under mild conditions into valuable products. First, a brief presentation of photochemical conversion of methane is provided and then the focus of this review on the use of heterogeneous photocatalysts for methane conversion are described. Finally, the main challenges and opportunities are discussed.