AUTHOR=Kumar Harsh , Kaur Gagandeep TITLE=Scrutinizing Self-Assembly, Surface Activity and Aggregation Behavior of Mixtures of Imidazolium Based Ionic Liquids and Surfactants: A Comprehensive Review JOURNAL=Frontiers in Chemistry VOLUME=9 YEAR=2021 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2021.667941 DOI=10.3389/fchem.2021.667941 ISSN=2296-2646 ABSTRACT=

The desire of improving various processes like enhanced oil recovery (EOR), water treatment technologies, biomass extraction, organic synthesis, carbon capture etc. in which conventional surfactants have been traditionally utilized; prompted various researchers to explore the self-assembly and aggregation behavior of different kinds of surface-active molecules. Ionic liquids (ILs) with long alkyl chain present in their structure constitute the advantageous properties of surfactant and ILs, hence termed as surface-active ionic liquids (SAILs). The addition of ILs and SAILs significantly influence the surface-activity and aggregation behavior of industrially useful conventional surfactants. After a brief review of ILs, SAILs and surfactants, the prime focus is made on analyzing the self-assembly of SAILs and the mixed micellization behavior of conventional surfactants with different ILs.