AUTHOR=Liu Cui , Zhang Fang , Hu Jiao , Gao Wenhui , Zhang Mingzhen TITLE=A Mini Review on pH-Sensitive Photoluminescence in Carbon Nanodots JOURNAL=Frontiers in Chemistry VOLUME=8 YEAR=2021 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2020.605028 DOI=10.3389/fchem.2020.605028 ISSN=2296-2646 ABSTRACT=

Carbon nanodots (C-dots) with sp2/sp3 framework and diameter of <10 nm contain abundant functional groups or polymers on their surface. C-dots have attracted immense attention because of their unique optical properties, excellent biocompatibility, facile preparation, and low cost. With these merits, C-dots have been used in a wide range of applications including sensing, bioimaging, catalysis, and light-emitting devices. C-dots exhibit good optical properties, such as tunable emission wavelength, good photostability, nonblinking, up-conversion emission, etc. Of note, C-dots show intrinsic pH-sensitive photoluminescence (PL), indicating their great potential for pH sensing, especially in biotic pH sensing. In this review, we systematically summarize the pH-sensitive PL properties and the pH-sensitive PL mechanism, as well as recent research progress of C-dots in pH sensing. The current challenges of pH-sensitive C-dots and their future research focus are also proposed here. We anticipate this review might be of great significance for understanding the characteristics of pH-sensitive C-dots and the development of photoluminescent nanomaterials with pH-sensitive properties.