AUTHOR=Qiu Gege , Nava Paola , Colomban Cédric , Martinez Alexandre TITLE=Control and Transfer of Chirality Within Well-Defined Tripodal Supramolecular Cages JOURNAL=Frontiers in Chemistry VOLUME=8 YEAR=2020 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2020.599893 DOI=10.3389/fchem.2020.599893 ISSN=2296-2646 ABSTRACT=

The development of new strategies to turn achiral artificial hosts into highly desirable chiral receptors is a crucial challenge in order to advance the fields of asymmetric transformations and enantioselective sensing. Over the past few years, C3 symmetrical cages have emerged as interesting class of supramolecular hosts that have been reported as efficient scaffolds for chirality dynamics (such as generation, control, and transfer). On this basis, this mini review, which summarizes the existing examples of chirality control and propagation in tripodal supramolecular cages, aims at discussing the benefits and perspectives of this approach.