AUTHOR=Li Wanmei , Cai Heng , Huang Lin , He Lei , Zhang Yilan , Xu Jun , Zhang Pengfei TITLE=Iron(III)-Mediated Rapid Radical-Type Three-Component Deuteration of Quinoxalinones With Olefins and NaBD4 JOURNAL=Frontiers in Chemistry VOLUME=8 YEAR=2020 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2020.00606 DOI=10.3389/fchem.2020.00606 ISSN=2296-2646 ABSTRACT=
Iron(III)-promoted rapid three-component deuteration of quinoxalinones with olefins and NaBD4 is reported for the first time, which provides a novel, economic, and efficient method for the rapid synthesis of deuterated quinoxalinones. In this transformation, a radical pathway is involved according to the results of control experiments.