AUTHOR=Aksenov Nicolai A. , Aksenov Alexander V. , Ovcharov Sergei N. , Aksenov Dmitrii A. , Rubin Michael TITLE=Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles JOURNAL=Frontiers in Chemistry VOLUME=8 YEAR=2020 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2020.00077 DOI=10.3389/fchem.2020.00077 ISSN=2296-2646 ABSTRACT=

Unusual reactivity of nitroalkanes, involving formation of aci-forms (nitronic acids or nitronates) and their subsequent interaction with carbon-based nucleophiles, is surveyed in this review.