AUTHOR=Zheng Penglun , Liu Quanyi , Wang Donghui , Li Zekun , Meng Yawei , Zheng Yun 

TITLE=Preparation of Covalent-Ionically Cross-Linked UiO-66-NH2/Sulfonated Aromatic Composite Proton Exchange Membranes With Excellent Performance

JOURNAL=Frontiers in Chemistry

VOLUME=8

YEAR=2020

URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2020.00056

DOI=10.3389/fchem.2020.00056

ISSN=2296-2646

ABSTRACT=<p>Metal-organic frameworks (MOFs), as newly emerging filler materials for polyelectrolytes, show many compelling intrinsic features, such as variable structural designability and modifiability of proton conductivity. In this manuscript, UiO-66-NH<sub>2</sub>, a stable MOF with -NH<sub>2</sub> functional groups in its ligands, was selected to achieve a high-performance sulfonated poly(arylene ether nitrile)s (SPENs)/UiO-66-NH<sub>2</sub>-x covalent-ionically cross-linked composite membrane. Simultaneously, the obtained composite membranes displayed excellent thermal stability and dimensional stability. The as-prepared SPEN/UiO-66-NH<sub>2</sub>-x cross-linked membranes exhibited higher proton conductivity than recast SPENs, which can be attributed to the construction of ionic clusters and well-connected ionic nanochannels along the interface between UiO-66-NH<sub>2</sub>-x and SPEN matrix via molecular interactions. Meanwhile, the methanol permeability of the SPEN/UiO-66-NH<sub>2</sub>-x composite membrane had been effectively reduced due to the barrier effect of cross-linking and the addition of UiO-66-NH<sub>2</sub>-x. The SPEN/UiO-66-NH<sub>2</sub>-5 composite membrane had the highest selectivity of 6.42 × 10<sup>5</sup> S·s·cm<sup>−3</sup>: 14.3-times higher than that of Nafion 117. The preparation of cross-linked UiO-66-NH<sub>2</sub>/SPEN composite was facile, which provides a new strategy for preparing high performance proton exchange membrane.</p>