AUTHOR=Xiong Xiaosong , Yan Wenqi , You Chaolin , Zhu Yusong , Chen Yuhui , Fu Lijun , Zhang Yi , Yu Nengfei , Wu Yuping TITLE=Methods to Improve Lithium Metal Anode for Li-S Batteries JOURNAL=Frontiers in Chemistry VOLUME=7 YEAR=2019 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2019.00827 DOI=10.3389/fchem.2019.00827 ISSN=2296-2646 ABSTRACT=

The lithium-sulfur (Li-S) battery has received a lot of attention because it is characterized by high theoretical energy density (2,600 Wh/kg) and low cost. Though many works on the “shuttle effect” of polysulfide have been investigated, lithium metal anode is a more challenging problem, which leads to a short life, low coulombic efficiency, and safety issues related to dendrites. As a result, the amelioration of lithium metal anode is an important means to improve the performance of lithium sulfur battery. In this paper, improvement methods on lithium metal anode for lithium sulfur batteries, including adding electrolyte additives, using solid, and/or gel polymer electrolyte, modifying separators, applying a protective coating, and providing host materials for lithium deposition, are mainly reviewed. In addition, some challenging problems, and further promising directions are also pointed out for future research and development of lithium metal for Li-S batteries.