AUTHOR=Esperança José M. S. S. , Tariq Mohammad , Pereiro Ana B. , Araújo João M. M. , Seddon Kenneth R. , Rebelo Luis Paulo N. TITLE=Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems JOURNAL=Frontiers in Chemistry VOLUME=7 YEAR=2019 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2019.00450 DOI=10.3389/fchem.2019.00450 ISSN=2296-2646 ABSTRACT=

This work highlights unexpected, not so well known responses of ionic liquids and ionic liquid-containing systems, which are reported in a collective manner, as a short review. Examples include: (i) Minima in the temperature dependence of the isobaric thermal expansion coefficient of some ILs; (ii) Viscosity Minima in binary mixtures of IL + Molecular solvents; (iii) Anomalies in the surface tension within a family of ILs; (iv) The constancy among IL substitution of Cp/Vm at and around room temperature; (v) ILs as glass forming liquids; (vi) Alternate odd-even side alkyl chain length effects; (vii) Absolute negative pressures in ILs and IL-containing systems; (viii) Reversed-charged ionic liquid pairs; (ix) LCST immiscibility behavior in IL + solvent systems.