AUTHOR=Fujihara Tetsuaki , Tsuji Yasushi 

TITLE=Carboxylation Reactions Using Carbon Dioxide as the C1 Source via Catalytically Generated Allyl Metal Intermediates

JOURNAL=Frontiers in Chemistry

VOLUME=7

YEAR=2019

URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2019.00430

DOI=10.3389/fchem.2019.00430

ISSN=2296-2646

ABSTRACT=<p>The use of carbon dioxide (CO<sub>2</sub>) is an important issue with regard to current climate research and the Earth's environment. Transition metal-catalyzed carboxylation reactions using CO<sub>2</sub> are highly attractive. This review summarizes the transition metal-catalyzed carboxylation reactions of organic substrates with CO<sub>2</sub> via allyl metal intermediates. First, carboxylation reactions via transmetalation are reviewed. Second, catalytic carboxylation reactions using allyl electrophiles and suitable reducing agents are summarized. The last section discusses the catalytic carboxylation reactions via addition reactions, affording allyl metal intermediates.</p>