AUTHOR=Savchuk Oleksandr A. , Carvajal Joan J. , Cesteros Yolanda , Salagre Pilar , Nguyen Huu Dat , Rodenas Airan , Massons Jaume , Aguiló Magdalena , Díaz Franscesc TITLE=Mapping Temperature Distribution Generated by Photothermal Conversion in Graphene Film Using Er,Yb:NaYF4 Nanoparticles Prepared by Microwave-Assisted Solvothermal Method JOURNAL=Frontiers in Chemistry VOLUME=7 YEAR=2019 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2019.00088 DOI=10.3389/fchem.2019.00088 ISSN=2296-2646 ABSTRACT=

This study analyzes the mapping of temperature distribution generated by graphene in a glass slide cover after illumination at 808 nm with a good thermal resolution. For this purpose, Er,Yb:NaYF4 nanoparticles prepared by a microwave-assisted solvothermal method were used as upconversion luminescent nanothermometers. By tuning the basic parameters of the synthesis procedure, such as the time and temperature of reaction and the concentration of ethanol and water, we were able to control the size and the crystalline phase of the nanoparticles, and to have the right conditions to obtain 100% of the β hexagonal phase, the most efficient spectroscopically. We observed that the thermal sensitivity that can be achieved with these particles is a function of the size of the nanoparticles and the crystalline phase in which they crystallize. We believe that, with suitable changes, these nanoparticles might be used in the future to map temperature gradients in living cells while maintaining a good thermal resolution.