AUTHOR=Yoshizawa Akina , Feula Antonio , Leach Andrew G. , Male Louise , Fossey John S. 

TITLE=Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes

JOURNAL=Frontiers in Chemistry

VOLUME=6

YEAR=2018

URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2018.00211

DOI=10.3389/fchem.2018.00211

ISSN=2296-2646

ABSTRACT=<p>Seven <italic>N,N</italic>'-palladium(II) chloride complexes, one <italic>N,N</italic>'-palladium(II) acetate complex of 2,4-<italic>cis</italic>-azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride <italic>N,N</italic>'-complexes of 2,4-<italic>cis</italic>-azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A <italic>CNN</italic>' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4-<italic>cis</italic>-disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.</p>