AUTHOR=Chotirotsukon Chayanon , Jirachavala Kunlanis , Raita Marisa , Pongchaiphol Suchat , Hararak Bongkot , Laosiripojana Navadol , Champreda Verawat TITLE=Effects of thermal and physical modification on functional properties of organosolv lignin from sugarcane bagasse and its application in cosmeceutical products JOURNAL=Frontiers in Chemical Engineering VOLUME=5 YEAR=2023 URL=https://www.frontiersin.org/journals/chemical-engineering/articles/10.3389/fceng.2023.1099010 DOI=10.3389/fceng.2023.1099010 ISSN=2673-2718 ABSTRACT=

Organosolv lignin is an emerging bio-additive for creating functional properties in various products with its advantages in high-purity, sulfur-free, biocompatibility, and solubility in green solvents. In this study, effects of thermal and physical modification on alterations of functional properties and particle size distribution of isolated organosolv lignin from sugarcane bagasse (OLB) were studied. Thermal treatment of OLB at increasing temperatures from 170 to 230°C in 70%w/w aqueous ethanol led to alteration of phenolic hydroxyl content, while ultrasonication resulted in homogeneous size distribution of the modified OLB according to laser diffraction and scanning electron micrograph. The highest ultraviolet light absorbance and antioxidant activities were obtained at 190°C treatment which were correlated to the highest phenolic group content. Application of the modified OLB at 3% w/w in a base cream formulation resulted in enhancement of the anti-UV activity to exceed SPF 50 with increasing antioxidant activity in the product. The work provides basis on modification of organosolv lignin for application as a potent functional additive in cosmeceutical products.