AUTHOR=Wu Mingzhou , He Shuqing , Ha Enna , Hu Junqing , Ruan Shuangchen 

TITLE=A facile synthesis of PEGylated Cu2O@SiO2/MnO2 nanocomposite as efficient photo−Fenton−like catalysts for methylene blue treatment

JOURNAL=Frontiers in Bioengineering and Biotechnology

VOLUME=10

YEAR=2022

URL=https://www.frontiersin.org/journals/bioengineering-and-biotechnology/articles/10.3389/fbioe.2022.1023090

DOI=10.3389/fbioe.2022.1023090

ISSN=2296-4185

ABSTRACT=<p>The removal of toxic organic dyes from wastewater has received much attention from the perspective of environmental protection. Metal oxides see wide use in pollutant degradation due to their chemical stability, low cost, and broader light absorption spectrum. In this work, a Cu<sub>2</sub>O−centered nanocomposite Cu<sub>2</sub>O@SiO<sub>2</sub>/MnO<sub>2</sub>−PEG with an average diameter of 52 nm was prepared for the first time <italic>via</italic> a wet chemical route. In addition, highly dispersed MnO<sub>2</sub> particles and PEG modification were realized simultaneously in one step, meanwhile, Cu<sub>2</sub>O was successfully protected under a dense SiO<sub>2</sub> shell against oxidation. The obtained Cu<sub>2</sub>O@SiO<sub>2</sub>/MnO<sub>2</sub>−PEG showed excellent and stable photo−Fenton−like catalytic activity, attributed to integration of visible light−responsive Cu<sub>2</sub>O and H<sub>2</sub>O<sub>2</sub>−responsive MnO<sub>2</sub>. A degradation rate of 92.5% and a rate constant of 0.086 min<sup>−1</sup> were obtained for methylene blue (MB) degradation in the presence of H<sub>2</sub>O<sub>2</sub> under visible light for 30 min. Additionally, large amounts of •OH and <sup>1</sup>O<sub>2</sub> species played active roles in MB degradation. Considering the enhanced degradation of MB, this stable composite provides an efficient catalytic system for the selective removal of organic contaminants in wastewater.</p>