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ORIGINAL RESEARCH article

Front. Mater., 25 March 2021
Sec. Structural Materials
This article is part of the Research Topic Advanced Nuclear Materials for Fission Reactors View all 8 articles

Preparation and Properties Study of Cr on FeCrAl Cladding Materials

Peng WangPeng Wang1Yingjie QiaoYingjie Qiao1Wen QiWen Qi1Shiyu Du,Shiyu Du1,2Zhen Liu,Zhen Liu1,2Fanping MengFanping Meng2Xiaohong ZhangXiaohong Zhang1Kun WangKun Wang1Qiuwu LiQiuwu Li1Zhaoding YaoZhaoding Yao1Chengying BaiChengying Bai1XiaoDong Wang
XiaoDong Wang1*
  • 1College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, China
  • 2Engineering Laboratory of Advanced Energy Materials, Ningbo Institute of Industrial Technology, Chinese Academy of Sciences, Ningbo, China

FeCrAl alloy is a promising candidate material for the fourth-generation reactor core cladding material. Adjustment of the Cr content is one of the effective ways to obtain enhanced performance for the FeCrAl alloy. In this work, Fe–xCr–6Al alloy (11 ≤ x ≤ 15) with different Cr content were successfully prepared by hot rolling. When Cr replacement of Fe atoms in Fe–xCr–6Al alloy rises from 11 to 15wt%, the lattice distortion of Fe–xCr–6Al alloy increases, and the mechanical properties and thermal conductivity of the Fe–xCr–6Al alloy are raised. Compared with Al content, Cr content has less effect on Fe–xCr–6Al oxidation resistance.

Introduction

In recent years, with the potential shortage of traditional energy sources, nuclear power has become increasingly important (Farmer et al., 2014). However, with the occurrence of some well-known nuclear accidents, people have realized that the second and third generation nuclear energy systems in operation would hardly meet the safety requirements and the development of fourth-generation nuclear energy systems is in demand (Guzonas and Novotny, 2014; Yamamoto et al., 2015; Gong et al., 2016). And at present, operating temperature of the typical light water reactor (LWR) in the third-generation nuclear reactor is 285–320°C, while the core outlet pressure and temperature of the supercritical water-cooled reactor (SCWR), which is the fourth-generation nuclear reactor and also adopts light water as the coolant, can be 25MPa and 620–650°C (MacDonald et al., 2005). As the first barrier for nuclear safety protection, the reliability of fuel cladding plays a key role. In the nuclear accident at Fukushima Nuclear Power Plant in Japan in 2011, the Zr alloy cladding was rapidly oxidized under the loss of coolant accident (LOCA) conditions at 1,200°C, resulting in damage to the core and a hydrogen explosion (Pint et al., 2015).

Subsequently, the researchers conducted a series of investigations on the corrosion mechanism of commercial zirconium alloys, and found the corrosion weight gain of Zr–1Nb and Zr–Sn–Nb in LiOH aqueous solution at 360°C/18.6MPa are 0.4–0.8mg/mm2 during 200-days exposure (Chen et al., 2015, 2016, 2018). And the oxidation weight gains of commercial zirconium alloy like Zry-4, D4, M5, E110 and Zirlo in 600°C high temperature water vapor are 2–10mg/cm2h during 45h exposure. But as the oxidation temperature increases, the oxidation weight gains of commercial zirconium alloy like Zry-4, D4, M5, E110 and Zirlo in 1,200°C high temperature water vapor are 50–80mg/cm2h (Steinbrück et al., 2011). Therefore, it is difficult to adopt the current commercial Zr alloys as claddings in the fourth-generation nuclear reactors, which call for novel materials to replace Zircaloy with higher tolerance under extreme conditions. Recently, the FeCrAl ferritic alloy attracts attention due to its excellent oxidation resistance, and quickly become one of the candidate materials for the fourth-generation nuclear energy system cladding (Dryepondt et al., 2018).

The nuclear fuel cladding is not only a protective layer between the nuclear fuel and the coolant, but also provides the necessary structural support for the nuclear fuel. (Chang et al., 2019). For this reason, the desired cladding materials should provide sufficient strength and oxidation resistance to ensure that it can last a long time in the LOCA conditions (Zinkle et al., 2014; Konings et al., 2015; Gamble et al., 2017). For the performance of FeCrAl alloy, researchers have reported plenty of studies on their oxidation resistance (Field et al., 2015; Yamamoto et al., 2015; Aghamiri et al., 2020). the oxidation weight gain of FeCrAl alloy is much lower than this value (Pan et al., 2016; Maeda et al., 2019; Qiao et al., 2020). However, challenge persists for reliability of FeCrAl alloys in a harsh environment, e.g. in a supercritical water-cooled reactor where the operating temperature may exceed 380°C and the enthalpy for the reaction between the nuclear fuel cladding material and supercritical water is increased (Naidin et al., 2009).

As the cladding of nuclear fuel suffers from the internal pressure caused by the swelling, investigations have been performed on the factors affecting the mechanical properties (Yano et al., 2017; Sun et al., 2018; Kim et al., 2019; Yang et al., 2020) as well as the thermal conductivities of the FeCrAl alloy (Niu et al., 2008; Liu et al., 2017). In the meantime, the influence of main element content on thermomechanical performances are also concerned on. He et al. (2018) used industrial pure metals Fe, Cr and Al for vacuum induction smelting, and prepared 25 kg FeCrAl alloy ingots with different Al contents. Their results show that the prepared FeCrAl alloy exists as a body-centered cubic solid solution of α-Fe (Cr, Al) in which Cr and Al are dissolved in Fe. The ferrite phase remains stable before and after the high temperature tensile test. At all temperatures, the peak stress and yield stress increase with the increase of Al content, resulting from Al solid solution strengthening. Additionally, Young’s modulus decreases with the increase of Al content. Qiu et al. (2018) found that the thermal conductivity of C35M and Zr4 alloy is similar, while the specific heat capacity of C35M alloy is higher than that of Zr4 alloy. Field et al. (2015) prepared four FeCrAl alloys with different Cr and Al content added by arc smelting. Then, the FeCrAl alloy samples were prepared by hot forging, hot rolling and heat treatment, which were used for irradiation experiments. It is found that the samples with low Cr content have no brittle fracture phenomenon after irradiated above 7.0 dpa when FeCrAl alloy is irradiated in the LWR operating temperature range. In addition, compared with traditional Zr-based alloys, FeCrAl alloy samples with low Cr content still retain sufficient tensile properties after neutron irradiation. However, when the content of Cr is within the composition range that is difficult to produce α phase (Dryepondt et al., 2018), its influence on the structure and mechanical properties of FeCrAl alloy still needs further study. Furthermore, it was also found Cr in FeCrAl alloy can participate in oxidation reaction at high temperature and affect the oxidation resistance of the cladding material (Niu et al., 2008). Therefore, more investigations are necessary to understand the effect of Cr on the high temperature water vapor oxidation resistance of the FeCrAl alloy, and control the production of its α phase at the same time. Considering the arguments outlined above, we have prepared different Fe–xCr–6Al alloys (11 ≤ x ≤ 15) with 11–15wt% Cr in this work to understand their composition-structure-property-performance relationships. Through analyzing the influence of Cr content on the mechanical properties, thermal performance and oxidation resistance of alloys, the current study may provide technical reference for the development of advanced nuclear energy system materials in future studies.

Experimental Procedures

Materials

In this study, five Fe–Cr–Al alloys with different Cr contents were designed, named as Fe-11Cr-6Al, Fe-12Cr-6Al, Fe-13Cr-6Al, Fe–14Cr–6Al and Fe–15Cr–6Al, respectively. The pure Fe [99.50wt% (Weight percent)], pure Cr (99.00wt%) and pure Al (99.60wt%) were used to prepare the Fe–xCr–6Al alloy (11 ≤ x ≤ 15). The Fe–xCr–6Al ingots with weight of 20kg were obtained by vacuum induction melting (VIM) (Song et al., 2018). Then the ingots were homogenized at 1,150°C for 3h, and then hot rolled to 16mm in thickness at 800°C, finally annealed at 1,000°C for 1h. The composition of Fe–Cr–Al alloy ingots were measured by Inductively Coupled Plasma Optical Emission Spectrometer (ICAP-6300) and carbon analyzer (HW2000B). The detection limits for ICAP-6300 and HW2000B are 0.01–99.99 and 0.0001–99.9999wt% and the results are listed in Table 1.

TABLE 1
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TABLE 1. Chemical compositions of experimental of Fe–Cr–Al alloy (wt%).

Experimental Setup

X-ray diffraction (XRD) measurements of Fe–xCr–6Al alloy were performed using a D8 Advance X-ray diffractometer with a Cu-Ka source (λ = 1.540,598Å). Surface morphologies were characterized by a Phenom Pure scanning electron microscope (SEM). Metallographic organization were characterized by a metallographic optical microscope. The HVS-1000A digital microhardness tester was used to test the microhardness of Fe–xCr–6Al alloy. The ES310D density balance was used to test the room temperature density of Fe–xCr–6Al alloy. Compression sample was 10 mm × 10 mm×30mm. Compression tests were conducted using shoulder loading at a crosshead speed of 2mm/min with WDW-100 mechanical testing machine. The engineering stress was calculated by dividing the applied load by the initial cross-sectional area. All compression tests were performed at room temperature.

The oxidation experiments were conducted with reference to ISO 102700 and GBT 13303-1991. Initially, the Al2O3 crucible was roasted at 1,200°C until the weight change was less than 0.0001mg, and the Fe–Cr–Al alloy sample with the size of 20mm × 10mm×3mm was polished to 2,000 mesh and then put into the vacuum atmosphere tube furnace (SLG-1400C) by leaning in the crucible. After the sample was placed stably, the steam evaporator feed pump was turned on and ran for 5min. After the air was discharged from the heating pipe, the heating device was switched to 1,200°C at 20°C/min and then kept for 4h. After cooling to room temperature, the total weight of the crucible and the sample was weighed. The schematic diagram of the experimental device is shown in Figure 1 (Qiao et al., 2020).

FIGURE 1
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FIGURE 1. Schematic diagram of a controlled environment fireside corrosion test setup (Qiao et al., 2020).

The FeCrAl alloy sample for thermal conductivity test is a cylindrical sheet with a size of Φ12.7mm × 3 mm. The testing equipment is a laser thermal conductivity meter LFA457. The coefficient of thermal expansion (CTE), of Fe–xCr–6Al alloy in the range of 40–400°C is characterized. The test sample size of CTE test is Φ10 mm × 20 mm, and the testing equipment is L75 Platinum Series thermal expansion meter.

Results and Discussions

The microstructure and macroscopic properties of the alloy are often affected by the types and contents of the elements in the alloy. Therefore, analyzing the influence of elements on the properties of the alloy can help better design the cladding alloy system (Huczkowski et al., 2015; Sun et al., 2017). By analyzing the influence of Cr content on the microstructure morphology, micromechanical properties, oxidation resistance and thermal properties of Fe–xCr–6Al series alloys (11 ≤ x ≤ 15), the relationships of composition-structure-property-performance can be obtained.

Microstructure Observations of Fe–xCr–6Al Cladding Materials

[The phase analysis of the rolled Fe–xCr–6Al alloy sample by X-ray diffractometer is shown in Figure 2. The crystal structure of Fe–Cr–Al alloy belongs to the Fe–Cr phase (PDF #54-0331, Space Group Im-3m, No.229). At the same time, its peak width includes Fe, CrFe3, CrFe, Cr2Fe, Cr3Fe and some other Fe–Cr structures. Since the test sample is in a bulk form, the crystal orientation of the samples will affect the absolute strength of XRD which makes the peak intensities varying from one alloy to another, but impact little on peak position. At the same time, the noise value of the XRD in this test is about 3%, which means no observable second phase was formed within the samples and no impurity that can cause notable influence was introduced with the increasing Cr content in the Fe–xCr–6Al alloy.

2dsinθ=nλ(1)

The lattice constants of Fe–xCr–6Al alloys with different Cr content can be obtained by the Bragg formula written as Eq. 1 (Saowadee et al., 2017). In Eq. 1, d is the interplanar distance of the Fe–xCr–6Al alloys; θ is the angle between the incident X-ray and the corresponding crystal plane; λ is the X-ray wavelength; n is the diffraction order, usually set to 1. Since Fe–xCr–6Al alloys are body-centered cubic, its lattice constant is 2days. The composition-lattice constant curve of the Fe–xCr–6Al alloy {2 0 0} crystal planes, as shown in Figure 3. It is found that the unit cell distorted with the increase of Cr content, and the lattice constant of Fe–xCr–6Al alloy increases. And α-Fe atomic radius is 0.1241nm, α-Cr atomic radius is 0.1249nm. When Cr content in Fe–xCr–6Al alloy increases, the unit cell of the alloy is expanded, making the unit cell size of the Fe–xCr–6Al alloy increase, and leading in the distortion of its crystal structure increase.

FIGURE 2
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FIGURE 2. X-ray diffraction patterns of Fe–xCr–6Al with different compositions.

FIGURE 3
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FIGURE 3. Average composition-lattice constant curve of Fe–xCr–6Al alloy in room temperature.

Figure 4 shows the as-cast Fe–13Cr–6Al alloy before metallographic corrosion. The surface morphology can be found in good homogeneity and there is no precipitation of carbides or other inclusions, although there are some small pores on the surface of the alloy, which may be produced during the casting process.

FIGURE 4
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FIGURE 4. As-cast Fe–13Cr–6Al alloy before metallographic surface treatment.

Figure 5 shows the grain structure of the columnar crystal region for the as-cast FeCrAl alloy after metallographic surface treatment. With the Cr content of the Fe–xCr–6Al alloy increasing from 11 to 15wt%, the grain size of the columnar crystal region for the as-cast Fe–xCr–6Al alloy fluctuates from 1,000 to 1,500μm. At the same time, it can be found that the micropores on the surface expanded after metallographic surface treatment.

FIGURE 5
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FIGURE 5. As-cast structure of Fe–xCr–6Al alloy with different Cr content.

Figure 6 shows the grain size of Fe–xCr–6Al alloy recrystallization annealed at 1,000°C for 60min after metallographic surface treatment. the observation shows that the Fe–xCr–6Al alloy has been completely recrystallized. And When the Cr content of Fe–xCr–6Al alloy varies from 11wt% to 15wt%, the grain size of Fe–xCr–6Al alloy fluctuates from 300 to 550μm.

FIGURE 6
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FIGURE 6. Recrystallization and annealing structure of Fe–xCr–6Al alloys with different Cr content after rolling.

Mechanical Properties of Fe–xCr–6Al Cladding Materials

Figure 7 shows the density of Fe–xCr–6Al series alloys at room temperature. When the Al content is unchanged and the Cr atoms replace the Fe atoms in the Fe–xCr–6Al alloy with 11wt.%-15wt%, the density of the Fe–xCr–6Al alloy decreases. The relative atomic mass of Cr element is 51.996g/mol, while that of Fe element is 55.845g/mol. Therefore, when the content of Al element remains unchanged, the replacement of Fe atoms in Fe–xCr–6Al alloy with 11–15wt% of Cr atoms will result in a decrease in its density. The density at 350°C is derived from Eqs 2 and 3. And △L is the linear expansion length, L is the original length, β is the coefficient of linear expansion, △T is the temperature difference, ρT is the density at temperature T, M is the mass of Fe–xCr–6Al alloy, and VT is the volume at temperature T, ρ is the density at room temperature.

ΔL=LβΔT(2)
ρT=M/VT=M/(L+ΔL)3=ρ/(1+βT)3(3)
Figure 8 shows the Vickers hardness of Fe–xCr–6Al alloy at room temperature. As a general trend, the Vickers hardness of the Fe–xCr–6Al alloy increases with the increasing Cr content when the Cr atoms replace the Fe atoms in the Fe–xCr–6Al alloy with 11–15wt%.
FIGURE 7
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FIGURE 7. Composition-density curves of Fe–xCr–6Al alloys with different Cr content. The density at 350°C is derived from the density of Fe–xCr–6Al alloys at 25°C and coefficient of thermal expansion at 350°C.

FIGURE 8
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FIGURE 8. Vickers hardness of Fe–xCr–6Al alloys with different Cr content.

The compressibility of FeCrAl cladding material appears to be influenced by the Cr content within the alloy, but the detail remains unclear and requires further study. Figure 9 shows the relationship between the Cr content and the compressive yield strength of the FeCrAl alloy at room temperature. It can be seen from Figure 9 that when the Cr content increases, the compressive yield strength of the Fe–xCr–6Al alloy increases. The deformation mechanism of Fe–xCr–6Al alloy is dominated by the movement of edge dislocations at room temperature (Osetsky et al., 2014; Korchuganov et al., 2018). As the Cr content increases, the movement of the dislocation requires greater energy efficiency, so the compressive performance of the Fe–xCr–6Al alloy is improved.

FIGURE 9
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FIGURE 9. Compressive yizeld strength of Fe–xCr–6Al alloys with different Cr content.

Thermal Performance of Fe–xCr–6Al

Figure 10 is the curve on CTE of Fe–xCr–6Al alloy at 350°C. It can be seen from Figure 10 that the CTE of Fe–xCr–6Al alloys show a positive trend with respect to the Cr contents. In order to understand this, simple diatomic models are built in this work. Using DFT method at the level of B3LYP/6-31G(d, p) by Gauss09 software, the relationship between the bond length r and the potential energy (△E) of Fe–Fe, Fe–Cr and Cr–Cr are calculated as shown in Figures 11A–C. The relationship between atomic bond length and relative atomic potential energy increase rate (△E′) (Figure 11D) and the relationship between atomic bond length and relative atomic bond length increase rate (Figure 11E) are established by Figures 11A–C. From Figure 11D, it is found ΔECrCr>ΔEFeFe>ΔEFeCr when the bond length is between 0.2 and 0.4nm and the bond energy required for each alloy bond growth decreases with the increase of the bond length. As a result, the increment of bond length with given energy shows an opposite trend as shown in Figure 11E and the rate of Fe–Cr appears the highest. The distance between each atom in Fe–xCr–6Al alloys is in the range of 0.24–0.32nm, and the increase of Cr content mainly leads to the decrease of Fe–Fe and the increase of Fe–Cr in the alloy. Moreover, since there is less segregation of Cr in the alloy in the range of 11–15wt%, the increase of Cr won’t lead to the increase of Cr–Cr. Therefore, the increase of the Cr content will increase the thermal expansion coefficient of Fe–xCr–6Al alloys.

FIGURE 10
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FIGURE 10. The relationship between CTE and temperature of Fe–xCr–6Al alloys.

FIGURE 11
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FIGURE 11. (A) rFe-Fe and △EFe–Fe, (B)rFe–Cr and △EFe–Cr, (C)rCr–Cr and △ECr–Cr, (D) bond length and energy increase rate (△E′), and (E) bond length and bond length increase rate.

The specific heat and thermal diffusion coefficient of Fe–xCr–6Al alloy were measured by Differential Scanning Calorimeter, as shown in Figures 12A,Figures 12B. The specific heat and the thermal conductivity of Zircaloy are used as comparison with the data reported by Ott et al. (2014). It can be seen from Figure 12A that when the Cr content in Fe–xCr–6Al increases from 11 to 15wt%, the specific heat of Fe–xCr–6Al alloy decreases first and then increases. When the temperature increases from 25 to 350°C, the specific heat of FeCrAl alloy increases. Compared with zirconium alloy, Fe–xCr–6Al alloy has a higher specific heat capacity.

FIGURE 12
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FIGURE 12. The thermal conductivity (A) and thermal diffusivity (B) of Fe–xCr–6Al alloy with different Cr content.

The thermal diffusion coefficient of Fe–xCr–6Al alloy were measured by laser thermal conductivity meter, as shown in Figure 12B. It can be seen from Figure 12B that the thermal diffusivity of Fe–xCr–6Al alloy decreases with the increase of Cr element content. The thermal diffusivity of Fe–11Cr–6Al alloy decreases from 3.65 to 3.26mm2/s at 25°C. At 350°C, the thermal diffusivity of Fe–11Cr–6Al alloy decreases from 3.89 to 3.53mm2/s.

Effect of Cr Content on the Specific Heat of Fe–xCr–6Al Cladding Materials

The relationship among solid material thermal conductivity λ, specific heat C, coefficient of thermal expansion α and density ρ is shown in Eq. 4 (Liu et al., 2019):

λ=Cαρ(4)

The specific heat and thermal diffusion coefficient of Fe–xCr–6Al alloy were measured by laser thermal conductivity meter, as shown in Figure 13. It found that the thermal conductivity of Fe–xCr–6Al alloy decreases slightly with the increase of Cr probably because the obstruction of Fe–xCr–6Al alloy’s electron and phonon transport increase with Cr content increase. The thermal conductivity of Fe–11Cr–6Al alloy decreases from 13.3 to 11.7 at 25°C. And at 350°C, the thermal conductivity of Fe–11Cr–6Al alloy decreases from 18.0 to 16.2W/(mK). It is found that the thermal performance of zirconium alloy is slightly better than Fe–xCr–6Al alloy at 25°C, but at 350°C operating temperature, the thermal conductivity of Fe–xCr–6Al alloy is higher than that of zirconium alloy. That means the Fe–xCr–6Al alloy transfers the heat energy of the core to the cooling water more efficiently at operating temperature, which will increase the power generation efficiency of nuclear power plants.

FIGURE 13
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FIGURE 13. The specific heat of Fe–xCr–6Al alloy with different Cr content.

Oxidation Weight Gain of Fe–xCr–6Al Cladding Materials

Figure 14 shows the composition-oxidation weight gain curve of Fe–xCr–6Al alloy at room temperature after being oxidized in high temperature water vapor at 1,200°C for 4h. When the Cr content in Fe–xCr–6Al increases from 11 to 14wt%, the oxidation weight gain of Fe–xCr–6Al alloy increases from 0.158mg/cm2 to 0.586mg/cm2 for the oxidation activity of Cr element is higher than that of Fe element. Namely, before forming an effective Al2O3 protective layer, as the content of Cr element increases, the oxidation weight of Fe–xCr–6Al alloy in high temperature water vapor at 1,200°C increases. And then the initial total formation rate of Cr2O3 and Fe2O3 oxides increases with the Cr content increases. At 1,200°C, the Al in the Fe–xCr–6Al alloy has high reducibility, which makes the rate of Al participating in the reduction reaction increase, and the Al2O3 film can be formed faster with the initial formation rate of Cr2O3. When Cr atoms replaced Fe atoms in Fe–xCr–6Al alloy with 14 wt.%-15wt%, the weight gain after oxidation of Fe–xCr–6Al alloy decreased from 0.586 to 0.293mg/cm2. It indicates the oxidation weight gain rate can be greatly reduced when the Al2O3 generated is enough via reducing enough Cr2O3 to coat the Fe–xCr–6Al alloy sample. When the Al2O3 film formed by the reaction is sufficient to cover the Fe–xCr–6Al alloy sample, the anti-corrosion characteristics of the alloy can be observed.

FIGURE 14
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FIGURE 14. Oxidation weight gain of Fe–xCr–6Al alloy with different Cr content after high temperature steam oxidation.

Conclusion

This work mainly studied the influence of different Cr content on the microstructure, mechanical properties, oxidation resistance and thermal properties of Fe–xCr–6Al alloy. When Cr atoms replace Fe atoms in Fe–xCr–6Al alloy from 11 to 15wt%, the changes in properties of Fe–xCr–6Al alloy are summarized as follows:

1. The grain size of the Fe–xCr–6Al alloy varies between 350 and 450μm. And the prepared Fe–xCr–6Al alloy is still a-Fe single-phase structure, which belongs to ferrite, and won’t change with the change of Cr content.

2. The density of Fe–xCr–6Al alloy is slightly reduced, its hardness will increase by 9.7%, and its compressive yield strength will increase from 370 to 394MPa.

3. The oxidation weight gains of the Fe–xCr–6Al alloy obtained by oxidation in a high temperature water vapor environment of 1,200°C for 4h first increased from 0.158 to 0.586mg/cm2 and then decreased to 0.293mg/cm2. This is mainly caused by the combined effect of the increase of the Cr content leading to the increase of the initial oxide generation rate and the substantial reduction of the oxidation rate after the aluminum oxide film completely covers the Fe–xCr–6Al alloy.

4. The thermal expansion coefficient increase, the thermal conductivity and thermal diffusion coefficient of Fe–xCr–6Al alloy decrease, and the specific heat decreases first and then increases.

Data Availability Statement

The original contributions presented in the study are included in the article/Supplementary Material, further inquiries can be directed to the corresponding author.

Author Contributions

PW: Methodology, Data Curation, Writing—original draft YQ: Conceptualization, Funding acquisition. WQ: Visualization, Investigation. SD: Writing—Reviewing and Editing, Resources, Software. ZL: Resources, Software. FM: Resources. XZ: Writing–Reviewing and Editing. KW: Resources, Investigation. QL: Resources. ZY: Resources. CB: Writing—Reviewing and Editing. XW: Supervision, Project administration.

Funding

The authors would like to express thanks to the financial support from the National Key Research and Development Program of China (Nos. 2016YFB0700100, 2016YFB0700104, and 2019YFB1901003), Zhejiang Province Key Research and Development Program (No. 2019C01060), National Natural Science Foundation of China (Grant No. 21875271), the project of the key technology for virtue reactors from NPIC, Aviation power fund (6141B090571), Heilongjiang Science and Technology Plan Project (GX17A012) and the Fundamental Research Funds for the Central Universities (3072020CF1001) and the Fund of Science and Technology on Reactor Fuel and Materials Laboratory (6142A06190208) and Key Laboratory of Superlight Materials and Surface Technology (Harbin Engineering University).

Conflict of Interest

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

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Keywords: FeCrAl alloy, thermal performance, mechanical behavior, high-temperature steam oxidation, micro structure

Citation: Wang P, Qiao Y, Qi W, Du S, Liu Z, Meng F, Zhang X, Wang K, Li Q, Yao Z, Bai C and Wang X (2021) Preparation and Properties Study of Cr on FeCrAl Cladding Materials. Front. Mater. 8:621086. doi: 10.3389/fmats.2021.621086

Received: 25 October 2020; Accepted: 08 February 2021;
Published: 25 March 2021.

Edited by:

Liqiang Wang, Shanghai Jiao Tong University, China

Reviewed by:

Liang-Yu Chen, Jiangsu University of Science and Technology, China
Hung-Wei Yen, National Taiwan University, Taiwan

Copyright © 2021 Wang, Qiao, Qi, Du, Liu, Meng, Zhang, Wang, Li, Yao, Bai and Wang. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

*Correspondence: XiaoDong Wang, wangxiaodong@hrbeu.edu.cn

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