Andreas Rosenkranz
Carsten Gachot
Ali Erdemir- 1Department of Chemical Engineering, Biotechnology and Materials, University of Chile, Santiago, Chile
- 2Department of Mechanical and Industrial Engineering, Design Engineering and Product Development, TU Wien, Vienna, Austria
- 3Department of Mechanical Engineering, Texas A&M University, College Station, TX, United States
Editorial on the Research Topic
2D-Layered Nanomaterials: Chemical Functionalization, Advanced Characterization, and Tribological Properties
Nowadays, a significant amount of the global energy output is consumed to overcome friction- and wear-induced problems or even damages, a situation that urgently calls for more efficient tribological solutions and strategies (Holmberg and Erdemir, 2017; Holmberg and Erdemir, 2019; Shah et al., 2020). 2D-layered nanomaterials such as graphene, graphene oxide (GO), MoS2, etc., have gained substantial attention for their use as solid lubricants and lubricant additives thus serving as promising alternatives to conventional lubrication approaches under harsh operating conditions (Berman et al., 2018; Zhang et al., 2019; Rosenkranz et al., 2020). Since 2011, the class of 2D nanomaterials has been significantly expanded by the discovery of a new class of 2D transition metal carbides and/or carbonitrides (Naguib et al., 2011; Naguib et al., 2014). These newly emerging nanomaterials, with Ti3C2Tx as their most prominent member, are called MXenes due to their origin in MAX-phases and their structural similarity to graphene. MXene nano-sheets have been extensively studied and also used in energy storage, catalysis, and water purification (Anasori et al., 2017; Gogotsi and Anasori, 2019; Naguib et al., 2021). During the last 2 years, MXenes have experienced increasingly more attention within the tribological community due to their remarkable solid lubrication abilities and outstanding anti-wear performance (Malaki and Varma, 2020; Marian et al., 2020; Wyatt et al., 2021).
Although they present a new paradigm as promising alternatives to conventional lubrication approaches, 2D-layered nanomaterials as solid lubricants and lubricant additives have still some shortcomings that need to be overcome to further optimize their friction and wear performance (Berman et al., 2018; Zhang et al., 2019; Rosenkranz et al., 2020). Concerning solid lubricants, the adhesion strength of the deposited nanomaterials/nano-films to the substrate is critical for the resulting tribological performance (Malaki and Varma, 2020). Regarding lubricant additives, the generally hydrophilic character of these nanomaterials lowers their dispersibility in hydrophobic oils, which goes hand in hand with stability and sedimentation problems over time. Irrespective of the nanomaterial and the application (solid lubricant or lubricant additive), the surface chemistry of these nanomaterials is considered as the key factor to solve these problems. The existing surface terminations can be used to chemically functionalize the 2D-layered nanomaterials, thus allowing for enhanced adhesion strength and improved dispersibility. Chemical modifications need to be complemented by advanced, high-resolution materials characterization (chemical and structural) to ensure the success of the functionalization process. Moreover, materials characterization is of utmost importance for shedding light onto the very complex nature of tribologically involved interfaces prior to and after the tribological experiments, to understand their underlying friction and wear mechanisms.
In the framework of this special issue, there are several highly innovative manuscripts ranging from new exfoliation approaches, nanoscale humidity-dependent lubrication mechanisms to the performance of hybrid nanocomposites. In this context, Zhang et al. presented a new exfoliation method for MoS2, which results in nano-flakes with bigger sizes and increased reaction yields. Claerbout et al. numerically investigated the frictional properties of multilayer MoS2 during sliding in the presence of water by nonequilibrium molecular dynamics simulations. Zhu et al. addressed the contribution of four oxygenated acids to oxygen-containing functional groups in Hummers’ method using first principle methods. Li et al. studied the friction behavior of graphene in air and nitrogen atmosphere thus considering the microstructural evolution caused by the variation of test environments and their effects on the coefficient of coefficient. Regarding composite materials, Jakubczak et al. verified the performance of graphene-based nano-hybrids, while Chen et al. addressed the tribological performance of self-assembled multilayer films of (GO/PDDA)n.
At this point, we would like to express our sincere thanks to Frontiers Publishing Group for providing the opportunity for this special issue. We would also thank the authors of each chapter for their great contributions. Lastly, we would also thank the readers for their interest in our special issue. Undoubtedly, they will appreciate the importance of 2D materials in combatting friction and wear although there remain several more challenges to overcome for large-scale industrial applications.
Author Contributions
All authors listed have made a substantial, direct, and intellectual contribution to the work and approved it for publication.
Conflict of Interest
The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.
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References
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Rosenkranz, A., Yangqin, L., Lin, Y., and Lei, C. (2020). 2D Nanomaterials beyond Graphene: from Synthesis to Tribological Studies. Appl. Nanoscience 2020, 1–36.
Shah, R., Woydt, M., Huq, N., and Rosenkranz, A. (2020). Tribology Meets Sustainability. Ind. Lubrication Tribology 73, 430. doi:10.1108/ILT-09-2020-0356
Wyatt, B. C., Rosenkranz, A., and Anasori, B. (2021). 2D MXenes: Tunable Mechanical and Tribological Properties. Adv. Mater. 33 (17), 2007973. doi:10.1002/adma.202007973
Keywords: 2D nanomaterials, MXenes, chemical functionalization, friction, materials characerization
Citation: Rosenkranz A, Gachot C and Erdemir A (2022) Editorial: 2D-Layered Nanomaterials: Chemical Functionalization, Advanced Characterization, and Tribological Properties. Front. Chem. 10:840213. doi: 10.3389/fchem.2022.840213
Received: 20 December 2021; Accepted: 03 February 2022;
Published: 17 February 2022.
Edited and reviewed by:
Mingshui Yao, Kyoto University, JapanCopyright © 2022 Rosenkranz, Gachot and Erdemir. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
*Correspondence: Andreas Rosenkranz, arosenkranz@ing.uchile.cl