Skip to main content

MINI REVIEW article

Front. Chem., 10 January 2023
Sec. Green and Sustainable Chemistry
This article is part of the Research Topic Sustainable Catalytic Production of Bio-Based Heteroatom-Containing Compounds, Volume III View all 13 articles

Advancement in utilization of magnetic catalysts for production of sustainable biofuels

Yutao Zhang,,
Yutao Zhang1,2,3*Weihua LiWeihua Li1Jialu WangJialu Wang3Jiaxing JinJiaxing Jin2Yixi ZhangYixi Zhang1Jingsong ChengJingsong Cheng2Qiuyun Zhang,,
Qiuyun Zhang1,2,3*
  • 1Engineering Technology Center of Control and Remediation of Soil Contamination of Guizhou Science and Technology Department, Anshun University, Anshun, Guizhou, China
  • 2School of Chemistry and Chemical Engineering, Anshun University, Anshun, Guizhou, China
  • 3College Rural Revitalization Research Center of Guizhou, Anshun University, Anshun, Guizhou, China

In this study, we summarize recent advances in the synthesis of magnetic catalysts utilized for biodiesel production, particularly focusing on the physicochemical properties, activity, and reusability of magnetic mixed metal oxides, supported magnetic catalysts, ionic acid-functionalized magnetic catalysts, heteropolyacid-based magnetic catalysts, and metal–organic framework-based magnetic catalysts. The prevailing reaction conditions in the production of biodiesel are also discussed. Lastly, the current limitations and challenges for future research needs in the magnetic catalyst field are presented.

1 Introduction

With the rapidly expanding economy and high energy demand, the over-consumption of fossil fuels and fossil fuel usage has led to severe effects on the environment (e.g., global warming), creating wide attention among researchers (Li et al., 2023; Pan et al., 2022a; Zhang et al., 2022a; Pan et al., 2022b). Thus, seeking a sustainable energy resource is a high priority. To date, various types of biofuels, such as biodiesel, bioethanol, and aviation biofuels, have been considered as fossil fuel replacements. Among them, biodiesel (fatty acid alkyl ester, FAME) has been getting significant interest as an alternative fuel because of its safety, biodegradability, and carbon-neutrality (Zhang et al., 2020; Hoang et al., 2021). Currently, biodiesel is synthesized from free fatty acids (FFAs) and various oils mixed with short-chain alcohols, using homogeneous, heterogeneous, or enzymatic catalysts to promote the reaction (Figure 1) (Zhang et al., 2023). However, the homogeneous catalysis system exhibits numerous disadvantages, such as the fact that homogeneous catalysts (e.g., NaOH, KOH, H2SO4, etc.) are non-recyclable and cause pollution (Zhang et al., 2021; Liu et al., 2022). In contrast, heterogeneous catalysts (e.g., zeolites, heteropolyacids, metal oxides, etc.) have attracted growing interest owing to their low pollution and easy recovery (Woo et al., 2021; Zhang et al., 2022b; Paiva et al., 2022; Ul Islam et al., 2022). However, high-efficiency separation of the catalyst from the liquid phase and reduction of catalyst loss remain challenges. The use of magnetic separation techniques is an interesting approach to solving these problems (Chen et al., 2022).

FIGURE 1
www.frontiersin.org

FIGURE 1. Classification of catalysts for biodiesel production.

In recent times, magnetic solid acid/base catalysts have been widely applied for esterification and transesterification reactions as compared to other heterogeneous catalysts because they are environmentally friendly and cheap, and their highly magnetic nature allows efficient separation with an external magnetic field (Shylesh et al., 2010; Zhang et al., 2014). The present work reviews recent applications of different types of magnetic catalysts and their functionalized magnetic composites employed in biodiesel production, including magnetic mixed metal oxides, supported magnetic catalysts, ionic acid-functionalized magnetic catalysts, heteropolyacid-based magnetic catalysts, and MOF-based magnetic catalysts, among others. The physicochemical properties, activity, and reusability of these magnetic catalysts are evaluated and discussed. Lastly, a brief conclusion and summary on the outlook for designing magnetic catalysts with high catalytic activity is presented.

2 Magnetic catalysts

In general, Fe-, Co-, and Ni-based catalysts exhibit permanent magnetism and can be used as magnetic materials; Fe-based catalysts have been especially widely studied. According to their characteristics, magnetic catalysts can be roughly classified into five types, namely, magnetic mixed metal oxides, supported magnetic catalysts, ionic acid-functionalized magnetic catalysts, heteropolyacid-based magnetic catalysts, and MOF-based magnetic catalysts.

2.1 Magnetic mixed metal oxides

Recently, spinel ferrites, MFe2O4 (where M indicates a transition metal atom of Cu, Zn, Mo, Co, or Mn) have been widely researched for applications as heterogeneous catalysts due to their thermal stability and ease of separation by using an external magnet. Luadthong et al. (2016) investigated the transesterification of palm oil using a copper ferrite spinel oxide (CuFe2O4) catalyst. The characterization results revealed that the major active species of CuFe2O4 were the Cu2+ and Fe2+. Optimal reaction conditions of 220°C, 1 g of catalyst, a methanol:oil molar ratio of 1:18, and a high FAME content of >90% were determined. A similar study was conducted by Ali et al. (2020), in which a cuprospinel CuFe2O4 catalyst was used for the transesterification of waste frying oil with methanol at 60°C, giving a 90.24% yield. Kinetic results showed that the transesterification reaction followed pseudo-first-order kinetics, and the activation energy was found to be 37.64 kJ/mol. AlKahlaway et al. (2021) prepared ferric molybdate, Fe2(MoO4)3, nanoparticles for biodiesel synthesis and the catalytic conversion of oleic acid was 90.5%.

In addition, some magnetic mixed metal oxides including MoO3/SrFe2O4 (Gonçalves et al., 2021), MnFe2O4/GO (Bai et al., 2021), MgFe2O4@OA@CRL (Iuliano et al., 2020), NaFeTiO4/Fe2O3–FeTiO3 (Gutierrez-Lopez et al., 2021), Mg2+-doped ZnFe2O4 (Ashok et al., 2021), and waste chalk/CoFe2O4/K2CO3 (Foroutan et al., 2022) have been explored for their application largely due to their unique magnetism. Gonçalves et al. (2021) prepared a magnetic catalyst, MoO3/SrFe2O4, for the transesterification of waste cooking oil, and results confirmed the success of MoO3 anchorage of the SrFe2O4 material. The activity test showed that a biodiesel yield of 95.4% was obtained in 4 h at 164°C. The MoO3/SrFe2O4 catalyst could be easily separated by a permanent magnet and showed high stability with a yield of 84% after five cycles. Bai et al. (2021) investigated the catalytic performance of a MnFe2O4/graphene oxide catalyst for biodiesel production from waste edible oil. The MnFe2O4/graphene oxide catalyst had a high basicity of 3978.6 mmol/g, and in transesterification reactions, a high biodiesel yield of 96.47% was achieved. Moreover, the physical properties of the synthetic biodiesel were within the ASTM D6751 and EN 14214 standard range. A K2CO3 modification to the waste chalk/CoFe2O4 was developed by Foroutan et al. (2022), and the characterization results showed that the composite catalyst had a lower surface area due to the introduction of K2CO3. The highest biodiesel yield of 98.87% was obtained under optimized conditions, and the activation energy and frequency factor of the reaction system was found to be 11.8 kJ/mol and 0.78 min−1, respectively.

Rezania et al. (2021) synthesized a heterogeneous magnetic MGO@MMO nanocatalyst via the ultra-sonication procedure for biodiesel production from waste frying oil. From the results, a high biodiesel yield of 94% was achieved with a 1.5 h reaction at 60°C; the catalyst could be separated and recycled four times, achieving an 86% biodiesel yield. However, after the eighth cycle, the biodiesel yield decreased significantly, possibly due to leaching of the active components or active site blocking. In a more recent study by Hanif et al. (2022), a magnetic Fe/SnO nanocatalyst supported on feldspar was synthesized for the transesterification of various non-edible oils. The magnetic catalyst exhibited a high catalytic activity with more than 97% yield for all the tested non-edible oils. A highly active bifunctional Na–Fe–Ca nanocatalyst was developed by Wang et al. (2022). The catalytic activity of the magnetic Na–Fe–Ca nanocatalyst in biodiesel production was evaluated at low temperatures. Interestingly, with a 500°C calcination temperature, the catalyst reached a 95.84% biodiesel yield with 16 cycles via magnetic separation. In conclusion, magnetic mixed metal oxides have been used successfully as acid/base catalysts or supports in the catalysis industry, and the design and composition of cheap, magnetic composite nanocatalysts is a highly desirable goal in the future.

2.2 Supported magnetic catalysts

Apart from magnetic spinel ferrite catalysts, supported magnetic acid/base catalysts have also attracted significant interest for biofuels production in recent years. At present, Fe3O4 magnetic particles do not commonly exhibit good catalytic activity, although they are easily separated and reused. Magnetic Fe3O4 is often used as a carrier, and the catalytic system is cost-effective and environment-friendly. Joorasty et al. (2021) prepared NaOH/clinoptilolite–Fe3O4 for the transesterification reaction of Amygdalus scoparia oil, and the highest biodiesel yield by the catalyst was 91%. The kinetics of NaOH/clinoptilolite–Fe3O4-catalyzed transesterification were also explored, and the activation energy was determined to be 9.21 kJ/mol. Xia et al. (2022) prepared bifunctional Co-doped Fe2O3–CaO nanocatalysts (Co/Fe2O3–CaO) and studied their catalytic performance in soybean oil transesterification. It was reported that the Co/Fe2O3–CaO catalyst had good ferromagnetism (26.2 emu/g) after the Co doping, and could be efficiently separated. In another study by Nizam et al. (2022), magnetic Fe2O3 immobilized on microporous molecular sieves (Fe2O3/MS) was developed using a plant extract-mediated method. In the catalytic reaction, the Fe2O3/MS catalyst exhibited excellent applicability in the esterification, transesterification, and photodegradation reactions. Mohamed et al. (2020) and Mohamed and El-Faramawy. (2021) used a newly developed α-Fe2O3/AlOOH(γ-Al2O3) nanocatalyst to produce biodiesel from waste oil. The α-Fe2O3/AlOOH(γ-Al2O3) catalyst presented the highest FAME yield and recyclability due to its large surface area of 323.3 m2/g, high acidity of 0.45 mmol/g, and exposed active site planes. Furthermore, thermal analyses showed that the catalytic reaction system was endothermic.

In a study conducted by Changmai et al. (2021a), a recoverable Fe3O4@SiO2–SO3H core@shell magnetic catalyst was successfully prepared by a stepwise co-precipitation, coating, and functionalization method. The obtained magnetic Fe3O4@SiO2-SO3H had a magnetic saturation of 30.94 emu/g, a relatively large surface area of 32.88 m2/g, and a high acidity of 0.76 mmol/g. The Fe3O4@SiO2–SO3H catalyst achieved a high conversion of Jatropha curcas oil of 98 ± 1% under optimal reaction conditions. Mohammadpour and Safaei (2022) developed a novel sulfonated carbon-coated magnetic catalyst (Fe3O4@C@OSO3H), which was used for the Pechmann condensation of phenol derivatives and β-ketoesters. The resulting yield values were as high as 98%, and the catalyst could be reused fifteen times with no significant loss in activity. Table 1 shows a summary of supported magnetic catalysts utilized for the synthesis of biodiesel.

TABLE 1
www.frontiersin.org

TABLE 1. Recent findings on green biodiesel production using supported magnetic catalysts.

2.3 Magnetic catalysts functionalized with ionic liquids (ILs)

Recently, due to their highly tunable nature, low volatility, and strong chemical and thermal stability, ionic liquids (ILs) have been widely reported for use in the catalysis field (Sharma et al., 2022). Among these, many IL-functionalized magnetic catalysts have been tested for the production of biodiesel because of their unique properties and commercial availability. Fauzi et al. (2014) used oleic acid as raw material and 1-butyl-3-methylimidazolium tetrachloroferrate ([BMIM][FeCl4]) as a magnetic catalyst to prepare biodiesel by esterification, with a yield of methyl oleate of 83.4% under optimum conditions. In addition, the [BMIM][FeCl4] catalyst was reused for six runs with little loss; the activation energy of the esterification system was 17.97 kJ/mol.

A novel IL-functionalized magnetic catalyst was fabricated by covalent bonding of [SO3H-PIM-TMSP]HSO4 ILs onto mesoporous silica-modified Fe3O4 nanoparticles (FSS–IL) (Wu et al., 2014; Wan et al., 2015). The characterization results revealed that the FSS–IL catalyst possessed a uniform core–shell structure and high specific surface area. In the process of preparing biodiesel, the conversion was 93.5% after 4 h using oleic acid as a raw material. More importantly, this FSS–IL catalytic system remained active for six cycles. In another study, magnetically hydrophobic acidic polymeric ionic liquids (FnmS-PILs) were prepared and exhibited good activity and reusability (Zhang et al., 2018). Xie and Wang. (2020a) prepared a magnetic Fe3O4/SiO2-supported polymeric sulfonated ionic liquid (Fe3O4/SiO2-PIL) for simultaneous transesterification and esterification of low-cost oils, and the highest conversion obtained under optimal conditions was 93.3%. Additionally, the reusability study showed that the Fe3O4/SiO2-PIL could be recycled and reused five times. The higher activity and excellent reusability were attributed to the polymeric acidic ILs and porous magnetic nanoparticles. An immobilized dual acidic-ionic liquid on core–shell-structured magnetic silica was also prepared, and the as-prepared magnetic acid catalyst exhibited a large surface acidity of 3.93 meq H+/g, a strong magnetism of 27.5 emu/g, and achieved the highest conversion of biodiesel at 94.2%. The catalyst was reused for five runs, and the conversion still reached 86% (Xie et al., 2021).

Similar catalysts [NiFe2O4@BMSI]Br, Fe3O4@GO@PBIL, Fe3O4@SiO2@[C4mim]HSO4, Fe3O4@SiO2@PIL, and [BSO3HMIm][HSO4]@IRMOF-3 were also studied (Ding et al., 2021; Naushad et al., 2021; Yu et al., 2021; Zhao et al., 2021; Cheng et al., 2022). Among them, the magnetic [NiFe2O4@BMSI]Br catalyst was synthesized by an ion-exchange process, and the resulting catalyst had a BET surface area of 89.21 m2/g. Moreover, the [NiFe2O4@BMSI]Br catalyst attained a maximum yield of 86.4% for the transesterification of palm oil, and the catalytic activity was retained up to six cycles without obvious loss of yield (Naushad et al., 2021). Based on recent literature projections, ILs are expected to develop as potential acid materials for the synthesis of functionalized composite magnetic catalysts in the future.

2.4 Magnetic catalysts based on heteropolyacids

Heteropolyacids are inorganic compounds with a Keggin structure that acts as a strong Brønsted acid. Heteropolyacids have a low surface area and easily dissolve in polar solvents, so researchers bonded them to magnetic supports to overcome these problems. Wu et al. (2016a) investigated the application of magnetic material grafted onto a poly(phosphotungstate)-based acidic ionic liquid as a heterogeneous catalyst for the esterification of oleic acid. Under optimal conditions, the conversion of oleic acid reached 93.4%. More specifically, the catalyst exhibited good reusability after six runs using an external magnetic field.

As reported by Helmi et al. (2021), phosphomolybdic acid was supported on clinoptilolite–Fe3O4, and the prepared catalyst showed excellent activity (80% yield in 8 h at 75°C) and reusability in the production of biodiesel from Salvia mirzayanii oil. The HPA/clinoptilolite–Fe3O4 catalyst was able to recycle up to four times with minimal loss in activity. A magnetic heteropolyanion-based ionic liquid (MNP@HPAIL) was synthesized by Dadhania et al. (2021), and was evaluated for the esterification of oleic acid under ultrasonic irradiation. The maximum oleic acid conversion of 58% was reached, and the catalyst could be reused for six consecutive cycles.

On the same note, Zhang et al. (2021) immobilized a 12-tungstophosphoric acid (HPW)-based magnetic catalyst (Fe3O4@SBA-15@HPW and Fe3O4@SBA-15-NH2-HPW) for the production of biodiesel from palm oil with methanol. The synthesized magnetic catalysts have a high content of Brønsted acid sites due to the induction of HPW. In particular, the Fe3O4@SBA-15-NH2-HPW exhibited a high biodiesel yield of 91% under optimal reaction conditions, and also exhibited high reusability. Ghasemzadeh et al. (2022) adapted a cotton/Fe3O4@SiO2@H3PW12O40 magnetic nanocomposite to catalyze the transesterification of sunflower oil. The catalyst had an excellent magnetism of 45 emu/g and demonstrated a high FAME yield of 95.3% under optimum conditions. After four cycles of transesterification, the FAME yield was still relatively high at 85.5%. In addition, the physical properties of the synthetic biodiesel meet the ASTM and EU standards. According to the reported literature, heteropolyacids grafted onto magnetic supports can be an effective solution to overcome the loss of heteropolyacids.

2.5 MOF-based magnetic catalysts

Recently, metal–organic frameworks (MOFs), as a newly emergent type of stable and tunable material, have become promising magnetic catalysts and supports, and MOF derivatives have been used for heterogeneous catalysis. Wu et al. (2016b) investigated the ability of the Fe3O4@NH2-MIL-88B(Fe) catalyst to perform the esterification of oleic acid with ethanol. The Fe3O4@NH2-MIL-88B(Fe) catalyst had an acidity of 1.76 mmol/g and achieved a high yield of 93.2% at 90°C. Moreover, the Fe3O4@NH2-MIL-88B(Fe) catalyst could be recycled six times without significant loss of activity.

Xie’s group (Xie and Wan, 2018; Xie and Huang, 2019; Xie and Wang, 2020; Xie et al., 2021b) has studied biodiesel production from soybean oil and low-quality oils using magnetic Fe3O4@HKUST-1-ABILs, Fe3O4@MIL-100(Fe)/Candida rugosa lipase, CoFe2O4/MIL-88B(Fe)-NH2/(Py-Ps)PMo, and H6PV3MoW8O40/Fe3O4/ZIF-8 catalysts. Their results revealed that all magnetic catalysts exhibited good catalytic performance and excellent reusability. Thus, these MOF-based magnetic catalysts comprise an excellent potential alternative for processing low-quality oils into biofuels. In another study by Zhou’s group (Zhou et al., 2019; Zhou et al., 2023), a MIL-100(Fe) was embedded in magnetic Fe3O4 nanoparticles (Fe3O4/MIL-100(Fe), and the Fe3O4/MIL-100(Fe) composite exhibited unexpectedly high catalytic activity with a rosin conversion of 94.8% at 240°C. Furthermore, the Fe3O4/MIL-100(Fe) composite showed good stability and recyclability over six cycles. An annealed Fe3O4/MOF-5 was also synthesized and used to catalyze rosin esterification with glycerol. The highest conversion of 94.1% was attained in 2.5 h at 240°C, and the annealed catalyst showed excellent reusability.

A novel TiO2-decorated magnetic ZIF-8 nanocomposite (Fe3O4@ZIF-8/TiO2) was synthesized by Sabzevar et al. (2021). The as-prepared nanocomposite demonstrated excellent performance in the esterification of oleic acid (92.25% yield), which was mainly attributed to its acidic properties and large surface area. After five cycles, the yield of biodiesel was still 77.22%. Abdelmigeed et al. (2021a), Abdelmigeed et al. (2021b) prepared NaOH/magnetized ZIF-8 catalysts for the production of high-quality biodiesel from a blend of sunflower and soybean oil with ethanol. The transesterification reaction with the blended oil produced 70% biodiesel in 1.5 h at 75°C. The ethanolysis reaction followed a pseudo-second-order kinetic model, and the activation energy was calculated as 77.27 kJ/mol.

In another important area of catalyst research, MOFs were pyrolized at various temperatures to act as self-sacrificial templates for the synthesis of structured nanoporous metal oxides (Reddy et al., 2020). Li et al. (2019), Li et al. (2020), Li et al. (2021) reported on a series of magnetic catalysts based on MOF derivatives (MM–SrO, magnetic CaO-based catalyst, carbonized MIL-100(Fe) supporting ammonium sulfate), and the physical, chemical, and thermal properties of the MOF-derived magnetic catalysts were evaluated. The researchers discovered that these catalysts exhibited strong magnetism and excellent catalytic activity and could be easily separated by an external magnetic field after each cycle. In another study, a bifunctional magnetic catalyst with various coordination states of Co and non-coordinated N sites was developed by Guo et al. (2022). The prepared bifunctional magnetic catalyst (550–30) was evaluated for biodiesel production from microalgal lipids. It had a high conversion efficiency of 96.0%, owing to the generated structural defects that formed a mesopore-dominated structure in the bifunctional magnetic catalyst. Also, the catalyst could be magnetically separated and reused for six cycles with a conversion efficiency of 89.7%.

3 Summary and outlook

In the field of catalysis, magnetic catalysts promote catalytic reactions efficiently and their strong magnetic properties allow them to be easily reused, which make magnetic catalysts more cost-effective and efficient when used in industrial catalysis. The current mini-review highlights recent applications of magnetic catalysts and their functionalized magnetic materials utilized for biodiesel production. Although remarkable progress has been achieved in the area of magnetic catalyst research, there are still some limitations that need to be overcome by continuing design improvements. The catalytic mechanisms and deactivation processes are not well understood, supported magnetic catalysts show weak interactions between active ingredients and magnetic supports, and the complex synthesis processes for some magnetic catalysts need to be simplified. Thus, future investigation into the preparation methods, performance, mechanisms, and economics of the magnetic catalyst is essential to correct the present issues. In light of the current evidence, however, we strongly believe that the integrated development of novel magnetic catalysts will play a key role in further developing a cost-effective biorefinery industry.

Author contributions

YTZ conceived the article, discussed the outline, and wrote the manuscript; WL, JW, JJ, YXZ, and JC made preliminary revisions to the manuscript; YTZ and QZ coordinated the entire content of the manuscript and made detailed revisions; QZ was in charge of project administration.

Funding

This work was financially supported by the Anshun Science and Technology Planning Project ((2021)1), National Natural Science Foundation of China (22262001), Creative Research Groups Support Program of Guizhou Education Department (KY (2017)049), Youth Growth Science and Technology Personnel Foundation of Guizhou Education Department (KY (2019)147), Guizhou Province Key Laboratory of Ecological Protection and Restoration of Typical Plateau Wetlands ((2020) 2002), and Project of Anshun University supporting Doctors Research ((2021)asxybsjj01).

Conflict of interest

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Publisher’s note

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors, and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.

References

Abdelmigeed, M. O., Al-Sakkari, E. G., Hefney, M. S., Ismail, F. M., Abdelghany, A., Ahmed, T. S., et al. (2021b). Magnetized ZIF-8 impregnated with sodium hydroxide as a heterogeneous catalyst for high-quality biodiesel production. Renew. Energy 165, 405–419. doi:10.1016/j.renene.2020.11.018

CrossRef Full Text | Google Scholar

Abdelmigeed, M. O., Al-Sakkari, E. G., Hefney, M. S., Ismail, F. M., Ahmed, T. S., and Ismail, I. M. (2021a). Biodiesel production catalyzed by NaOH/Magnetized ZIF-8: Yield improvement using methanolysis and catalyst reusability enhancement. Renew. Energy 174, 253–261. doi:10.1016/j.renene.2021.04.057

CrossRef Full Text | Google Scholar

Ali, R. M., Elkatory, M. R., and Hamad, H. A. (2020). Highly active and stable magnetically recyclable CuFe2O4 as a heterogenous catalyst for efficient conversion of waste frying oil to biodiesel. Fuel 268, 117297. doi:10.1016/j.fuel.2020.117297

CrossRef Full Text | Google Scholar

AlKahlaway, A. A., Betiha, M. A., Aman, D., and Rabie, A. M. (2021). Facial synthesis of ferric molybdate (Fe2(MoO4)3) nanoparticle and its efficiency for biodiesel synthesis via oleic acid esterification. Environ. Technol. Innov. 22, 101386. doi:10.1016/j.eti.2021.101386

CrossRef Full Text | Google Scholar

Ambat, I., Srivastava, V., Haapaniemi, E., and Sillanpää, M. (2019). Nano-magnetic potassium impregnated ceria as catalyst for the biodiesel production. Renew. Energy 139, 1428–1436. doi:10.1016/j.renene.2019.03.042

CrossRef Full Text | Google Scholar

Ashok, A., Ratnaji, T., John Kennedy, L., Vijaya, J. J., and Pragash, R. G. (2021). Magnetically recoverable Mg substituted zinc ferrite nanocatalyst for biodiesel production: Process optimization, kinetic and thermodynamic analysis. Renew. Energy 163, 480–494. doi:10.1016/j.renene.2020.08.081

CrossRef Full Text | Google Scholar

Bai, L. Q., Tajikfar, A., Tamjidi, S., Foroutan, R., and Esmaeili, H. (2021). Synthesis of MnFe2O4@graphene oxide catalyst for biodiesel production from waste edible oil. Renew. Energy 170, 426–437. doi:10.1016/j.renene.2021.01.139

CrossRef Full Text | Google Scholar

Booramurthy, V. K., Kasimani, R., Subramanian, D., and Pandian, S. (2020). Production of biodiesel from tannery waste using a stable and recyclable nano-catalyst: An optimization and kinetic study. Fuel 260, 116373. doi:10.1016/j.fuel.2019.116373

CrossRef Full Text | Google Scholar

Cao, X. Y., Xu, H., Li, F. S., Zou, Y. J., Ran, Y. L., Ma, X. R., et al. (2021). One-step direct transesterification of wet yeast for biodiesel production catalyzed by magnetic nanoparticle-immobilized lipase. Renew. Energy 171, 11–21. doi:10.1016/j.renene.2021.02.065

CrossRef Full Text | Google Scholar

Changmai, B., Rano, R., Vanlalveni, C., and Rokhum, L. (2021a). A novel Citrus sinensis peel ash coated magnetic nanoparticles as an easily recoverable solid catalyst for biodiesel production. Fuel 286, 119447. doi:10.1016/j.fuel.2020.119447

CrossRef Full Text | Google Scholar

Changmai, B., Wheatley, A. E. H., Rano, R., Halder, G., Selvaraj, M., Rashid, U., et al. (2021b). A magnetically separable acid-functionalized nanocatalyst for biodiesel production. Fuel 305, 121576. doi:10.1016/j.fuel.2021.121576

CrossRef Full Text | Google Scholar

Chen, R., Qiao, X. Q., and Liu, F. M. (2022). Ionic liquid-based magnetic nanoparticles for magnetic dispersive solid-phase extraction: A review. Anal. Chim. Acta X. 1201, 339632. doi:10.1016/j.aca.2022.339632

PubMed Abstract | CrossRef Full Text | Google Scholar

Cheng, J., Mao, Y. X., Guo, H., Qian, S., Shao, Y., Yang, W. J., et al. (2022). Synergistic and efficient catalysis over Brønsted acidic ionic liquid [BSO3HMIm] [HSO4]-modified metal-organic framework (IRMOF-3) for microalgal biodiesel production. Fuel 322, 124217. doi:10.1016/j.fuel.2022.124217

CrossRef Full Text | Google Scholar

Chingakham, C., David, A., and Sajith, V. (2023). Fe3O4 nanoparticles impregnated eggshell as a novel catalyst for enhanced biodiesel production. Chin. J. Chem. Eng. 27, 2835–2843. doi:10.1016/j.cjche.2019.02.022

CrossRef Full Text | Google Scholar

Dadhania, H., Raval, D., and Dadhania, A. (2021). Magnetically separable heteropolyanion based ionic liquid as a heterogeneous catalyst for ultrasound mediated biodiesel production through esterification of fatty acids. Fuel 296, 120673. doi:10.1016/j.fuel.2021.120673

CrossRef Full Text | Google Scholar

Ding, J., Zhou, C. W., Wu, Z. W., Chen, C., Feng, N. J., Wang, L., et al. (2021). Core-shell magnetic nanomaterial grafted spongy-structured poly (ionic liquid): A recyclable brönsted acid catalyst for biodiesel production. Appl. Catal. A General 616, 118080. doi:10.1016/j.apcata.2021.118080

CrossRef Full Text | Google Scholar

Farrokheh, A., Tahvildari, K., and Nozari, M. (2021). Comparison of biodiesel production using the oil of Chlorella Vulgaris micro-algae by electrolysis and reflux methods using CaO/KOH-Fe3O4 and KF/KOH-Fe3O4 as magnetic nano catalysts. Waste Biomass Valorization 12, 3315–3329. doi:10.1007/s12649-020-01229-5

CrossRef Full Text | Google Scholar

Fauzi, A. H. M., Amin, N. A. S., and Mat, R. (2014). Esterification of oleic acid to biodiesel using magnetic ionic liquid: Multi-objective optimization and kinetic study. Appl. Energy 114, 809–818. doi:10.1016/j.apenergy.2013.10.011

CrossRef Full Text | Google Scholar

Foroutan, R., Peighambardoust, S. J., Mohammadi, R., Peighambardoust, S. H., and Ramavandi, B. (2022). Application of waste chalk/CoFe2O4/K2CO3 composite as a reclaimable catalyst for biodiesel generation from sunflower oil. Chemosphere 289, 133226. doi:10.1016/j.chemosphere.2021.133226

PubMed Abstract | CrossRef Full Text | Google Scholar

Ghasemzadeh, B., Matin, A. A., Habibi, B., and Ebadi, M. (2022). Cotton/Fe3O4@SiO2@H3PW12O40 a magnetic heterogeneous catalyst for biodiesel production: Process optimization through response surface methodology. Ind. Crops Prod. 181, 114806. doi:10.1016/j.indcrop.2022.114806

CrossRef Full Text | Google Scholar

Gonçalves, M. A., Lourenço Mares, E. K., Zamian, J. R., da Rocha Filho, G. N., and da Conceição, L. R. V. (2021). Statistical optimization of biodiesel production from waste cooking oil using magnetic acid heterogeneous catalyst MoO3/SrFe2O4. Fuel 304, 121463. doi:10.1016/j.fuel.2021.121463

CrossRef Full Text | Google Scholar

Guo, H., Cheng, J., Mao, Y. X., Qian, L., Shao, Y., and Yang, W. J. (2022). Fabricating different coordination states of cobalt as magnetic acid-base bifunctional catalyst for biodiesel production from microalgal lipid. Fuel 322, 124172. doi:10.1016/j.fuel.2022.124172

CrossRef Full Text | Google Scholar

Gutierrez-Lopez, A. N., Mena-Cervantes, V. Y., García-Solares, S. M., Vazquez-Arenas, J., and Hernandez-Altamirano, R. (2021). NaFeTiO4/Fe2O3-FeTiO3 as heterogeneous catalyst towards a cleaner and sustainable biodiesel production from Jatropha curcas L. Oil. J. Clean. Prod. 304, 127106. doi:10.1016/j.jclepro.2021.127106

CrossRef Full Text | Google Scholar

Hanif, M., Bhatti, I. A., Zahid, M., and Shahid, M. (2022). Production of biodiesel from non-edible feedstocks using environment friendly nano-magnetic Fe/SnO catalyst. Sci. Rep. 12, 16705. doi:10.1038/s41598-022-20856-7

PubMed Abstract | CrossRef Full Text | Google Scholar

Helmi, M., Ghadiri, M., Tahvildari, K., and Hemmati, A. (2021). Biodiesel synthesis using clinoptilolite-Fe3O4-based phosphomolybdic acid as a novel magnetic green catalyst from salvia mirzayanii oil via electrolysis method: Optimization study by Taguchi method. J. Environ. Chem. Eng. 9, 105988. doi:10.1016/j.jece.2021.105988

CrossRef Full Text | Google Scholar

Hoang, A. T., Tabatabaei, M., Aghbashlo, M., Carlucci, A. P., Ölçer, A. I., Le, A. T., et al. (2021). Rice bran oil-based biodiesel as a promising renewable fuel alternative to petrodiesel: A review. Renew. Sustain. Energy Rev. 135, 110204. doi:10.1016/j.rser.2020.110204

CrossRef Full Text | Google Scholar

Iuliano, M., Sarno, M., Pasquale, S. D., and Ponticorvo, E. (2020). Candida rugosa lipase for the biodiesel production from renewable sources. Renew. Energy 162, 124–133. doi:10.1016/j.renene.2020.08.019

CrossRef Full Text | Google Scholar

Joorasty, M., Hemmati, A., and Rahbar-Kelishami, A. (2021). NaOH/clinoptilolite-Fe3O4 as a novel magnetic catalyst for producing biodiesel from Amygdalus scoparia oil: Optimization and kinetic study. Fuel 303, 121305. doi:10.1016/j.fuel.2021.121305

CrossRef Full Text | Google Scholar

Ke, P., Zeng, D. L., Wu, J., Cui, J. W., Li, X., and Wang, G. H. (2019). Preparation and characterization of sulfonated magnetic SiO2 microspheres as the solid acid catalysts for esterification. ACS Omega 4, 22119–22125. doi:10.1021/acsomega.9b03262

PubMed Abstract | CrossRef Full Text | Google Scholar

Khakestarian, M., Taghizadeh, M., and Fallah, N. (2022). Magnetic mesoporous KOH/Fe3O4@MCM-41 nanocatalyst for biodiesel production from waste cooking oil: Optimization of process variables and kinetics study. Environ. Prog. Sustain. Energy 2022, e13863. doi:10.1016/j.enconman.2022.116292

CrossRef Full Text | Google Scholar

Krishnan, S. G., Pua, F. L., and Zhang, F. (2022). Oil palm empty fruit bunch derived microcrystalline cellulose supported magnetic acid catalyst for esterification reaction: An optimization study. Energy Convers. Manag. X 13, 100159. doi:10.1016/j.ecmx.2021.100159

CrossRef Full Text | Google Scholar

Lani, N. S., and Ngadi, N. (2022). Highly efficient CaO-ZSM-5 zeolite/Fe3O4 as a magnetic acid-base catalyst upon biodiesel production from used cooking oil. Appl. Nanosci. 12, 3755–3769. doi:10.1007/s13204-021-02121-x10.1007/s13204-021-02121-x

CrossRef Full Text | Google Scholar

Li, H., Liu, F. S., Ma, X. L., Wu, Z. J., Li, Y., Zhang, L. H., et al. (2019). Catalytic performance of strontium oxide supported by MIL-100(Fe) derivate as transesterification catalyst for biodiesel production. Energy Convers. Manag. 180, 401–410. doi:10.1016/j.enconman.2018.11.012

CrossRef Full Text | Google Scholar

Li, H., Wang, J. C., Ma, X. L., Wang, Y. Y., Li, G. N., Guo, M., et al. (2021). Carbonized MIL-100(Fe) used as support for recyclable solid acid synthesis for biodiesel production. Renew. Energy 179, 1191–1203. doi:10.1016/j.renene.2021.07.122

CrossRef Full Text | Google Scholar

Li, H., Wang, Y. B., Ma, X. L., Wu, Z. J., Cui, P., Lu, W. P., et al. (2020). A novel magnetic CaO-based catalyst synthesis and characterization: Enhancing the catalytic activity and stability of CaO for biodiesel production. Chem. Eng. J. 391, 123549. doi:10.1016/j.cej.2019.123549

CrossRef Full Text | Google Scholar

Li, Y. C., Zhu, K. X., Jiang, Y. Y., Chen, L., Zhang, H., Li, H., et al. (2023). Biomass-derived hydrophobic metal-organic frameworks solid acid for green efficient catalytic esterification of oleic acid at low temperatures. Fuel Process. Technol. 239, 107558. doi:10.1016/j.fuproc.2022.107558

CrossRef Full Text | Google Scholar

Liu, K., Zhang, L. Y., Wei, G. T., Yuan, Y. H., and Huang, Z. Y. (2022). Synthesis, characterization and application of a novel carbon-doped mix metal oxide catalyst for production of castor oil biodiesel. J. Clean. Prod. 373, 133768. doi:10.1016/j.jclepro.2022.133768

CrossRef Full Text | Google Scholar

Luadthong, C., Khemthong, P., Nualpaeng, W., and Faungnawakij, K. (2016). Copper ferrite spinel oxide catalysts for palm oil methanolysis. Appl. Catal. A General 525, 68–75. doi:10.1016/j.apcata.2016.07.002

CrossRef Full Text | Google Scholar

Mohamed, M. M., Bayoumy, W. A., El-Faramawy, H., El-Dogdog, W., and Mohamed, A. A. (2020). A novel a-Fe2O3/AlOOH(γ-Al2O3) nanocatalyst for efficient biodiesel production from waste oil: Kinetic and thermal studies. Renew. Energy 160, 450–464. doi:10.1016/j.renene.2020.07.006

CrossRef Full Text | Google Scholar

Mohamed, M. M., and El-Faramawy, H. (2021). An innovative nanocatalyst α-Fe2O3/AlOOH processed from gibbsite rubbish ore for efficient biodiesel production via utilizing cottonseed waste oil. Fuel 297, 120741. doi:10.1016/j.fuel.2021.120741

CrossRef Full Text | Google Scholar

Mohammadpour, P., and Safaei, E. (2022). Biodiesel and adipic acid production using molybdenum(VI) complex of a bis(phenol) diamine ligand supported on Fe3O4 magnetic nanoparticles. Fuel 327, 124831. doi:10.1016/j.fuel.2022.124831

CrossRef Full Text | Google Scholar

Naushad, M., Ahamad, T., and Khan, M. R. (2021). Fabrication of magnetic nanoparticles supported ionic liquid catalyst for transesterification of vegetable oil to produce biodiesel. J. Mol. Liq. 330, 115648. doi:10.1016/j.molliq.2021.115648

CrossRef Full Text | Google Scholar

Nizam, A., Warrier, V. G., Devasia, J., and Ganganagappa, N. (2022). Magnetic iron oxide nanoparticles immobilized on microporous molecular sieves as efficient porous catalyst for photodegradation, transesterification and esterification reactions. J. Porous Mat. 29, 119–129. doi:10.1007/s10934-021-01150-9

CrossRef Full Text | Google Scholar

Paiva, M. F., de Freitas, E. F., de França, J. O. C., da Silva Valadares, D., Dias, S. C. L., and Dias, J. A. (2022). Structural and acidity analysis of heteropolyacids supported on faujasite zeolite and its effect in the esterification of oleic acid and n-butanol. Mol. Catal. 532, 112737. doi:10.1016/j.mcat.2022.112737

CrossRef Full Text | Google Scholar

Pan, H., Xia, Q. N., Li, H., Wang, Y. G., Shen, Z. F., Wang, Y. Q., et al. (2022a). Direct production of biodiesel from crude Euphorbia lathyris L. Oil catalyzed by multifunctional mesoporous composite materials. Fuel 309, 122172. doi:10.1016/j.fuel.2021.122172

CrossRef Full Text | Google Scholar

Pan, H., Xia, Q. N., Wang, Y., Shen, Z. F., Huang, H., Ge, Z. G., et al. (2022b). Recent advances in biodiesel production using functional carbon materials as acid/base catalysts. Fuel Process. Technol. 237, 107421. doi:10.1016/j.fuproc.2022.107421

CrossRef Full Text | Google Scholar

Reddy, R. C. K., Lin, J., Chen, Y. Y., Zeng, C. H., Lin, X. M., Cai, Y. P., et al. (2020). Progress of nanostructured metal oxides derived from metal-organic frameworks as anode materials for lithium-ion batteries. Coord. Chem. Rev. 420, 213434. doi:10.1016/j.ccr.2020.213434

CrossRef Full Text | Google Scholar

Rezania, S., Kamboh, M. A., Arian, S. S., Al-Dhabi, N. A., Arasu, M. V., Esmail, G. A., et al. (2021). Conversion of waste frying oil into biodiesel using recoverable nanocatalyst based on magnetic graphene oxide supported ternary mixed metal oxide nanoparticles. Bioresour. Technol. 323, 124561. doi:10.1016/j.biortech.2020.124561

PubMed Abstract | CrossRef Full Text | Google Scholar

Sabzevar, A. M., Ghahramaninezhad, M., and Shahrak, M. N. (2021). Enhanced biodiesel production from oleic acid using TiO2-decorated magnetic ZIF-8 nanocomposite catalyst and its utilization for used frying oil conversion to valuable product. Fuel 288, 119586. doi:10.1016/j.fuel.2020.119586

CrossRef Full Text | Google Scholar

Sharma, J., Kumar, P., Sillanpaa, M., Kumar, D., and Nemiwal, M. (2022). Immobilized ionic liquids on Fe3O4 nanoparticles: A potential catalyst for organic synthesis. Inorg. Chem. Commun. 145, 110055. doi:10.1016/j.inoche.2022.110055

CrossRef Full Text | Google Scholar

Sharma, N., Guliani, D., Kaur, K., Verma, A., Sobti, A., and Toor, A. P. (2019). Enhanced catalytic activity of nano-Fe2O3–MCM-48–SO4 as a green catalyst for the esterification of acetic acid with methanol. Iran. J. Sci. Technol. Trans. Sci. 43, 2831–2842. doi:10.1007/s40995-019-00779-1

CrossRef Full Text | Google Scholar

Shylesh, S., Schuenemann, V., and Thiel, W. R. (2010). Magnetically separable nanocatalysts: Bridges between homogeneous and heterogeneous catalysis. Angew. Chem. Int. Ed. 49, 3428–3459. doi:10.1002/anie.200905684

PubMed Abstract | CrossRef Full Text | Google Scholar

Teo, S. H., Islam, A., Chan, E. S., Choong T, S. Y., Alharthi, N. H., Taufiq-Yap, Y. H., et al. (2019). Efficient biodiesel production from Jatropha curcus using CaSO4/Fe2O3-SiO2 core-shell magnetic nanoparticles. J. Clean. Prod. 208, 816–826. doi:10.1016/j.jclepro.2018.10.107

CrossRef Full Text | Google Scholar

Ul Islam, M. G., Jan, M. T., Farooq, M., Naeem, A., Khan, I. W., and Khattak, H. U. (2022). Biodiesel production from wild olive oil using TPA decorated Cr-Al acid heterogeneous catalyst. Chem. Eng. Res. Des. 329, 540–549. doi:10.1016/j.cherd.2021.12.040

CrossRef Full Text | Google Scholar

Wan, H., Wu, Z. W., Chen, W., Guan, G. F., Cai, Y., Chen, C., et al. (2015). Heterogenization of ionic liquid based on mesoporous material as magnetically recyclable catalyst for biodiesel production. J. Mol. Catal. A Chem. 398, 127–132. doi:10.1016/j.molcata.2014.12.002

CrossRef Full Text | Google Scholar

Wang, H., Covarrubias, J., Prock, H., Wu, X., Wang, D., and Bossmann, S. H. (2015). Acid-functionalized magnetic nanoparticle as heterogeneous catalysts for biodiesel synthesis. J. Phys. Chem. C 119, 26020–26028. doi:10.1021/acs.jpcc.5b08743

CrossRef Full Text | Google Scholar

Wang, X. M., Zeng, Y. N., Jiang, L. Q., Wang, Y. T., Li, J. G., Kang, L. L., et al. (2022a). Highly stable NaFeO2-Fe3O4 composite catalyst from blast furnace dust for efficient production of biodiesel at low temperature. Ind. Crops Prod. 182, 114937. doi:10.1016/j.indcrop.2022.114937

CrossRef Full Text | Google Scholar

Wang, Y. T., Wang, X. M., Gao, D., Wang, F. P., Zeng, Y. N., Li, J. G., et al. (2022b). Efficient production of biodiesel at low temperature using highly active bifunctional Na-Fe-Ca nanocatalyst from blast furnace waste. Fuel 322, 124168. doi:10.1016/j.fuel.2022.124168

CrossRef Full Text | Google Scholar

Woo, J., Joshi, R., Park, Y. K., and Jeon, J. K. (2021). Biodiesel production from jatropha seeds with bead-type heterogeneous catalyst. Korean J. Chem. Eng. 38, 763–770. doi:10.1007/s11814-021-0759-7

CrossRef Full Text | Google Scholar

Wu, M., Yao, X. J., Jiang, J. L., Ji, Y. N., Gu, Y. X., Deng, Q. L., et al. (2022). Synthesis of magnetic sulfonated carbon/Fe3O4/palygorskite composites and application as a solid acid catalyst. Clays Clay Min. 70, 514–526. doi:10.1007/s42860-022-00199-0

CrossRef Full Text | Google Scholar

Wu, Z. W., Chen, C., Wan, H., Wang, L., Li, Z., Li, B. X., et al. (2016b). Fabrication of magnetic NH2-MIL-88B (Fe) confined Brønsted ionic liquid as an efficient catalyst in biodiesel synthesis. Energy fuels. 30, 10739–10746. doi:10.1021/acs.energyfuels.6b01212

CrossRef Full Text | Google Scholar

Wu, Z. W., Chen, C., Wang, L., Wan, H., and Guan, G. F. (2016a). Magnetic Material Grafted Poly(phosphotungstate-based acidic ionic liquid) as efficient and recyclable catalyst for esterification of oleic acid. Ind. Eng. Chem. Res. 55, 1833–1842. doi:10.1021/acs.iecr.5b02906

CrossRef Full Text | Google Scholar

Wu, Z. W., Li, Z., Wu, G. M., Wang, L. L., Lu, S. Q., Wang, L., et al. (2014). Brønsted acidic ionic liquid modified magnetic nanoparticle: An efficient and green catalyst for biodiesel production. Ind. Eng. Chem. Res. 53, 3040–3046. doi:10.1021/ie4040016

CrossRef Full Text | Google Scholar

Xia, S. G., Li, J., Chen, G. Y., Tao, J. Y., Li, W. Q., and Zhu, G. B. (2022). Magnetic reusable acid-base bifunctional Co doped Fe2O3-CaO nanocatalysts for biodiesel production from soybean oil and waste frying oil. Renew. Energy 189, 421–434. doi:10.1016/j.renene.2022.02.122

CrossRef Full Text | Google Scholar

Xie, W. L., Gao, C. L., and Li, J. B. (2021b). Sustainable biodiesel production from low-quantity oils utilizing H6PV3MoW8O40 supported on magnetic Fe3O4/ZIF-8 composites. Renew. Energy 168, 927–937. doi:10.1016/j.renene.2020.12.129

CrossRef Full Text | Google Scholar

Xie, W. L., and Huang, M. Y. (2019). Enzymatic production of biodiesel using immobilized lipase on core-shell structured Fe3O4@MIL-100(Fe) composites. Catalysts 9, 850. doi:10.3390/catal9100850

CrossRef Full Text | Google Scholar

Xie, W. L., and Huang, M. Y. (2020). Fabrication of immobilized Candida rugosa lipase on magnetic Fe3O4-poly(glycidyl methacrylate-co-methacrylic acid) composite as an efficient and recyclable biocatalyst for enzymatic production of biodiesel. Renew. Energy 158, 474–486. doi:10.1016/j.renene.2020.05.172

CrossRef Full Text | Google Scholar

Xie, W. L., and Wan, F. (2018). Basic ionic liquid functionalized magnetically responsive Fe3O4@HKUST-1 composites used for biodiesel production. Fuel 220, 248–256. doi:10.1016/j.fuel.2018.02.014

CrossRef Full Text | Google Scholar

Xie, W. L., and Wang, H. (2021). Grafting copolymerization of dual acidic ionic liquid on core-shell structured magnetic silica: A magnetically recyclable brönsted acid catalyst for biodiesel production by one-pot transformation of low-quality oils. Fuel 283, 118893. doi:10.1016/j.fuel.2020.118893

CrossRef Full Text | Google Scholar

Xie, W. L., and Wang, H. (2020a). Immobilized polymeric sulfonated ionic liquid on core-shell structured Fe3O4/SiO2 composites: A magnetically recyclable catalyst for simultaneous transesterification and esterifications of low-cost oils to biodiesel. Renew. Energy 145, 1709–1719. doi:10.1016/j.renene.2019.07.092

CrossRef Full Text | Google Scholar

Xie, W. L., and Wang, Q. (2020b). Synthesis of heterogenized polyoxometalate-based ionic liquids with brönsted-lewis acid sites: A magnetically recyclable catalyst for biodiesel production from low-quality oils. J. Ind. Eng. Chem. 87, 162–172. doi:10.1016/j.jiec.2020.03.033

CrossRef Full Text | Google Scholar

Xie, W. L., Xiong, Y. F., and Wang, H. Y. (2021a). Fe3O4-poly(AGE-DVB-GMA) composites immobilized with guanidine as a magnetically recyclable catalyst for enhanced biodiesel production. Renew. Energy 174, 758–768. doi:10.1016/j.renene.2021.04.086

CrossRef Full Text | Google Scholar

Yu, J. T., Wang, Y. H., Sun, L. Q., Xu, Z., Du, Y. D., Sun, H. L., et al. (2021). Catalysis preparation of biodiesel from waste schisandra chinensis seed oil with the ionic liquid immobilized in a magnetic catalyst: Fe3O4@SiO2@[C4mim]HSO4. ACS Omega 6, 7896–7909. doi:10.1021/acsomega.1c00504

PubMed Abstract | CrossRef Full Text | Google Scholar

Zhang, H., Li, H., Pan, H., Wang, A. P., Souzanchi, S., Xu, C., et al. (2018). Magnetically recyclable acidic polymeric ionic liquids decorated with hydrophobic regulators as highly efficient and stable catalysts for biodiesel production. Appl. Energy 223, 416–429. doi:10.1016/j.apenergy.2018.04.061

CrossRef Full Text | Google Scholar

Zhang, P. B., Liu, P., Fan, M. M., Jiang, P. P., and Haryono, A. (2021b). High-performance magnetite nanoparticles catalyst for biodiesel production: Immobilization of 12-tungstophosphoric acid on SBA-15 works effectively. Renew. Energy 175, 244–252. doi:10.1016/j.renene.2021.05.033

CrossRef Full Text | Google Scholar

Zhang, P., Han, Q., Fan, M., and Jiang, P. (2014). Magnetic solid base catalyst CaO/CoFe2O4 for biodiesel production: Influence of basicity and wettability of the catalyst in catalytic performance. Appl. Surf. Sci. 317, 1125–1130. doi:10.1016/j.apsusc.2014.09.043

CrossRef Full Text | Google Scholar

Zhang, Q. Y., Ling, D., Lei, D. D., Wan, J. L., Liu, X. F., Zhang, Y. T., et al. (2020). Green and facile synthesis of metal-organic framework Cu-BTC supported Sn (II)-substituted Keggin heteropoly composites as an esterification nanocatalyst for biodiesel production. Front. Chem. 8, 129. doi:10.3389/fchem.2020.00129

PubMed Abstract | CrossRef Full Text | Google Scholar

Zhang, Q. Y., Luo, Q. Z., Wu, Y. P., Yu, R. F., Cheng, J. S., and Zhang, Y. T. (2021a). Construction of a Keggin heteropolyacid/Ni-MOF catalyst for esterification of fatty acids. RSC Adv. 11, 33416–33424. doi:10.1039/D1RA06023F

PubMed Abstract | CrossRef Full Text | Google Scholar

Zhang, Q. Y., Wang, J. L., Zhang, S. Y., Ma, J., Cheng, J. S., and Zhang, Y. T. (2022a). Zr-Based metal-organic frameworks for green biodiesel synthesis: A minireview. Bioengineering 9, 700. doi:10.3390/bioengineering9110700

PubMed Abstract | CrossRef Full Text | Google Scholar

Zhang, Q. Y., Yang, B. B., Tian, Y. Y., Yang, X. J., Yu, R. F., Wang, J. L., et al. (2022b). Fabrication of silicotungstic acid immobilized on Ce-based MOF and embedded in Zr-based MOF matrix for green fatty acid esterification. Green process. Synth. 11, 184–194. doi:10.1515/gps-2022-0021

CrossRef Full Text | Google Scholar

Zhang, W. L., Wang, C. R., Luo, B. N., He, P. H., Li, L., and Wu, G. Q. (2023). Biodiesel production by transesterification of waste cooking oil in the presence of graphitic carbon nitride supported molybdenum catalyst. Fuel 332, 126309. doi:10.1016/j.fuel.2022.126309

CrossRef Full Text | Google Scholar

Zhao, R., Yang, X. Y., Li, M. Z., Peng, X. J., Wei, M. X., Zhang, X. C., et al. (2021). Biodiesel preparation from Thlaspi arvense L. seed oil utilizing a novel ionic liquid core-shell magnetic catalyst. Ind. Crops Prod. 162, 113316. doi:10.1016/j.indcrop.2021.113316

CrossRef Full Text | Google Scholar

Zhou, D., Chen, X. P., Liang, B. F., Fan, X. X., Wei, X. J., Liang, J. Z., et al. (2019). Embedding MIL-100(Fe) with magnetically recyclable Fe3O4 nanoparticles for highly efficient esterification of diterpene resin acids and the associated kinetics. Microporous Mesoporous Mat. 289, 109615. doi:10.1016/j.micromeso.2019.109615

CrossRef Full Text | Google Scholar

Zhou, D., Wang, L. L., Chen, X. P., Wei, X. J., Liang, J. Z., Tang, R., et al. (2023). Reaction mechanism investigation on the esterification of rosin with glycerol over annealed Fe3O4/MOF-5 via kinetics and TGA-FTIR analysis. Chem. Eng. J. 401, 126024. doi:10.1016/j.cej.2020.126024

CrossRef Full Text | Google Scholar

Keywords: magnetic, heterogeneous catalysis, reusability, esterification, transesterification, biodiesel

Citation: Zhang Y, Li W, Wang J, Jin J, Zhang Y, Cheng J and Zhang Q (2023) Advancement in utilization of magnetic catalysts for production of sustainable biofuels. Front. Chem. 10:1106426. doi: 10.3389/fchem.2022.1106426

Received: 23 November 2022; Accepted: 06 December 2022;
Published: 10 January 2023.

Edited by:

Hu Li, Guizhou University, China

Reviewed by:

Jian He, Jishou University, China
Hu Pan, Jiaxing University, China

Copyright © 2023 Zhang, Li, Wang, Jin, Zhang, Cheng and Zhang. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

*Correspondence: Yutao Zhang, zyt0516@126.com; Qiuyun Zhang, sci_qyzhang@126.com

Disclaimer: All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article or claim that may be made by its manufacturer is not guaranteed or endorsed by the publisher.