Supercritical CO2 Synthesis of Freestanding Se1-xSx Foamy Cathodes for High-Performance Li-Se1-xSx Battery

Selenium-sulfur solid solutions (Se_1-xS_x) are considered to be a new class of promising cathodic materials for high-performance rechargeable lithium batteries owing to their superior electric conductivity than S and higher theoretical specific capacity than Se. In this work, high-performance Li-Se_1-xS_x batteries employed freestanding cathodes by encapsulating Se_1-xS_x in a N-doped carbon framework with three-dimensional (3D) interconnected porous structure (NC@SWCNTs) are proposed. Se_1-xS_x is uniformly dispersed in 3D porous carbon matrix with the assistance of supercritical CO₂ (SC-CO₂) technique. Impressively, NC@SWCNTs host not only provides spatial confinement for Se_1-xS_x and efficient physical/chemical adsorption of intermediates, but also offers a highly conductive framework to facilitate ion/electron transport. More importantly, the Se/S ratio of Se_1-xS_x plays an important role on the electrochemical performance of Li- Se_1-xS_x batteries. Benefiting from the rationally designed structure and chemical composition, NC@SWCNTs@Se_0.2S_0.8 cathode exhibits excellent cyclic stability (632 mA h g−1 at 200 cycle at 0.2 A g⁻¹) and superior rate capability (415 mA h g⁻¹ at 2.0 A g⁻¹) in carbonate-based electrolyte. This novel NC@SWCNTs@Se_0.2S_0.8 cathode not only introduces a new strategy to design high-performance cathodes, but also provides a new approach to fabricate freestanding cathodes towards practical applications of high-energy-density rechargeable batteries.

Introduction

Lithium-sulfur (Li-S) batteries are considered as promising next-generation electrochemical energy-storage systems in view of their high theoretical energy density (2600 W h kg⁻¹), environmental friendliness and natural richness of sulfur (Yao et al., 2017; Zheng et al., 2020; Yuan et al., 2021a; Yuan et al., 2021b; Sun et al., 2021). Although great progress has been made, the widespread practical application of Li-S battery is still facing issues of the insulation property of natural sulfur (5 × 10⁻³⁰ S m⁻¹, 25°C), the serious volume effect in the cycle process, and the dissolution of the intermediate polysulfide, leading to the low sulfur utilization, fast capacity decay and poor cycle stability (Zhang et al., 2020).

As a congener of element S, Se has similar chemical properties with S, such as high theoretical volumetric capacity (3,253 mA h cm⁻³, ρ = 4.81 g cm⁻³), which is suitable for mobile devices and hybrid electric vehicles with strict restrictions on battery volume (Lin et al., 2021; Sun et al., 2021). Meanwhile, selenium is a semiconductor with much higher electronic conductivity (1 × 10⁻³ S m⁻¹) than sulfur, which is conducive to excellent kinetic behavior (Zhang et al., 2020). Nevertheless, in the current research stage of Li-Se batteries, there are still many problems in Se cathode materials, such as relatively unfavorable higher cost and lower gravimetric capacity (675 mA h g⁻¹) when compared to Li-S batteries (1,675 mA h g⁻¹) (Fang et al., 2018b). In order to offset the drawbacks of Se and S and complement each other’s advantages, a solid solution of Se and S (Se_1-xS_x, 0 < x < 1) has been proposed as high-performance cathode materials for lithium storage. Se_1-xS_x is a class of chemical compounds with different Se-S ratios, which not only owns a higher theoretical capacity than pure Se, but also has increased electronic conductivity and accelerated reaction kinetics than pristine S (Abouimrane et al., 2012; Wei et al., 2016; Xu et al., 2019).

However, similar to S, Se_1-xS_x cathode materials also suffer from poor cycle lifespan and low Coulombic efficiency due to the dissolution and shuttling of intermediates (Chen et al., 2019; Du et al., 2020). Since Se_1-xS_x cathode materials exhibit similar electrochemical behaviors to S, the strategies of immobilizing S should also be effective for Se_1-xS_x (Luo et al., 2014). At present, the main host materials of Se_1-xS_x are carbonaceous materials (Sun et al., 2021), such as hollow carbon spheres (Xu et al., 2015; Hu et al., 2020), mesoporous carbon (Han et al., 2019), carbon nanotubes (Fan et al., 2018; Guan et al., 2019; Shen et al., 2020), carbon fiber (Chen et al., 2014; Zhang et al., 2017), graphene (Tang et al., 2016; Chen et al., 2019) and carbonized polyacrylonitrile (Li et al., 2018). Generally, expect serving as hosts for Se_1-xS_x, these carbonaceous materials play another dual role of establishing conductive frameworks to facilitate ions/electrons transport and inhibiting the shuttle effect (Hu et al., 2020). Nevertheless, the physical adsorption ability of nonpolar pristine carbon materials to polar intermediates is too weak to effectively prevent the dissolution and diffusion of intermediate (Sun et al., 2016; Nazarian-Samani et al., 2021). Research shows heteroatom-doped (B, N, O, etc.) carbon hosts can effectively improve the electrochemical performance of Li-Se_1-xS_x batteries due to the strong chemical affinity of polarized carbon surface, which can significantly trap the soluble intermediates to inhibit the shuttle effect and side reactions in the electrolyte (Guo et al., 2016; Zhang et al., 2017; Fan et al., 2018; He et al., 2018; Sun et al., 2021).

Herein, a series of Se_1-xS_x cathode materials with optimized Se/S ratio are incorporated into N-doped three-dimensional (3D) porous carbon matrix to form novel freestanding Se_1-xS_x foamy cathodes (NC@SWCNTs@Se_1-xS_x) with the assistance of supercritical CO₂ fluid (Figure 1). In carbonate-based electrolyte, NC@SWCNTs@Se_1-xS_x cathodes exhibit single-phase transformation during charge/discharge. Benefiting from the rationally designed structure and chemical composition, NC@SWCNTs@Se_1-xS_x cathodes with high conductivity and strong adsorption present superior electrochemical performance.

FIGURE 1

FIGURE 1. Schematic illustration of the synthetic process of NC@SWCNTs@Se_1-xS_x.

Experimental Section

Preparation of NC@SWCNTs

Melamine foam (3 cm × 3 cm × 3 cm) was washed with anhydrous ethanol and dried in an oven at 80°C for 12 h, then immersed in SWCNTs/NMP suspension (0.4%). After 6 h, the melamine foam impregnated with SWCNTs/NMP suspension was taken out and dried in a vacuum oven at 80°C for 24 h to obtain the precursor of melamine/SWCNTs. The above precursor was calcined at 700°C under flowing N₂ atmosphere for 3 h to obtain NC@SWCNTs host.

Preparation of NC@SWCNTs@Se_1-xS_x

NC@SWCNTs@Se_1-xS_x composites were prepared with the help of supercritical CO₂ (SC-CO₂) fluid, which is reported in our previous works (Fang et al., 2018a; Fang et al., 2018b; Fang et al., 2020). Firstly, S and Se powders with different molar ratios (S:Se = 7:3, 8:2, 9:1) were put into stainless-steel milling jars, respectively. The pre-mixed Se and S mixture was obtained after ball milling (500 rpm) for 12 h. Subsequently, 0.6 g pre-mixed Se and S mixture and a piece of NC@SWCNTs (3 cm × 3 cm × 3 cm, ∼0.4 g) were put into a stainless-steel jar. Then, CO₂ was pumped into the jar until the gaseous pressure reached 8.5 MPa. After the jar was kept at 32°C for 24 h, NC@SWCNTs@Se_1-xS_x precursor was obtained by rapidly releasing CO₂. Then, NC@SWCNTs@Se_1-xS_x precursor was sealed in a quartz glass tube under vacuum. Finally, the sealed quartz glass tube was heated to 400°C for 3 h to obtain NC@SWCNTs@Se_1-xS_x. The samples with different Se/S molar ratios were labeled as NC@SWCNTs@Se_0.3S_0.7, NC@SWCNTs@Se_0.2S_0.8 and NC@SWCNTs@Se_0.1S_0.9, respectively. For comparison, NC@SWCNTs hosts impregnated with Se or S were prepared by using the same SC-CO₂ method and named NC@SWCNTs@Se and NC@SWCNTs@S, respectively.

Materials Characterizations

The morphologies and microstructures of samples were observed on field-emission scanning electron microscopy (FE-SEM, Hitachi S-4800) and transmission electron microscopy (TEM, FEI Tecnai G2 F30) equipped with an energy-dispersive spectroscopy (EDS) detector. X-ray diffraction (XRD) patterns were recorded on Rigaku Ultima IV powder X-ray diffractometer by using Cu Kα radiation (λ = 0.15418 nm). Raman spectra were performed by Renishaw InVia Raman spectrometer (λ = 532 nm). Thermogravimetric analysis (TGA) was conducted on SDT Q600 analyzer (TA Instruments) under a flowing Ar atmosphere.

Electrochemical Measurements

NC@SWCNTs@Se_1-xS_x cathodes were cut into disks of 15 mm in diameter and 2 mm in height. CR2025 coin-type cells were assembled in an Ar-filed glove box (MIKROUNA, moisture <1.0 ppm, oxygen <1.0 ppm) with NC@SWCNTs@Se_1-xS_x composites as cathodes, commercial microporous polypropylene membrane (Celgard 2400) as separator, and lithium metal as anode. A solution of 1.0 M LiPF₆ in a co-solvent of ethylene carbonate (EC) and dimethyl carbonate (DMC) (1:1, volume ratio) was used as electrolyte. The dosage of electrolyte in coin-type cells is 15 μl mg⁻¹ (based on the mass of Se_1-xS_x). Li-Se_1-xS_x cells were cycled in the voltage range of 1.0–3.0 V on a battery testing system (Shenzhen Neware Technology Co. Ltd.). Cyclic voltammetry (CV) was performed on a CHI650B electrochemical workstation (Chenhua, Shanghai, China).

Results and Discussion

The morphology and microstructure of NC@SWCNTs host are characterized by SEM and TEM as illustrated in Figure 2. As vividly depicted in Figure 2A and Supplementary Figure S1, NC@SWCNTs host exhibits a 3D honeycombed network structure, fully inheriting the 3D interconnected framework of melamine foam. Local magnification SEM images (Figures 2B,C) demonstrate that numerous interlaced SWCNTs are covered the surface of melamine foam derived carbon skeletons, as well as SWCNTs are formed into small sheets between carbon skeletons. This unique interconnecting structure not only endows NC@SWCNTs a highly conductive 3D network to accelerate the electron/ion transport, but also effectively enhances the mechanical strength and flexibility of NC@SWCNTs host. Moreover, TEM results (Figure 2D) further indicate that SWCNTs are crisscrossed in carbon skeletons, forming an intertwined 3D network structure. On the basis of EDS results (Figure 2E), the main elements in NC@SWCNTs are C, O and N, which are uniformly distributed in NC@SWCNTs. Notably, N signal is derived from melamine foam since melamine has high content of N. According to the above analysis, NC@SWCNTs host has a typical 3D network structure that is composed of SWCNTs-coated N-doped carbon skeleton derived from melamine foam and wafery sheets interwoven by SWCNTs. The pores and layer gaps in NC@SWCNTs host are conducive to loading more Se_1-xS_x active materials. Meanwhile, the 3D interconnected conductive network framework can not only effectively promote redox kinetics, but also endow NC@SWCNTs host with strong mechanical properties to buffer the volume expansion during cycling. Additionally, the doped N is also beneficial to the adsorption of intermediates.

FIGURE 2

FIGURE 2. (A–C) SEM images and (D) TEM image of NC@SWCNTs. (E) STEM image of NC@SWCNTs and the corresponding mapping images.

After Se_1-xS_x impregnation, compared to NC@SWCNTs host, NC@SWCNTs@Se_1-xS_x composites well maintain the original morphology of NC@SWCNTs (Supplementary Figure S2). Moreover, no discernible Se_1-xS_x particles can be found at the surface of NC@SWCNTs. Additionally, according to EDS mapping results, the C, N, Se and Se signals are overlapped well, suggesting Se_1-xS_x composites are uniformly permeated into the pores and layer gaps of NC@SWCNTs host with the assistance of SC-CO₂ due to the good permeability, excellent diffusivity and high solubility of SC-CO₂. Furthermore, elemental analyses (Supplementary Table S1) of NC@SWCNTs@Se_1-xS_x show that molar ratios of Se to S in NC@SWCNTs@Se_1-xS_x conform to the design values.

NC@SWCNTs@Se_1-xS_x composites are further revealed by XRD and Raman analysis. As illustrated in Figure 3A, all the samples have a wide peak in 2θ ranging from 15 to 40^o, corresponding to the existence of NC@SWCNTs. Meanwhile, the characteristic diffraction peaks of Se and S are clearly observed in NC@SWCNTs@Se and NC@SWCNTs@S samples, respectively. With the introduction of Se, no characteristic diffraction peak of Se is detected in NC@SWCNTs@Se_1-xS_x composites. However, some characteristic diffraction peaks of S with low intensity can be still observed, indicating a small amount of Se may occupy S position and further form Se_1-xS_x in NC@SWCNTs host (Yao et al., 2017). To further investigate the bond between Se and S, Raman spectra were depicted in Figure 3B. Apparently, all the samples have three characteristic peaks located at 260, 375 and 470 cm⁻¹, respectively, which are assigned to Se-Se, Se-S and S-S stretching vibrations, (Chen et al., 2019; Pham et al., 2019). With increasing Se content in Se_1-xS_x, the strength of Se-Se and Se-S bonds are simultaneously increased, whereas the strength of S-S bonds are gradually decreased. Thus, it could be concluded that Se_1-xS_x composites are successfully synthesized.

FIGURE 3

FIGURE 3. (A) XRD patterns of NC@SWCNTs@S, NC@SWCNTs@Se_0.3S_0.7, NC@SWCNTs@Se_0.2S_0.8, NC@SWCNTs@Se_0.1S_0.9 and NC@SWCNTs@Se. (B) Raman spectra of NC@SWCNTs@Se_0.3S_0.7, NC@SWCNTs@Se_0,2S_0.8 and NC@SWCNTs@Se_0.1S_0.9.

To further inspect the Se_1-xS_x content and thermal stability of NC@SWCNTs@Se_1-xS_x composites, TGA tests are performed as shown in Supplementary Figure S3. According to TG results, NC@SWCNTs@S and NC@SWCNTs@Se exhibit the lowest and highest onset decomposition temperatures of ∼130 and ∼300°C, respectively. Meanwhile, the onset decomposition temperatures of NC@SWCNTs@Se_0.3S_0.7, NC@SWCNTs@Se_0.2S_0.8, and NC@SWCNTs@Se_0.1S_0.9 are between NC@SWCNTs@S and NC@SWCNTs@Se samples, and gradually increase with increasing Se content in Se_1-xS_x. It is because the thermal stability of Se is higher than that of S, the higher the content of Se in Se_1-xS_x, the higher the thermal stability of solid solution. Moreover, the distinct weight losses exist in all the samples, corresponding to the active material in samples. Therefore, the actual contents of S, Se_0.3S_0.7, Se_0.2S_0.8, Se_0.1S_0.9, and Se in NC@SWCNTs@S, NC@SWCNTs@Se_0.3S_0.7, NC@SWCNTs@Se_0.2S_0.8, NC@SWCNTs@Se_0.1S_0.9, and NC@SWCNTs@Se are 54.8, 58.7, 52.5, 58.4, and 56.8%, respectively, which are close to the design value of ∼60%.

In order to evaluate the electrochemical performance of NC@SWCNTs@Se_1-xS_x composites, NC@SWCNTs@Se_1-xS_x composites are employed as freestanding cathodes in Li-Se_1-xS_x batteries with carbonate-based electrolyte (LiPF₆-EC/DMC). Figure 4A and Supplementary Figure S4 show initial three cyclic voltammetry (CV) curves of NC@SWCNTs@Se_1-xS_x cathodes at a scanning rate of 0.1 mV s⁻¹ in the potential window from 1.0 to 3.0 V versus Li/Li⁺. At the initial scan, a sharp reduction peak at ∼1.38 V, a small reduction peak at ∼2.37 V, and a broadened oxidation peak at ∼2.14 V are clearly observed. The small reduction peak at ∼2.37 V disappears after the first scan, while the sharp reduction peak at ∼1.38 V shifts to ∼1.7 V during the subsequent scan. The peak shift indicates the activation process during the first lithification process, and the polarization is effectively reduced thereafter (Luo et al., 2014; Zhu et al., 2018). The subsequent CV curves are well overlapped after the first scan, indicating the good cyclability and reversibility of NC@SWCNTs@Se_0.2S_0.8 cathode (Guo et al., 2019). It should be mentioned that the CV curves of NC@SWCNTs@Se_1-xS_x cathodes are obviously different from S cathode, indicating the introduction of Se changes the electrochemical reaction process of S that is conducive to its stable work in carbonate-based electrolytes. Moreover, galvanostatic charge-discharge curves (Figure 4B and Supplementary Figure S5) of NC@SWCNTs@Se_1-xS_x cathodes are consistent with CV results. During the first discharge process, there are two plateaus: one is an extremely short plateau at ∼2.38 V, and another is a long plateau at ∼1.75 V. In the subsequent cycles, the short plateau at ∼2.38 V disappears, while the long plateau at ∼1.75 V becomes a little steeper and shifts to ∼1.88 V. The short plateau at ∼2.38 V is attributed to the transformation of Se_0.2S_0.8 to polysulfides/polyselenides intermediates. And the disappearance of the short plateau is probably due to the dissolution of intermediates into the electrolyte (Li et al., 2015). Meanwhile, the long plateau at 1.75–1.88 V is assigned to the conversion of polysulfides/polyselenides to Li₂S/Li₂Se (Luo et al., 2014). During the charge process, there is only one sloping plateau at ∼2.12 V, corresponding to the conversion of Li₂Se/Li₂S to Se_0.2S_0.8.

FIGURE 4

FIGURE 4. (A) CV curves of the NC@SWCNTs@Se_0.2S_0.8 cathode. (B) Charge/discharge curves of the NC@SWCNTs@Se_0.2S_0.8 cathode at 0.2 A g⁻¹. (C) Cycle performances and (D) rate performances of NC@SWCNTs@Se_1-xS_x cathodes.

Figure 4C shows the cyclic performance of NC@SWCNTs@Se_1-xS_x cathodes with different Se/S ratios at a current density of 0.2 A g⁻¹. NC@SWCNTs@Se_0.2S_0.8 cathode delivers the highest initial discharge capacity (2,398.5 mA h g⁻¹) among NC@SWCNTs@Se_0.3S_0.7, NC@SWCNTs@Se_0.2S_0.8 and NC@SWCNTs@Se_0.1S_0.9 samples. The initial discharge capacity exceeds the theoretical capacity may be attributed to side reactions and the formation of SEI layer on the surface of electrode (Luo et al., 2014). After 200 cycles, the reversible capacities of NC@SWCNTs@Se_0.3S_0.7, NC@SWCNTs@Se_0.2S_0.8 and NC@SWCNTs@Se_0.1S_0.9 samples are 490, 632 and 360 mA h g⁻¹ with the corresponding capacity retentions of 51.7, 65.3 and 47.9%, respectively. Obviously, NC@SWCNTs@Se_0.2S_0.8 cathode exhibits the superior cyclic stability. In addition, the rate capabilities of NC@SWCNTs@Se_1-xS_x cathodes at different current densities are presented in Figure 4D. Compare to other samples, NC@SWCNTs@Se_0.2S_0.8 cathode demonstrates the best rate performance. The reversible rate capacities of NC@SWCNTs@Se_0.2S_0.8 cathode are 998.4, 723.7, 606.8, 506.1, and 415.0 mA h g⁻¹ at the current density of 0.2, 0.5, 0.8, 1.0 and 2.0 A g⁻¹, respectively. When the current density switches back to 0.5 A g⁻¹, the reversible discharge capacity of NC@SWCNTs@Se_0.2S_0.8 cathode reverts to the initial value. Moreover, as shown in Supplementary Table S2 and Supplementary Figure S4, NC@SWCNTs@Se_0.2S_0.8 cathode with Se loading of as high as 4.4 mg cm⁻² (a relevant areal capacity of as high as 2.78 mA h cm⁻²) can surpass most reported Se_1-xS_x cathodes (Luo et al., 2014; Li et al., 2015; Guo et al., 2016; Wei et al., 2016; Li et al., 2017; Yao et al., 2017; Zhang et al., 2017; Hu et al., 2018; Li et al., 2018; Zhu et al., 2018). Such remarkable electrochemical performance of NC@SWCNTs@Se_0.2S_0.8 cathode mainly is due to the following reasons: 1) Se and S in Se_0.2S_0.8 solid solution play different roles: Se can significantly improve the electrical conductivity, while S can greatly enhance capacity. 2) N-doped 3D porous carbon matrix and interlaced SWCNTs not only provide storage space for Se_1-xS_x, but also effectively reinforce the structural stability, and further promote the cycling stability of NC@SWCNTs@Se_1-xS_x cathodes.

Conclusion

In summary, a series of rationally designed freestanding NC@SWCNTs@Se_1-xS_x cathodes with 3D interconnected porous structure are developed with the assistance of supercritical CO₂ fluid. NC@SWCNTs host with 3D network structure serves as an effective matrix for encapsulating Se_1-xS_x as well as facilitating ion/electron transport and redox kinetics. Benefiting from the rationally designed structure and optimized chemical composition, NC@SWCNTs@Se_0.2S_0.8 cathode exhibits excellent cycling stability (632 mA h g⁻¹ at 0.2 A g⁻¹ at 200 cycle) and remarkable rate performance (415 mA h g⁻¹ at 2 A g⁻¹) in carbonate-based electrolyte. This work offers a feasible approach to develop high-performance Se_1-xS_x cathodes for advanced Li-Se_1-xS_x batteries.

Data Availability Statement

The original contributions presented in the study are included in the article/Supplementary Material, further inquiries can be directed to the corresponding author.

Author Contributions

CL: materials preparation, data analysis and manuscript writing; RF: materials preparation and data analysis; KW: manufacture and result analysis of battery; ZX: materials characterization and data analysis; GK: material properties analysis and discussion; YG: electrochemical performance test and results discussion; XH: electrochemical performance test and materials characterization; HH: data analysis and discussion; WZ: data analysis and discussion; YX: experimental design and manuscript revision. All authors contributed to the article and approved the submitted version.

Funding

This research was supported by Zhejiang Provincial Natural Science Foundation of China (LY21E020005), China Postdoctoral Science Foundation (2020M671785 and 2020T130597), National Natural Science Foundation of China (U20A20253) and Zhejiang Provincial Special Support Program for High-level Talents (2020R51004).

Conflict of Interest

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Publisher’s Note

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.

Supplementary Material

The Supplementary Material for this article can be found online at: https://www.frontiersin.org/articles/10.3389/fchem.2021.738977/full#supplementary-material

References

Abouimrane, A., Dambournet, D., Chapman, K. W., Chupas, P. J., Weng, W., and Amine, K. (2012). A New Class of Lithium and Sodium Rechargeable Batteries Based on Selenium and Selenium-Sulfur as a Positive Electrode. J. Am. Chem. Soc. 134, 4505–4508. doi:10.1021/ja211766q

PubMed Abstract | CrossRef Full Text | Google Scholar

Chen, X., Peng, L., Wang, L., Yang, J., Hao, Z., Xiang, J., et al. (2019). Ether-compatible Sulfurized Polyacrylonitrile Cathode with Excellent Performance Enabled by Fast Kinetics via Selenium Doping. Nat. Commun. 10, 1021. doi:10.1038/s41467-019-08818-6

PubMed Abstract | CrossRef Full Text | Google Scholar

Chen, Y., Li, X., Park, K.-S., Hong, J., Song, J., Zhou, L., et al. (2014). Sulfur Encapsulated in Porous Hollow CNTs@CNFs for High-Performance Lithium-Sulfur Batteries. J. Mater. Chem. A. 2, 10126–10130. doi:10.1039/C4TA01823K

CrossRef Full Text | Google Scholar

Du, H., Feng, S., Luo, W., Zhou, L., and Mai, L. (2020). Advanced Li-Se S Battery System: Electrodes and Electrolytes. J. Mater. Sci. Technol. 55, 1–15. doi:10.1016/j.jmst.2020.01.001

CrossRef Full Text | Google Scholar

Fan, H.-N., Chen, S.-L., Chen, X.-H., Tang, Q.-L., Hu, A.-P., Luo, W.-B., et al. (2018). 3D Selenium Sulfide@carbon Nanotube Array as Long-Life and High-Rate Cathode Material for Lithium Storage. Adv. Funct. Mater. 28, 1805018. doi:10.1002/adfm.201805018

CrossRef Full Text | Google Scholar

Fang, R., Liang, C., Xia, Y., Xiao, Z., Huang, H., Gan, Y., et al. (2018a). Supercritical CO2 Mediated Incorporation of Sulfur into Carbon Matrix as Cathode Materials Towards High-Performance Lithium-Sulfur Batteries. J. Mater. Chem. A. 6, 212–222. doi:10.1039/C7TA08768C

CrossRef Full Text | Google Scholar

Fang, R., Lu, C., Zhong, Y., Xiao, Z., Liang, C., Huang, H., et al. (2020). Puffed rice Carbon with Coupled Sulfur and Metal Iron for High-Efficiency Mercury Removal in Aqueous Solution. Environ. Sci. Technol. 54, 2539–2547. doi:10.1021/acs.est.9b07385

PubMed Abstract | CrossRef Full Text | Google Scholar

Fang, R., Xia, Y., Liang, C., He, X., Huang, H., Gan, Y., et al. (2018b). Supercritical CO2-assisted Synthesis of 3D Porous SiOC/Se Cathode for Ultrahigh Areal Capacity and Long Cycle Life Li-Se Batteries. J. Mater. Chem. A. 6, 24773–24782. doi:10.1039/C8TA09758E

CrossRef Full Text | Google Scholar

Guan, B., Zhang, Y., Fan, L., Wu, X., Wang, M., Qiu, Y., et al. (2019). Blocking Polysulfide with Co2B@CNT via "Synergetic Adsorptive Effect" toward Ultrahigh-Rate Capability and Robust Lithium-Sulfur Battery. ACS Nano 13, 6742–6750. doi:10.1021/acsnano.9b01329

PubMed Abstract | CrossRef Full Text | Google Scholar

Guo, B., Yang, T., Du, W., Ma, Q., Zhang, L.-Z., Bao, S.-J., et al. (2019). Double-walled N-Doped carbon@NiCo2S4 Hollow Capsules as SeS2 Hosts for Advanced Li-SeS2 Batteries. J. Mater. Chem. A. 7, 12276–12282. doi:10.1039/C9TA02695A

CrossRef Full Text | Google Scholar

Guo, S.-P., Li, C.-X., Chi, Y., Ma, Z., and Xue, H.-G. (2016). Novel 3-D Network SeS/NCPAN Composites Prepared by One-Pot In-Situ Solid-State Method and its Electrochemical Performance as Cathode Material for Lithium-Ion Battery. J. Alloys Compd. 664, 92–98. doi:10.1016/j.jallcom.2015.12.208

CrossRef Full Text | Google Scholar

Han, B., Li, X., Zhou, Y., Gao, X., Qu, W., Zhang, S., et al. (2019). "Bubble-linking-bubble" Hybrid Fibers Filled with Ultrafine TiN: a Robust and Efficient Platform Achieving Fast Kinetics, strong Ion Anchoring and High Areal Loading for Selenium Sulfide. J. Mater. Chem. A. 7, 18404–18416. doi:10.1039/C9TA05527D

CrossRef Full Text | Google Scholar

He, J., Lv, W., Chen, Y., Xiong, J., Wen, K., Xu, C., et al. (2018). Direct Impregnation of SeS2 into a MOF-Derived 3D Nanoporous Co-N-C Architecture towards superior Rechargeable Lithium Batteries. J. Mater. Chem. A. 6, 10466–10473. doi:10.1039/C8TA02434K

CrossRef Full Text | Google Scholar

Hu, J., Ren, Y., and Zhang, L. (2020). Dual-confined SeS2 Cathode Based on Polyaniline-Assisted Double-Layered Micro/mesoporous Carbon Spheres for Advanced Li-SeS2 Battery. J. Power Sourc. 455, 227955. doi:10.1016/j.jpowsour.2020.227955

CrossRef Full Text | Google Scholar

Hu, J., Zhong, H., Yan, X., and Zhang, L. (2018). Confining Selenium Disulfide in 3D Sulfur-Doped Mesoporous Carbon for Rechargeable Lithium Batteries. Appl. Surf. Sci. 457, 705–711. doi:10.1016/j.apsusc.2018.06.296

CrossRef Full Text | Google Scholar

Li, X., Liang, J., Zhang, K., Hou, Z., Zhang, W., Zhu, Y., et al. (2015). Amorphous S-Rich S1−xSex/C (X ≤ 0.1) Composites Promise Better Lithium-Sulfur Batteries in a Carbonate-Based Electrolyte. Energy Environ. Sci. 8, 3181–3186. doi:10.1039/C5EE01470K

CrossRef Full Text | Google Scholar

Li, Z., Zhang, J., Lu, Y., and Lou, X. W. (2018). A Pyrolyzed Polyacrylonitrile/selenium Disulfide Composite Cathode with Remarkable Lithium and Sodium Storage Performances. Sci. Adv. 4, eaat1687. doi:10.1126/sciadv.aat1687

PubMed Abstract | CrossRef Full Text | Google Scholar

Li, Z., Zhang, J., Wu, H. B., and Lou, X. W. D. (2017). An Improved Li-SeS2 Battery with High Energy Density and Long Cycle Life. Adv. Energ. Mater. 7, 1700281. doi:10.1002/aenm.201700281

CrossRef Full Text | Google Scholar

Lin, S., Chen, Y., Wang, Y., Cai, Z., Xiao, J., Muhmood, T., et al. (2021). Three-dimensional Ordered Porous Nanostructures for Lithium-Selenium Battery Cathodes that Confer superior Energy-Storage Performance. ACS Appl. Mater. Inter. 13, 9955–9964. doi:10.1021/acsami.0c21065

CrossRef Full Text | Google Scholar

Luo, C., Zhu, Y., Wen, Y., Wang, J., and Wang, C. (2014). Carbonized Polyacrylonitrile-Stabilized SeSxCathodes for Long Cycle Life and High Power Density Lithium Ion Batteries. Adv. Funct. Mater. 24, 4082–4089. doi:10.1002/adfm.201303909

CrossRef Full Text | Google Scholar

Nazarian-Samani, M., Haghighat-Shishavan, S., Nazarian-Samani, M., Kashani-Bozorg, S. F., Ramakrishna, S., and Kim, K.-B. (2021). Perforated Two-Dimensional Nanoarchitectures for Next-Generation Batteries: Recent Advances and Extensible Perspectives. Prog. Mater. Sci. 116, 100716. doi:10.1016/j.pmatsci.2020.100716

CrossRef Full Text | Google Scholar

Pham, V. H., Boscoboinik, J. A., Stacchiola, D. J., Self, E. C., Manikandan, P., Nagarajan, S., et al. (2019). Selenium-sulfur (SeS) Fast Charging Cathode for Sodium and Lithium Metal Batteries. Energ. Storage Mater. 20, 71–79. doi:10.1016/j.ensm.2019.04.021

CrossRef Full Text | Google Scholar

Shen, C., Wang, T., Xu, X., and Tian, X. (2020). 3D Printed Cellular Cathodes with Hierarchical Pores and High Mass Loading for Li-SeS2 Battery. Electrochimica Acta 349, 136331. doi:10.1016/j.electacta.2020.136331

CrossRef Full Text | Google Scholar

Sun, F., Cheng, H., Chen, J., Zheng, N., Li, Y., and Shi, J. (2016). Heteroatomic SenS8-N Molecules Confined in Nitrogen-Doped Mesoporous Carbons as Reversible Cathode Materials for High-Performance Lithium Batteries. ACS Nano 10, 8289–8298. doi:10.1021/acsnano.6b02315

PubMed Abstract | CrossRef Full Text | Google Scholar

Sun, J., Du, Z., Liu, Y., Ai, W., Wang, K., Wang, T., et al. (2021). State‐Of‐The‐Art and Future Challenges in High Energy Lithium-Selenium Batteries. Adv. Mater. 33, 2003845. doi:10.1002/adma.202003845

CrossRef Full Text | Google Scholar

Tang, C., Li, B.-Q., Zhang, Q., Zhu, L., Wang, H.-F., Shi, J.-L., et al. (2016). CaO-templated Growth of Hierarchical Porous Graphene for High-Power Lithium-Sulfur Battery Applications. Adv. Funct. Mater. 26, 577–585. doi:10.1002/adfm.201503726

CrossRef Full Text | Google Scholar

Wei, Y., Tao, Y., Kong, Z., Liu, L., Wang, J., Qiao, W., et al. (2016). Unique Electrochemical Behavior of Heterocyclic Selenium-Sulfur Cathode Materials in Ether-Based Electrolytes for Rechargeable Lithium Batteries. Energ. Storage Mater. 5, 171–179. doi:10.1016/j.ensm.2016.07.005

CrossRef Full Text | Google Scholar

Xu, F., Tang, Z., Huang, S., Chen, L., Liang, Y., Mai, W., et al. (2015). Facile Synthesis of Ultrahigh-Surface-Area Hollow Carbon Nanospheres for Enhanced Adsorption and Energy Storage. Nat. Commun. 6, 7221. doi:10.1038/ncomms8221

PubMed Abstract | CrossRef Full Text | Google Scholar

Xu, Q.-T., Xue, H.-G., and Guo, S.-P. (2019). Status and Prospects of SexSy Cathodes for Lithium/sodium Storage. Inorg. Chem. Front. 6, 1326–1340. doi:10.1039/C9QI00278B

CrossRef Full Text | Google Scholar

Yao, Y., Zeng, L., Hu, S., Jiang, Y., Yuan, B., and Yu, Y. (2017). Binding S0.6 Se0.4 in 1D Carbon Nanofiber with C-S Bonding for High-Performance Flexible Li-S Batteries and Na-S Batteries. Small 13, 1603513. doi:10.1002/smll.201603513

PubMed Abstract | CrossRef Full Text | Google Scholar

Yuan, Y. F., Chen, Q., Zhu, M., Cai, G. S., and Guo, S. Y. (2021a). Nano Tube-In-Tube CNT@void@TiO2@C with Excellent Ultrahigh Rate Capability and Long Cycling Stability for Lithium Ion Storage. J. Alloys Compd. 851, 156795. doi:10.1016/j.jallcom.2020.156795

CrossRef Full Text | Google Scholar

Yuan, Y. F., Zhao, W. C., Chen, L., Cai, G. S., and Guo, S. Y. (2021b). CoO Hierarchical Mesoporous nanospheres@TiO2@C for High-Performance Lithium-Ion Storage. Appl. Surf. Sci. 556, 149810. doi:10.1016/j.apsusc.2021.149810

CrossRef Full Text | Google Scholar

Zhang, J., Li, Z., and Lou, X. W. D. (2017). A Freestanding Selenium Disulfide Cathode Based on Cobalt Disulfide-Decorated Multichannel Carbon Fibers with Enhanced Lithium Storage Performance. Angew. Chem. Int. Ed. 56, 14107–14112. doi:10.1002/ange.20170810510.1002/anie.201708105

PubMed Abstract | CrossRef Full Text | Google Scholar

Zhang, W., Li, S., Wang, L., Wang, X., and Xie, J. (2020). Insight into Sulfur-Rich Selenium Sulfide/pyrolyzed Polyacrylonitrile Cathodes for Li-S Batteries. Sustain. Energ. Fuels 4, 3588–3596. doi:10.1039/D0SE00512F

CrossRef Full Text | Google Scholar

Zheng, Y. Q., Yuan, Y. F., Tong, Z. W., Yin, H., Yin, S. M., and Guo, S. Y. (2020). Watermelon-like TiO2 Nanoparticle (P25)@microporous Amorphous Carbon Sphere with Excellent Rate Capability and Cycling Performance for Lithium-Ion Batteries. Nanotechnology 31, 215407. doi:10.1088/1361-6528/ab73be

PubMed Abstract | CrossRef Full Text | Google Scholar

Zhu, T., Pang, Y., Wang, Y., Wang, C., and Xia, Y. (2018). S0.87Se0.13/CPAN Composites as High Capacity and Stable Cycling Performance Cathode for Lithium Sulfur Battery. Electrochimica Acta 281, 789–795. doi:10.1016/j.electacta.2018.06.026

CrossRef Full Text | Google Scholar